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JavaScript is disabled on your browser. Please enable JavaScript to use all the features on this page. Skip to main contentSkip to article ScienceDirect * Journals & Books * * Search RegisterSign in * View PDF * Download full issue Search ScienceDirect OUTLINE 1. Highlights 2. Abstract 3. Keywords 4. 1. Introduction 5. 2. The century-old theory for underwater visibility 6. 3. New theory for underwater visibility 7. 4. Verification of the new model with independent measurements 8. 5. Discussion and conclusions 9. Acknowledgments 10. Appendix A. An illustration of the relationship between Kdpc and Kdtr 11. References Show full outline CITED BY (215) FIGURES (7) 1. 2. 3. 4. 5. 6. Show 1 more figure TABLES (1) 1. Table 1 REMOTE SENSING OF ENVIRONMENT Volume 169, November 2015, Pages 139-149 SECCHI DISK DEPTH: A NEW THEORY AND MECHANISTIC MODEL FOR UNDERWATER VISIBILITY Author links open overlay panelZhongPing Lee a, Shaoling Shang b, Chuanmin Hu c, Keping Du d, Alan Weidemann e, Weilin Hou e, Junfang Lin a, Gong Lin b Show more Outline Add to Mendeley Share Cite https://doi.org/10.1016/j.rse.2015.08.002Get rights and content Under a Creative Commons license open access HIGHLIGHTS * • Caveats in the century-old underwater visibility theory are discussed. * • A new theory for underwater visibility is proposed. * • A new mechanistic model for Secchi disk depth is established. * • Results from the new model are verified with wide range of measurements. ABSTRACT Secchi disk depth (ZSD) is a measure of water transparency, whose interpretation has wide applications from diver visibility to studies of climate change. This transparency has been explained in the past 60 + years with the underwater visibility theory, the branch of the general visibility theory for visual ranging in water. However, through a thorough review of the physical processes involved in visual ranging in water, we show that this theory may not exactly represent the sighting of a Secchi disk by a human eye. Further, we update the Law of Contrast Reduction, a key concept in visibility theory, and develop a new theoretical model to interpret ZSD. Unlike the classical model that relies strongly on the beam attenuation coefficient, the new model relies only on the diffuse attenuation coefficient at a wavelength corresponding to the maximum transparency for such interpretations. This model is subsequently validated using a large (N = 338) dataset of independent measurements covering oceanic, coastal, and lake waters, with results showing excellent agreement (~ 18% average absolute difference, R2 = 0.96) between measured and theoretically predicted ZSD ranging from < 1 m to > 30 m without regional tuning of any model parameters. This study provides a more generalized view of visual ranging, and the mechanistic model is expected to significantly improve the current capacity in monitoring water transparency of the global aquatic environments via satellite remote sensing. * Previous article in issue * Next article in issue KEYWORDS Secchi disk depth Water transparency Visibility theory Remote sensing Beam attenuation coefficient Diffuse attenuation coefficient 1. INTRODUCTION Secchi disk, a white or black-and-white disk with a diameter generally about 30 cm, is the oldest “optical instrument” used to measure transparency of ocean and lake waters (see Tyler (1968), Wernand (2010), and Aas, Høkedal, and Sørensen (2014) for a detailed review of the history of Secchi disk). The Secchi disk depth (ZSD, m), a depth when a Secchi disk is no longer viewable by an observer when it is lowered into the water, represents a quantitative measure of the transparency of that water body, or the visibility in the vertical direction (Duntley, 1952). Since the demonstration of transparency measurements with a Secchi disk about 200 years ago (Aas et al., 2014, Wernand, 2010), due to its low cost and easiness to operate, there have been millions of such measurements (along with different sizes of disks) worldwide in the past century (Boyce, Lewis, & Worm, 2012), with ZSD found in a range of a few centimeters for turbid lakes to around 70 m for the clearest oceanic waters (http://www.secchidipin.org/secchi_records.htm). Although more sophisticated optical-electro systems are currently available to measure water quality parameters, Secchi disks are still being widely and regularly used to measure water transparency in both limnology and oceanography studies. Such data are useful to describe the spatial variability of water properties (Arnone et al., 1984, Binding et al., 2007, Carlson, 1977, Lewis et al., 1988, Megard and Berman, 1989); to highlight the impact of light availability for the health of substrates (Yentsch et al., 2002); and to show the changes of phytoplankton concentration in the oceans in the past 100 + years (Boyce, Lewis, & Worm, 2010). The theoretical interpretation of the Secchi disk depth falls into the visual optics of natural waters (Preisendorfer, 1976, Preisendorfer, 1986) or the underwater visibility theory (Duntley, 1952, Zaneveld and Pegau, 2003) — the branch of the general visibility theory for visual ranging in water. Detailed derivations (also see Section 2) to relate ZSD with water's optical properties can be found in Duntley (1952), Preisendorfer, 1976, Preisendorfer, 1986, Zaneveld and Pegau (2003), and Aas et al. (2014). A general conclusion from these classical works is that ZSD is inversely proportional to the sum of Kd and c within the visible