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This, in turn, suggests that the geochemical evolution of each magmatic unit may have occurred independently, and that emplacement-stage fractionation may have been a minor feature. Thus, it is reasonable to suspect a deep and perhaps source-inherited origin for the main geochemical variations in the rocks of the batholith. This possibility will be further explored below. Primary reduction was by jaw crusher, intermediate reduction by steel Tema mill, and fine crushing was carried out in a tungsten carbide Tema mill. Sample preparation and major-element analyses were carried out in the Central Analytical Facility at the University of Stellenbosch, by X-ray fluorescence spectrometry XRF , using glass disks made with lithium borate flux, but without any heavy absorber added. The loss on ignition LOI values and original totals are also provided. Samples were analysed for trace elements including REE by solution inductively coupled plasma mass spectrometry ICP-MS in the Department of Geological Sciences at the University of Cape Town, using a Thermo X-Series 2 instrument, and the following analytical procedure: 50 mg of sample powder were dissolved in a HF—HNO 3 mixture in sealed Savilex beakers on a hotplate for 48 h, followed by evaporation to incipient dryness and two treatments of 2 ml of concentrated HNO 3. Standardization was against artificial multi-element standards. Major-oxide, trace-element and REE data for the eight intrusive units are presented in Table 3. Percentage relative deviations of measured concentrations from certified values in standard basalt BHVO Figure 4 shows a variety of major-element Harker-type variation diagrams for the Heerenveen rocks. SiO 2 contents do not vary continuously. This division into low- and high-SiO 2 groups or SiO 2 gap occurs not only between units, but also within two of the mapped units. It is thus a fundamental division, the nature of which will be explored later. SIMELIZA TOURS, BARBERTON: ADDRESS, PHONE NUMBER, SIMELIZA TOURS REVIEWS: 5/5 African Dating And Singles Site. Browse Now. Trust Your Love Life to the Experts – Get Started! Pair Up And Share the Power Of Love. What follows is a description of the variations and a discussion of their meaning for the genesis of the magmas. Geochemical variation diagrams showing the compositional variations within the units and stages of the batholith. Black squares, Stage 1, leucogranite 1; dark grey symbols, Stage 2 circles, porphyritic granite; squares, grey granite ; light grey symbols, Stage 3 circles, leucogranite 2; squares, quartz monzonite; diamonds, pink granite; triangles, granodiorite ; white circles, Stage 4, pink granite 2. The Badplaas pluton forms the wall-rocks of the Heerenveen batholith and the data were taken from Clemens et al. In e the fields for low-, medium- and high-K calcalkaline and shoshonitic series from Le Maitre et al. For rocks other than the quartz monzonite of Stage 3, TiO 2 shows a good, quasi-linear correlation with SiO 2 , with the expected negative slope Fig. The Stage 3 quartz monzonite data points form what appears to be a splay trend of lower slope, at lower SiO 2 concentration. Those for the grey granite of Stage 2 also appear to form a sub-trend. P 2 O 5 not shown exhibits a similar variation to TiO 2. Al 2 O 3 variation also not shown is rather scattered, as is apparent from the observation that, at c. As for TiO 2 , the Stage 3 quartz monzonites and the Stage 2 grey granites form sub-trends. The scatter in TiO 2 , relative to FeO T would be compatible with entrainment of peritectic or restitic ilmenite in varying proportions, in most of the Heerenveen magmas, but not for the quartz monzonite of Stage 3. Overall, the MgO variation Fig. Again, the grey granite shows an internal, good linear variation, and there may be a trend in the data points for the quartz monzonite. However, the data for the other units are more scattered. One possible model for the production of a series of magmas such as this involves mixing between felsic and mafic end-member magmas. Average Early Archaean basaltic and andesitic rocks Condie, are also plotted as crosses. It is readily apparent that neither the overall trend in the variation of MgO nor any internal sub-trend that might exist is likely have an intermediate or mafic magma as a mixing end-member, and especially not an end-member similar to average Early Archaean intermediate to mafic igneous rocks. It therefore seems highly unlikely that the variations within the Heerenveen batholith are due to magma mixing. This conclusion is reinforced in some of the other variation diagrams discussed below, and is also supported by the paucity of magmatic enclaves in the rocks. FOOD AND DINING CaO variation Fig. For most groups of rocks, K 2 O is highly scattered Fig. In this K 2 O plot, many of the rock units form distinct clusters. The plot also shows the dividing lines between the various rock series, from Le Maitre et al. Fractionation paths normally produce variation trends that are subparallel to the series boundaries e. The lack of such trends and the presence of a high degree of vertical scatter in the plot suggest that crystal fractionation is an unlikely explanation for this variation. K 2 O is plotted against Na 2 O in Fig. Overall there is an expected negative trend, with quasi-linear variations for some of the units. This suggests that the protoliths for these magmas may have been basaltic in composition. It should be noted, however, that the data points for many of the units actually straddle this boundary, implying magma derivation from heterogeneous source rocks. The positions of the data points for average Early Archaean basalt and andesite are, again, in a region of the plot that effectively rules out magma mixing with such end-members as a cause of the variation. Figure 5 shows the variations in some calculated parameters, plotted against SiO 2 or MgO. The only unit that is actually metaluminous is the quartz monzonite of Stage 3. This, along with its low SiO 2 , high MgO, separate trends on the variation diagrams and potassic, alkaline character mark the magmas of this unit as fundamentally different from the others in the batholith. For Mg-number [mol. THINGS TO DO IN BARBERTON For the rest of the units, the data points define either uncorrelated clouds or near-vertical arrays. This sort of variation is unlike that expected for rocks that belong to a differentiation series produced by crystal fractionation, or a series produced through magma mixing. This reinforces the already cited evidence that these processes were not important for the Heerenveen magmas. The other important observation in this diagram is that the units belonging to the earlier emplacement stages Stages 1 and 2 tend to be more magnesian higher Mg-number , despite their lower MgO contents Fig. Partial melting experiments on all types of protoliths have demonstrated that the MgO contents of melts increase with T. This is true whether the experiments are fluid-absent or fluid-present. Thus, it seems more likely that the protoliths for the earlier stages contained more mafic rocks. Combined with their peraluminous character, it seems likely that the magmas from these early stages of batholith construction were produced through melting reactions that left substantial quantities of hornblende behind in the residual assemblages see, e. The inferred presence of large modal quantities of residual hornblende in the restitic source rocks suggests that the melting reactions may have been fluid-present, as fluid-absent partial melting would have destroyed the amphibole, leaving residual, anhydrous pyroxenes. Figure 5 c Mg-number plotted against MgO content shows that there is no correlation between these two parameters. This is instructive because it rules out production of the series of magma compositions by any kind of mixing between a mafic magma high MgO and Mg-number and a felsic magma low MgO and Mg-number. The same is true for CaO variation with MgO not shown ; the lack of correlation here also rules out mafic—felsic magma mixing. 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