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* Skip to Article Content * Skip to Article Information Working off-campus? Learn about our remote access options Search withinThis JournalAnywhere * Search term Advanced Search Citation Search * Search term Advanced Search Citation Search Login / Register Macromolecular Symposia Volume 186, Issue 1 p. 81-86 Article CONDUCTIVE POLYMERS AS A NEW TYPE OF THERMOELECTRIC MATERIAL Naoki Toshima, Naoki Toshima Department of Materials Science and Engineering, Science University of Tokyo in Yamaguchi, Onoda-shi, Yamaguchi 756-0884, Japan Search for more papers by this author Naoki Toshima, Naoki Toshima Department of Materials Science and Engineering, Science University of Tokyo in Yamaguchi, Onoda-shi, Yamaguchi 756-0884, Japan Search for more papers by this author First published: 17 September 2002 https://doi.org/10.1002/1521-3900(200208)186:1<81::AID-MASY81>3.0.CO;2-S Citations: 113 About * * RELATED * INFORMATION * PDF PDF Tools * Request permission * Export citation * Add to favorites * Track citation ShareShare Give access Share full text access Close modal Share full-text access Please review our Terms and Conditions of Use and check box below to share full-text version of article. I have read and accept the Wiley Online Library Terms and Conditions of Use -------------------------------------------------------------------------------- Shareable Link Use the link below to share a full-text version of this article with your friends and colleagues. Learn more. Copy URL Share a link Share on * Facebook * Twitter * Linked In * Reddit * Wechat ABSTRACT Thermoelectric properties were investigated for the films of electrically conductive doped polyanilines. The thermoelectric performance, evaluated by thermoelectric figure-of-merit (ZT = T (S2 σ) / κ), of various protonic acid-doped polyaniline bulk films was found to depend on the electrical conductivity σ of the film. Thus, the higher the electrical conductivity, the higher the figure-of-merit is, because the thermal conductivity κ of polyaniline films does not depend on the electrical conductivity. Among the conductive bulk films of polyaniline, the highest figure-of-merit (ZT = 1 × 10−4) was observed for (±)-10-camphorsulfonic acid (CSA)-doped polyaniline in an emeraldine form (σ - 188 S cm−1) at room temperature. The multilayered film, composed of electrically insulating emeraldine base layers and electrically conducting CSA-doped emeraldine salt layers, exhibited 6 times higher ZT at 300 K than that of a bulk film of CAS-doped polyaniline, showing the highest ZT value of 1.1 × 10−2 at 423 K. Stretching of the CAS-doped polyaniline film also increased the figure-of-merit of doped polyaniline films along the direction of the stretching. CITING LITERATURE Volume186, Issue1 Special Issue: Macromolecule-Metal Complexes (mmc-9) August 2002 Pages 81-86 * RELATED * INFORMATION RECOMMENDED * Conductive polymers/polyacrylonitrile composite fibers: Fabrication and properties Youyi Xia, Yun Lu, Polymer Composites * Nanostructured Conductive Polymers by Electrospinning Ioannis S. Chronakis, Nanostructured Conductive Polymers, [1] * Conductive blends of thermally dodecylbenzene sulfonic acid-doped polyaniline with thermoplastic polymers M. Zilberman, G. I. Titelman, A. Siegmann, Y. Haba, M. Narkis, D. Alperstein, Journal of Applied Polymer Science * Conducting polymers: Efficient thermoelectric materials Nidhi Dubey, Mario Leclerc, Journal of Polymer Science Part B: Polymer Physics * Carbon-Nanotube-Based Thermoelectric Materials and Devices Jeffrey L. Blackburn, Andrew J. Ferguson, Chungyeon Cho, Jaime C. 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