domain, with Kd (m− 1) being the diffuse attenuation coefficient of downwelling plane irradiance and c (m− 1) the beam attenuation coefficient. c is an inherent optical property (IOP) (Preisendorfer, 1976) which does not vary with the angular distribution of a light field, while Kd is an apparent optical property (AOP) which does vary with the angular light distribution (Preisendorfer, 1976). Because c is generally 2–5 times or more greater than Kd for wavelengths in the visible domain, in essence ZSD is primarily determined by c following the classical theory. But, numerous measurements (Aas et al., 2014, Bukata et al., 1988, Davies-Colley and Vant, 1988, Effler, 1988, Holmes, 1970, Kratzer et al., 2003, Megard and Berman, 1989) have found that: (1) there is no universal relationship between ZSD and c, and: (2) the correlation between ZSD and Kd is typically similar or better than the correlation between ZSD and c. Note that in general Kd and c are two independent optical properties for aquatic environments. In addition, field measurements (Verschuur, 1997) of ZSD show that it varies with sun angle by ~ 20% between the Sun at zenith and the Sun at 60° from zenith. Such observations are contradictory to the theoretical prediction based on the classical underwater visibility theory. Furthermore, this theory could predict that a half-black–half-white disk will be detectable regardless of its depth in water, which is also contradictory to human experiences (see more detailed discussions in Section 2.2). These observations and results are quite puzzling, as the underwater visibility theory and the associated models have been the rule in the past 60 + years to theoretically interpret ZSD (Duntley, 1952, Preisendorfer, 1986). Here we revisit the derivations, in particular the key assumptions, associated with the classical visibility theory (CVT) and discuss the likely lapses in that theory for the inconsistency between the theoretical predictions and observations. We further propose a new theory and a mechanistic model to interpret and estimate ZSD, which we subsequently verify with independent measurements from a wide range of aquatic environments. 2. THE CENTURY-OLD THEORY FOR UNDERWATER VISIBILITY 2.1. THEORETICAL DERIVATIONS Consider a Lambertian disk placed horizontally at a depth z in water which is viewed by a snorkeler just below the surface (see Fig. 1). Following radiative transfer theory, the radiance over the target (LT) propagating upward towards the snorkeler can be expressed as (Aas et al., 2014, Duntley, 1952, Højerslev, 1986, Preisendorfer, 1986, Zaneveld and Pegau, 2003),(1)dLTzdz=−cLTz+∫4πL'Tzθφβθφdω,with L'T the radiance distribution in the 4π direction above the target and β the volume scattering function of water (see Table 1 for notations; here the wavelength dependence is omitted for brevity). Note that here we use radiometric rather than photometric quantities (Aas et al., 2014, Duntley, 1952, Højerslev, 1986, Preisendorfer, 1986, Zaneveld and Pegau, 2003) to discuss the concepts and assumptions taken by the CVT in interpreting Secchi disk depth, as the concepts and assumptions remain the same in both radiometric and photometric formulation. 1. Download : Download high-res image (236KB) 2. Download : Download full-size image Fig. 1. A cartoon showing how the light over an underwater target and that of the background are detected by a surface snorkeler. Table 1. Notations. SymbolDescriptionUnitβVolume scattering function of waterm− 1 sr− 1bfForward scattering coefficientm− 1cBeam attenuation coefficientm− 1CaApparent contrast–CanNew apparent contrastsr− 1CiInherent contrast–CinNew inherent contrastsr− 1CtContrast threshold of human eye–CtrContrast threshold of human eye in radiance reflectancesr− 1[Chl]Concentration of chlorophyllmg/m3EdDownwelling irradianceW/m2/nmKdDiffuse attenuation coefficient of downwelling plane irradiancem− 1KdpcDepth-averaged diffuse attenuation coefficient of downwelling irradiance at the wavelength of perceived colorm− 1KdtrDepth-averaged diffuse attenuation coefficient of downwelling irradiance in the spectral transparent windowm− 1KTtrDepth-averaged diffuse attenuation coefficient of radiance reflected by a target and in the spectral transparent windowm− 1LwUpwelling radiance of adjacent water without a diskW/m2/nm/srL'TRadiance distribution over the targetW/m2/nm/srL'wRadiance distribution over the backgroundW/m2/nm/srLTUpwelling radiance over the area with a targetW/m2/nm/srLTtr(0 −)Upwelling radiance just below the surface of the target areaW/m2/nm/srLwtr(0 −)Upwelling radiance just below the surface of the background areaW/m2/nm/srLCtrContrast in radiance between the disk and no-disk areasW/m2/nm/srrTRadiance reflectance right above a targetsr− 1rwRadiance reflectance of background (water)sr− 1VwVisibility in horizontal directionmzWater depthmZSDSecchi disk depth or vertical visibilitym Similarly the upward radiance of the adjacent water without the disk (Lw) is given by(2)dLwzdz=−cLwz+∫4πL'wzθφβθφdω,with L'w the radiance distribution of the background (reference) in the 4π direction. In all historical derivations (Aas et al., 2014, Duntley, 1952, Preisendorfer, 1986, Zaneveld and Pegau, 2003), it was assumed that(3)∫4πL'Tzθφβθφdω=∫4πL'wzθφβθφdω,and subtraction of Eqs. (1), (2) resulted in(4)dLTz−Lwzdz=−cLTz−Lwz. Assuming the water is homogeneous, integrating Eq. (4) from depth to surface results in(5)LT0−Lw0=LTz−Lwze−cz. Further, in the CVT, the apparent contrast (Ca) between the target and the background (or reference) is defined as(6)Ca=LT0−Lw0Lw0. The solar irradiance propagating from surface to depth generally follows an exponential decline function (Gordon & Morel, 1983)(7)Edz=Ed0−e−Kdz. Applying Eqs. (6), (7) to Eq. (5) leads to(8)Ca=Cie−Kd+cz,with the inherent contrast, Ci, defined as (Aas et al., 2014, Duntley, 1952, Preisendorfer, 1986, Zaneveld and Pegau, 2003)(9)Ci=rT−rwrw. Here rT and rw are the reflectance of the target (measured right above it) and the background, respectively. Eq. (8) forms the Law of Contrast Reduction (Duntley, 1952, Preisendorfer, 1986), which is the core of the classical theory for visibility in both air and water, and has been adopted by the research community for more than 60 years to interpret underwater visibility. Such a Law of Contrast Reduction is the same as that used for visual ranging in air (Middleton, 1952). When Ca matches the threshold of eye detection (Ct), the visibility in the vertical direction (ZSD, or V− 90 in Duntley (1952)), is given by(10)ZSD=1Kd+cln1CtrT−rwrw. Further, if the target is black (rT = 0, i.e., negative contrast between the target and the background) and viewed horizontally, the maximum horizontal detectable distance is (Duntley, 1952, Preisendorfer, 1986, Zaneveld and Pegau, 2003)(11)Vw=−lnCtc. As Duntley (1952) pointed out, Eq. (11) is in an identical form as the Koschmieder theory established 90 years ago for visibility in the air (Middleton, 1952). Furthermore, because c is an IOP, the predicted horizontal visibility is independent of the azimuth viewing direction (or the background) for a given threshold, which thus actually represents an easy-to-understand index for the quality of atmosphere or water. Eqs. (10), (11) become the key analytical models for visibility applications in air and water in the past 60 + years. And, for the above derivations, Eq. (3) is the critical assumption. The validity of this assumption, however, as discussed in detail below, may not be assumed automatically for visual ranging. 2.2. CAVEATS IN THE CLASSICAL THEORY AND ASSOCIATED MODEL 2.2.1. THE ATTENUATION OF CONTRAST The beam attenuation coefficient (c) is used in the CVT to propagate the contrast of a finite-size target (Eqs. (5), (8)), where by definition c represents the attenuation of a collimated light beam (Preisendorfer, 1976). In the theoretical derivations to reach Eqs. (5), (8), there was no consideration of the unique high-angular resolution of human eyes; and the relative size between the target and the viewing distance (see Fig. 1) is ignored. Basically, the target is treated as a small object, leading to the assumption that both sides of Eq. (3) can be assumed to equal each other. This assumption is the key for the resulted contrast propagation (Eq. (5)) and the Law of Contrast Reduction for a vertically-viewed target (Eq. (8)). This assumption is generally appropriate for the visibility theory in air where the maximum viewable distance is often in the order of several tens of kilometers and the target (a finite size black object) is in the order of meters (Middleton, 1952). For a target in water (such as a Secchi disk or a diver, which is usually several tens of centimeters or larger), because of the significantly higher absorption and scattering coefficients of water constituents than that of air molecules (Kirk, 1994, Middleton, 1952), the maximum viewable distance is at most several tens of meters, i.e., ~ 1/1000 of that in air, consequently the validity of Eq. (3) is in question. The “measurement” or detection of a target by the human eye is very different from that by an eletro-optic sensor (Duntley, 1952), where the eye–brain system is an optical imager with an array of millions of “tiny-sensors”. For a healthy eye system, it can collect information simultaneously for targets in a range of ~ 160° × 175° (although the actual imaging region is smaller than this). Such a unique combination enables simultaneous observations of the target and the background (or reference), which is the key for target sighting under varying environmental lighting. The angular resolution of the human eye is ~ 0.5 arcmin (equivalent to a spatial resolution of ~ 0.2 mm from a distance of 1 m) (Clark, 1990, Curcio et al., 1990). This is equivalent to a digital camera with ~ 600 Megapixels, thus enables the collection of radiance at very fine resolutions, which is why we can see fine details of a target and how we can read. Due to this extremely fine resolution of the human eye, the relationship between the pixel size of the collected image and the size of a target will depend on the distance (z) and the size of the target (d, see Fig. 1). In the water ZSD is often several tens of meters, resulting in a pixel size of several millimeters. Thus, a Secchi disk is much larger than the pixel size and can no longer be considered as a point source. Consequently, the radiance distribution over a Secchi disk could be very different from that over the nearby background. This unique feature and phenomenon are demonstrated in Fig. 2 for a black-and-white disk in water pictured with a digital camera ~ 1 m above the disk. For a point (B) over the disk and a point (A) in the adjacent water (both at same depth), their surrounding light (represented by the brown dashed line above each letter in the right side of Fig. 2) are L'T(z, B) and L'w(z, A), respectively. Because the radiance distribution is generally not uniform at a given depth (especially for depths closer to the target) due to the intrusion of this target, there