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facilities. This concurs with the results of Lueker et al. The red line is the
median, the box spans the interquartile range 25—75 percentiles and the whiskers
show the extreme data points not considered outliers.

Additionally, given the relatively small contribution of the LSLE deep waters
and their similarity to the carbonate chemistry of the CIL, their influence is
considered inconsequential on the properties of the mixture. Hence, a
conservative mixing model was constructed based on the chemical properties of
the two main source water masses in the fjord i.

Field measurements follow the trend displayed by the mixing model. The fjord
appears to be a net source of CO 2 to the atmosphere during periods of high
freshwater discharge i. This is consistent with the weak buffer capacity of the
freshwater. Lawrence Estuary near Tadoussac at the mouth of the fjord are highly
supersaturated in CO 2 with respect to the atmosphere and only the highly
productive waters of the Lower St. Lawrence Estuary manage to draw down the
surface p CO 2 to near atmospheric values.

In other words, degassing of the metabolic CO 2 accumulated in the river and
upper estuary is slow. Thus, changes in temperature-normalized p CO 2 primarily
reflect changes in DIC by mixing and biological activity. Hence, discrepancies
between results of the mixing model and field measurements can be ascribed to
microbial respiration and photosynthesis. The dashed line represents equilibrium
with the atmosphere i.

Data points above the line indicate that waters are supersaturated in O 2 ,
whereas those below the line identify O 2 -undersaturated waters with respect to
the atmosphere. Error bars show standard error of the mean for O 2 saturation
values. Thus, during these sampling periods, biological activity was dominated
by microbial respiration Fig.


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Data were normalized to a common salinity average for each sampling period
according to the method of Friis et al. Error bars show standard error of the
mean for NDIC values. Error bars show standard error of the mean for AOU values.
Furthermore, Fig. Likewise, the September data reveal little biological
activity, although a slight dominance of respiration i. These results highlight
the importance of the freshwater plume from the Saguenay River in regulating the
p CO 2 dynamics in the fjord. However, wind speeds are relatively low in the
studied system 1.

Mixing of marine waters with SRW at the head of the fjord leads to the formation
of a brackish surface layer wedge , while the CIL replenishes the bottom waters
of the fjord. The analysis further unveiled a small contribution of the LSLE
bottom water to the bottom waters of the fjord, adding to the complexity of the
water column structure.

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The SLRW has a negligible influence on the water properties in the fjord, except
near its mouth — sampling of the very turbulent waters directly over the fjord's
first and shallowest sill would help refine the contribution of the SLRW to the
fjord's surface waters. Direct measurements of surface water p CO 2 acquired in
May confirmed this trend.

Biological activity alters the surface water p CO 2 , with both photosynthesis
and respiration impacting the waters depending on the sampling month. Overall,
the fjord serves as a source of CO 2 to the atmosphere during the ice-free
season, with an average yearly outgassing flux of 0. A study of the dissolved
inorganic carbon budget of fjords not only affords information on their carbon
dioxide levels i. In addition to biological production, upwelling, water
temperature and the spreading of freshwater plumes all regulate p CO 2 in
coastal systems.

Wind speed is also critical as it impacts sea state and the efficiency of gas
exchange at the air—sea interface Chen et al. Hence, the importance of wind on
controlling the CO 2 flux needs to be further investigated, especially in
high-latitude fjords where strong winds are often focused along narrow channels
between steep cliffs and narrow inlets. Anthropogenic activities, through
climate change, are altering the continental water cycle, along with the flows
of carbon, nutrients and sediment to the coastal oceans Borges, and thus the
sequestration of anthropogenic CO 2 by the oceans.

In glacial fjords, freshwater discharge will be modified by accelerated glacier
melting and their ultimate demise. Knowledge of the spatial and temporal
variability of glacial discharge and seasonal ice cover in high-latitude fjords
is essential to estimate their influence on circulation patterns and freshwater
export, both of which impact local productivity, terrestrial carbon burial and
export as well as CO 2 fluxes in these complex ecosystems.

Finally, an improved understanding of the coastal carbon cycle will require a
more comprehensive spatial and temporal coverage of surface mixed layer p CO 2
data in these environments, ideally from direct measurements. Each large symbol
square, circle, triangle and star identifies distinct source water masses. Where
possible, pH is reported on the total scale, except for freshwater samples which
are reported on the NBS scale. Few pH data are available on the total scale for
May , as 0.

Data presented in this paper are available upon request from one of the authors
louise.

AM and LD conceived the project. AM acquired and processed the data prior to LD
conducted the data analysis and wrote the first draft of the paper, whereas AM
provided editorial and scientific recommendations. HT provided results of
alkalinity and dissolved inorganic carbon analyses and scientific
recommendations. Annane, S. Bauer, J. Bellis, A. Belzile, M.

Borges, A. Bourgault, D. Ocean, 50, 17—30, Brewer, P. Cai, W.


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Caldeira, K. Chen, C. II, 56, —, Chester, R. Clayton, T. I, 40, —, Dickie, L.
Dickson, A. Dinauer, A. Lawrence, Canada , Mar. Doney, S. Douglas, N. El-Sabh,
M. Epstein, S. Feely, R. Friedlingstein, P.

Friis, K. Frankignoulle, M. Galbraith, P. Lawrence, J. Gattuso, J. Gilbert, D.
In recent decades, living alone has grown in popularity in young and middle
adulthood, among men of all ages, and for both sexes following a separation or
divorce. With these shifts, pathways to living alone and future intentions have
also become more varied.

For some individuals, living alone is seen as a transitional situation before
forming a family. For others, it has become a more enduring lifestyle that was
not necessarily planned or desired, but that occurred as a result of
circumstances. Other individuals may see living alone as a preferred way of
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