is in general:(12)L'TBz≠L'wAz. 1. Download : Download high-res image (323KB) 2. Download : Download full-size image Fig. 2. (left) An alternating-black-and-white Secchi disk in blue water observed vertically. (right) Variation of radiance (digital counts) for pixels on the black lines of the Secchi disk image. Points A and B indicate likely locations for judgment decisions on whether the disk is still discernable by a human eye, with the brown dashed lines indicating the range of radiance that could be used in Eq. (3) for integrations. Radiance within the green circles indicates those outside of the overlap that are used in Eq. (3). Note that the digital camera was saturated for radiance over the white portion of the disk, while the radiance over the black portion of the disk increases towards the center due to adjacent contributions from the white portion of the disk. Radiance at the center of the disk is omitted due to interference of the holding string. Therefore Eq. (3) is not always true for a Secchi disk or large objects, especially for depths closer to the target (Aas et al., 2014). One exception is when points A and B are two adjacent pixels (such as a point-source target, or when B is at the edge of a finite-size target while A is an adjacent water pixel), the two brown dashed lines will approach each other and the approximation of Eq. (3) could then be valid. The sighting of a Secchi disk in water, however, is generally not determined based on the contrast between its edge and the adjacent water, but rather based on the detection of any portion of the disk that has the highest contrast from the background. In general the distance between points A and B is likely 10's to 100's of pixels. In these cases, after subtracting the overlapping potions of L'T(z, B) and L'w(z, A), an exact Eq. (4) in the above derivations for points A and B would be:(13)dLTzB−LwzAdz=−cLTzB−LwzA+∫ζL'TzBζβζdω−∫ξL'wzAξβξdω,with [ζ] and [ξ] representing the residual solid angles outside of the overlapping range between points A and B, shown as the circled portions in the right side of Fig. 2. We may further divide the radiances within [ζ] and [ξ] as the upward and downward radiances following Zaneveld (1995). Because downward radiance is mainly determined by incident light, L'T(z,B,ζd) is approximately L'w(z,A,ξd). For upward radiance, L'T(z,B,ζu) and L'w(z,A,ξu) contribute to LT(z,B) and Lw(z,A), respectively, through forward scattering (Zaneveld, 1995). Therefore, Eq. (13) can be written as(14)dLTzB−LwzAdz=−cLTzB−LwzA+εbfLTzB−LwzA,which further leads to a more generalized equation for contrast propagation(15)LT0−Lw0=LTz−Lwze−c−εbfz. The value of parameter ε depends on the distance (i.e. size of the target) between points A and B. For a small target, ε approaches 0, and contrast propagation follows the beam attenuation coefficient; for a large target, because of contributions from forward scattering of adjacent pixels within the target, ε is greater than 0 and the attenuation of contrast no longer follows the beam attenuation coefficient. This dependence of attenuation on target sizes is consistent with conclusions regarding image propagation through a media (Hou et al., 2007, Wells, 1973a, Wells, 1973b), where the attenuation of high-spatial-frequency images (small objects or narrow beam) follows c (which is the sum of absorption and scattering coefficients) while the attenuation of low-spatial-frequency images (large objects or broad beam) follows the sum of absorption coefficient and a portion of the scattering coefficient (Wells, 1973a, Wells, 1973b). In short, for visual ranging of a target in water or air, if the size of the target is much larger than the spatial resolution of a human eye, Eq. (3) is not necessarily valid, the Law of Contrast Reduction (Eq. (8)) could not be derived, and then visibility models (Eqs. (10), (11)) based on this theory may not be appropriate. Such a caveat associated with the CVT can also be explained as follows. If Eq. (5) is valid, mathematically it will lead to,(16)LT0−LTze−cz=Lw0−Lwze−cz. For this to be satisfied for any c and z, the following relationships must be true,(17a)LT0=LTze−cz+Xz,(17b)Lw0=Lwze−cz+Xz. Here X(z) is a function of z (such as the path radiance between depth z and surface) and becomes 0 when z is 0. Radiative transfer theory tells us that Eq. (17a) is valid only for a point source or small target. This caveat associated with the contrast attenuation of a Secchi disk in the CVT could be the fundamental reason why many studies have shown that the estimated ZSD based on the classical theory agree poorly with observations (Bowers et al., 2000, Doron et al., 2011, Morel, Huot, et al., 2007, Zhang et al., 2014). Instead of questioning the assumptions behind the theory, the discrepancies between the modeled and observed ZSD were often implicitly attributed to measurement errors or algorithms to estimate the IOPs. In addition, there have been numerous reports showing c-based empirical models of ZSD (Aas et al., 2014, Bukata et al., 1988, Davies-Colley and Vant, 1988, Devlin et al., 2008, Gallegos et al., 2011, Holmes, 1970, Megard and Berman, 1989). Although strong correlations (R2 ~ 0.9 in general) were presented for each dataset, the slopes between the modeled and measured ZSD show a rather wide range of variations even for measurements of nearby lakes obtained by the same researchers (e.g., Bukata et al. (1988)). Sometimes for data from the same group, the measurements of ZSD < 2 m have to be excluded in order to obtain a good fit with the c-based formula (Aas et al., 2014). These results indicate further that there does not exist a single and globally applicable relationship between ZSD and c (or c + Kd as c is ~ 2–5 times or more larger than Kd) for global waters (Gordon, 1978). This non-uniformity, again, could be mainly due to the assumption of Eq. (3). The sighting of a black disk horizontally just below the surface may be a special case (Davies-Colley and Vant, 1988, Zaneveld and Pegau, 2003). In this scenario, while the distance between points A and B could still be relatively wide (compared to eye resolution), the approximation of Eq. (3) might still be valid. This may occur because most of the surrounding light over the target and the background are strong radiances in the horizontal directions as demonstrated with field observations (Zaneveld and Pegau, 2003). 2.2.2. CONTRAST FOR VISUAL JUDGMENT (CI AND CA) In the CVT, the contrast for visual judgment (Ci and Ca) is defined as a relative difference of radiance (or reflectance) between the target and the background or reference (Eq. (6) or Eq. (9)) (Aas et al., 2014, Duntley, 1952, Preisendorfer, 1986, Zaneveld and Pegau, 2003). This definition and application of contrast provide a good measure of the sharpness of a picture, but is subjective to the use of “background” or “reference” and may result in false prediction of target sighting as the maximum Ci value is infinite. For instance, for an alternating-black-and-white disk (usually used in limnology studies), the Ci value approaches infinite when the black side is considered as the background or reference. With this formulation for contrast the Secchi disk should be detectable even at hundreds of meters deep as the calculated apparent contrast (Eq. (8)) would still be greater than the eye threshold. Or, for a white cup filled with black coffee, the white bottom of the cup should be always viewable regardless of the cup's depth as Ci approaches infinite when the black coffee is considered as the background. Such contradictions can be further demonstrated with a hypothetical scenario. Assuming a 90-m deep bottom under clear waters (e.g., those in the Caribbean) and the bottom is sharply divided into two sides with different bottom types, one side is black bottom (near 0 reflectivity) and the other side (the target) is quartz sand bottom (50% reflectivity). The water has a chlorophyll concentration ([Chl]) of 0.1 mg/m3 and all optical properties following the Case-1 scheme (Morel & Maritorena, 2001). Fig. 3 shows the subsurface radiance reflectance (r, sr− 1) of the two sides simulated by Hydrolight (Mobley & Sundman, 2013), along with Ca calculated between the two sides following Eq. (6). Value of Ca (see Fig. 3) in the spectral window around 490 nm is ~ 0.9% (contrast becomes ~ 0.2% when using spectrally-integrated luminance), which jumps to ~ 5.5% if the bottom is uplifted to 70 m (contrast becomes ~ 1.4% when using spectrally-integrated luminance). These values are around or higher than the 0.66% threshold for detection by the human eye as suggested for Secchi disk sighting (Højerslev, 1986, Preisendorfer, 1986, Tyler, 1968). However, such visual sightings have never been reported in the literature or news. In contrast, reports for sighting bright bottoms in clear waters are in the range of 20–30 m. In addition, these Ca values are much smaller than that would be predicted by Eq. (8) as the inherent contrast between the two sides approach infinite with the black side as the background. 1. Download : Download high-res image (180KB) 2. Download : Download full-size image Fig. 3. An example showing how the contrast evaluation in classical underwater visibility theory would result in likely false prediction of detecting a half-bright–half-black bottom in deep clear waters. The y-axis to the left shows the radiance reflectance of clear waters just below the surface (r(0 −), sr− 1) with a highly reflecting quartz (solid circle) and black (open circle) bottom at 90 m depth. The y-axis to the right shows the apparent contrast (Eq. (6), square symbol). Open square represents the apparent contrast if the quartz/black bottom is uplifted to 70 m. Fundamentally, target sighting by the eye-brain system depends on where there is sufficient difference in the radiance (or brightness) between the target and the background (reference) when there is no difference in color (Blackwell, 1946). This difference in radiance changes with both the incident light and the difference in reflectivity between the target and the background. On the other hand, the sensitivity of the human eye also adapts to the intensity of the ambient light. Therefore, what really matters for this judgment decision under the photopic vision regime (i.e., light intensity is in a range of usual indoor to outdoor light) is the difference in reflectivity between the target and the background, or the so called “brightness constancy” concept of visual perception (Bartleson and Breneman, 1967, Freeman, 1967). Specifically, it means “… judgments of brightness have been shown to be dependent not on the quantity of light entering the eye, but rather on the reflectance of the surface from which luminous energy is reflected” (Freeman, 1967). This is why we perceive a black–white checker board nearly the same under either sunshine or tree shadows. The definition and application of relative difference in radiance or reflectance as the contrast in the CVT, however, is not consistent with the “brightness constancy” concept in visual perception. It is following this brightness constancy concept that a new theory for underwater visibility is formulated. 3. NEW THEORY FOR UNDERWATER VISIBILITY The ultimate goal of a generalized visibility theory is to express parameter ε in Eq. (15) as a function of both target size and distance for any light illumination conditions. This will require not only complex derivations based on radiative transfer, but also sophisticated and carefully designed field experiments for different objects under various conditions. Here the problem is simplified to Secchi disks only and viewed vertically by a human eye in the photopic vision regime. As discussed in details in Section 2, a regular Secchi disk (~ 30 cm in diameter) in the viewable range in water is significantly larger than the size of an image pixel of a human eye (generally d/Z > > angular resolution and within the FOV of a human eye), thus we may consider this target as a large bottom for the array of tiny sensors of a human eye when observed vertically at surface (see Fig. 1). The upwelling radiance just below the surface from pixels within such a target can then be considered to follow the relationships established for optically shallow waters (Albert and Mobley, 2003, Lee et al., 1998, Lyzenga, 1981, Philpot, 1989, Voss et al., 2003)(18)LT0−=rwEd0−1−e−Kd+KTz+rTEd0−e−Kd+KTz. Here LT(0 −) represents the radiance signal (after integration from the target depth to surface) reaching the eye system, with Ed(0 −) the incident downwelling irradiance just below the surface. rT and rw are the radiance reflectance of a Secchi disk and background water, respectively. Kd (m− 1) is the depth-averaged diffuse attenuation coefficient of plane downwelling irradiance, while KT (m− 1) is the depth-averaged diffuse attenuation coefficient of the upwelling radiance arising from the target reflection. Here wavelength dependence is omitted for brevity unless it is necessary. For adjacent water pixels (outside the glow of the disk where the adjacency effect is minimal) that serve as the background, the total upwelling signal just below the surface is(19)Lw0−=rwEd0−. Because visual perception of a target by the human eye is based on the detection of enough difference in brightness (radiance) and/or color between the target and the reference (Blackwell, 1946), the contrast in radiance reaching a human eye is calculated as(20)LC0−=LT0−−Lw0−. Applying Eqs. (18), (19), Eq. (20) becomes(21)LC0−=rT−rwEd0−e−Kd+KTz. This expression is conceptually consistent with Eq. (15) for contrast attenuation as generally the diffuse attenuation coefficient is a function of total absorption and backscattering coefficients (Gordon, 1989, Lee et al., 2005). Similarly (c − ε bf) of Eq. (15) also represents a function of total absorption and backscattering coefficients as ε approaches 1 for large targets (Wells, 1973a, Wells, 1973b). 3.1. SECCHI DISK DETECTION BY A HUMAN EYE: SPECTRAL INFORMATION OF A TARGET Detection of a target by the eye–brain system uses both intensity and color contrast. In particular, a human eye can distinguish millions of colors in the visible domain (Judd & Wyszecki, 1975), which translates to thousands of spectral bands in the 400–700 nm range with each band at 1-nm bandwidth. For sighting a target in air, while the relative contribution of light from the target will decrease at each wavelength with the increase of distance, this reduction is nearly the same across the visible domain, i.e. there will be little change in the apparent color of the target at distance. In short, the transmittance in air is spectrally neutral (except for the narrow absorption bands of atmosphere gases or smokes) in general, and this spectral neutrality remains nearly the same for different visibility ranges. Consequently photometric (brightness) quantities are used for the evaluation of contrast for a white or black target in air, and this approach was adopted in the classical underwater visibility theory (Preisendorfer, 1986, Zaneveld and Pegau, 2003). Because of the spectrally selective nature of the absorption and scattering properties of water constituents (Kirk, 1994, Mobley, 1994), however, spectral quality is no longer the same for observing a target in water. When a Secchi disk is lowered in water and observed by a human eye at the surface, the relative contribution of light from the Secchi disk will decrease with the increase of depth. This reduction, however, is strongly spectrally dependent and photons reflected by the Secchi disk that reach a human eye very quickly narrow to waters' spectrally transparent window. In short, when a Secchi disk is lowered deeper and deeper, there are changes in both brightness and color between the area containing the Secchi disk and the adjacent water, and eventually the difference in color diminishes (Aas et al., 2014) and the contrast in brightness at this color (wavelength) becomes below the detection threshold of a human eye. This phenomenon is illustrated in Fig. 4, where Fig. 4a shows the change of spectral radiance with increasing Secchi disk depth (simulated with Eq. (18)), while Fig. 4b shows the corresponding colors in CIE chromaticity diagram (Mobley, 1994) perceived by a human eye and the dominant wavelengths. For clear water ([Chl] = 0.1 mg/m3) with the disk 5 m below the surface, there is not only a strong difference in radiance (brightness) between the target and the background, but also a rather big difference in color, with the target and the background centered at 486 nm and 478 nm, respectively. When the disk gets to 40 m below the surface (a depth approaching the limitation of detection), the difference in radiance (brightness) between the target and the background is significantly reduced, and the color of the target (479 nm) approaches that of the background (478 nm). It is therefore reasonable to hypothesize that the detection of a Secchi disk in water by a human eye depends on the contrast of brightness in the spectral window of the perceived water color; whereas this spectral window changes significantly from water to water. Experimental proof of this hypothesis is beyond the scope of the current work as it would require sophisticated equipment and field-based measurements in different water environments. However, such a hypothesis is supported by the results shown later. 1. Download : Download high-res image (153KB) 2. Download : Download full-size image Fig. 4. Illustration of changes of brightness (radiance) and color when a Secchi disk is lowered in deep blue water, where the color difference between the two disappears when the disk is approaching 40 m. (a) Spectral radiance (Lw) of the water without the Secchi disk (“deep” in the legend, [Chl] = 0.1 mg/m3) and spectral radiance of the water area containing a Secchi disk (with a reflectance as 0.85) at different depths (modeled with Eq. (18)). All are under a clear sky with the Sun at 30° from zenith. (b) The perceived colors by the human eyes and their dominant wavelengths (annotated with circles) for the corresponding radiance spectra on the left. Here the x- and y-axes represent the two normalized values of the three tristimulus values. Note that when the disk is 40-m deep the wavelength (479 nm) corresponding to the human perceived color is very close to the wavelength (478 nm) from the nearby waters (the background). The background CIE chromaticity diagram is a courtesy of Wikipedia. The contrast of brightness at the wavelength corresponding to the color perceived by a human eye when the Secchi disk starts to disappear can be written as(22)NCpc0−=rT−rwpcHdpc0−e−Kdpc+KTpcz. Here NC represents the contrast in luminance recorded by a human eye, Hd is the equivalent input illuminance, and the superscript “pc” stands for the perceived color by a human eye and each color is associated with a specific wavelength (see Fig. 4). Kdpc and KTpc in Eq. (22) are the depth-averaged diffuse attenuation coefficients of the downwelling plane irradiance and upwelling radiance arising from the target reflection at the wavelength of the perceived color, respectively. Because there have been no measurements or studies of Kd specifically for the human eye perceived color, we rely on the modeling of Kdpc for waters with a wide range of chlorophyll concentrations (see Appendix A for details of this modeling). It is found that Kdpc can be well represented by the minimum Kd within the visible domain (400–700 nm) (see Fig. 5), which is the attenuation coefficient of the transparent window of the water column (Kdtr). We use this diffuse attenuation coefficient to approximate Kdpc and KTpc, respectively, in the following for easy computation, and rewrite Eq. (22) as,(23)NCpc0−=rT−rwpcHdpc0−e−Kdtr+KTtrz,with Kdtr and KTtr the depth-averaged diffuse attenuation coefficient of the downwelling irradiance and upwelling radiance arising from the target reflection at the transparent window of the water, respectively. 1. Download : Download high-res image (87KB) 2. Download : Download full-size image Fig. 5. Relationship between diffuse attenuation coefficient at the wavelength of the perceived color (Kdpc) and diffuse attenuation coefficient of the transparent window (Kdtr) for waters with [Chl] as 0.03, 0.1, 0.3, 1, 3, 10, and 30 mg/m3. Details of the simulations are provided in Appendix A. These results suggest that Kdpc can be approximated by Kdtr for the interpretation of Secchi disk depth. 3.2. SECCHI DISK DETECTION BY A HUMAN EYE: CONTRAST FOR JUDGMENT DECISION Detection of a target by a human eye requires that NC is greater than a threshold. On the other hand, this threshold also varies with the intensity of ambient light (Blackwell, 1946), thus a more applicable evaluation of the contrast for the target detection is the ratio of NC to Hd. This is consistent with the “brightness constancy” concept for visual perception under the photopic vision regime (Bartleson and Breneman, 1967, Freeman, 1967). Therefore a new apparent contrast (Can, sr− 1) is defined as(24)Can=NCpc0−Hdpc0−. Applying Eq. (23) we obtain(25)Can0−=rT−rwpce−Kdtr+KTtrz. This further leads to a new Law of Contrast Reduction for sighting a Secchi disk as(26)Can=Cine−Kdtr+KTtrz,with Cin the new inherent contrast and defined as(27)Cin=rT−rwpc. Compared to the contrast evaluation in the CVT (Eq. (9)), now the contrast is evaluated as the absolute difference in reflectance between the target and the background (or reference). With such a formulation, the maximum value of Cin is limited by the reflectance of the target or the background. For an alternating-white–black disk as that usually used in limnology studies, the inherent contrast will then become rT of the white side when the black side is considered as the reference (assuming black side has a reflectance as 0). This value is just slightly larger than the contrast between the white disk and the water, which then explains why the observed ZSD were nearly the same between using completely white disks and using alternating-white–black disks. In the following, since reflectance in a narrow spectral band is the same for both radiometric and photometric quantities, radiometric quantities are employed for the derivation and discussion of Secchi disk depth. 3.3. NEW MECHANISTIC MODEL FOR SECCHI DISK DEPTH When Can matches the contrast threshold (Ctr(0 −), sr− 1, i.e. measured in sub-surface radiance reflectance) for target detection by the eye-imager, the maximum detectable distance of this disk in the vertical direction or vertical visibility (Duntley, 1952) becomes(28)ZSD=1Kdtr+KTtrlnrT−rwpcCtr0−. The diffuse attenuation coefficient (Kd) is generally a function of IOPs and solar elevation (Gordon, 1989, Lee et al., 2005). For easier data processing, considering KTtr ≈ 1.5 Kdtr for the upwelling radiance arising from the reflection by a Lambertian bottom and for the Sun high above the horizon (Kirk, 1991, Lee et al., 1994, Lee et al., 1998), Secchi disk depth described by Eq. (28) can be approximated as(29)ZSD=12.5KdtrlnrT−rwpcCtr0−. Eqs. (26), (27), (28) form the core of the new underwater visibility theory and mechanistic models to interpret Secchi disk depth. Compared to the CVT, the new visibility theory provides a mechanistic explanation for the numerous observations over the past many decades that there is a strong inverse relationship between ZSD and the diffuse attenuation coefficient (Holmes, 1970, Kratzer et al., 2003, Megard and Berman, 1989, Padial and M.Thomaz, 2008). Also, with the new visibility theory and model the bottom of a regular-size white cup filled with black coffee or a 70-m deep half-bright–half-black bottom in clear waters will not be detectable under the photopic vision regime (because the inherent contrast is now limited), which is consistent with our observations. 4. VERIFICATION OF THE NEW MODEL WITH INDEPENDENT MEASUREMENTS The establishment of the new visibility theory and its associate model (Eqs. (28), (29)) is based entirely on radiative transfer theory. In addition to the above theoretical arguments, their ultimate verification requires concurrent measurements of visibilities and water optical properties (spectral rw, Kd and KT) over a wide dynamic range of environments. This is a prerequisite rarely met. However, by searching the SeaWiFS Bio-optical Archive and Storage System (SeaBASS) database, a dataset with 144 measurements containing both ZSD and Rrs(λ) was found for waters around the USA, with Rrs (sr− 1) being the above-surface remote-sensing reflectance (Mobley, 1999). In addition, a total of 197 data points having both ZSD and Rrs were compiled from measurements of oceanic and coastal waters off China (Shang et al., 2011). This combined dataset covers oceanic, coastal, and lake waters (see Fig. 6a for locations), where ZSD ranges between 0.1 and 30 m and Rrs values are provided at 412, 443, 488, 532, 555 and 665 nm, with measurements conducted independently by many research groups. 1. Download : Download high-res image (662KB) 2. Download : Download full-size image Fig. 6. (a) Locations of field measurements, with data obtained from NASA's SeaBASS archive and measured in oceanic and coastal waters off China. (b) Comparison between measured and predicted vertical visibility with the mechanistic model (and its coefficients) developed following the new underwater visibility theory. The three red points were considered as outliers (the measured reflectance of these points are extremely different from those of waters with identical or similar ZSD values) and were excluded in the model verification. If included, the mean absolute percent difference increases from 18.2% to 19.3%. Because Secchi disk depth was determined from viewers above the surface, the radiance contrast in air (LCtr) must be used, which is written as(30)LCtr0+=tn2LTtr0−+LT−skytr−tn2Lwtr0−+Lw−skytr. Here t is the radiance transmittance across the water-air interface and n is the refractive index of seawater; while LT − skytr and Lw − skytr are the surface-reflected skylight of the target and the reference areas in the transparent window of water, respectively. Assume LT − skytr and Lw − skytr are the same during the observations, after converting the radiance contrast to reflectance contrast (i.e., divided by Edtr(0 +), and note that Edtr(0 −) = t Edtr(0 +)), there is(31)Can0+=t2n2rT−rwpce−Kdtr+KTtrz. Lastly the visibility equivalent to Eq. (29) for an above-surface observer is(32)ZSD=12.5Kdtrlnt2n2rT−rwpcCtr,with Ctr (sr− 1) the detection threshold of the human eye in air. To obtain the required Kd information for the estimation of ZSD, the Rrs values were first fed to the latest version (http://www.ioccg.org/groups/software.html) of the Quasi-Analytical Algorithm (Lee, Carder, & Arnone, 2002) to obtain total absorption (a) and backscattering (bb) coefficients. Subsequently Kd at 443, 488, 532, 555 and 665 nm were derived from a and bb following the IOP-based model (Lee et al., 2005, Lee et al., 2013) by assuming a nominal 30° for solar zenith angle. The minimum Kd for wavelengths between 443 nm and 665 nm (the visible domain) was used to represent Kdtr in Eq. (32). Further, rw can be converted to Rrs following Lee et al. (2002), and Rrspc was taken as the Rrs value corresponding to the wavelength with minimum Kd. Considering the disk is white with RT = 0.85 (Preisendorfer, 1986, Tyler, 1968), rT is RT/π ≈ 0.27 sr− 1. Also, t2/n2 approximates 0.54 for oceanic waters (Austin, 1974, Mobley, 1994), Eq. (32) then becomes(33)ZSD=12.5MinKd443,488,532,555,665ln0.14−RrspcCtr. The threshold contrast (Ctr) for sighting a white Secchi disk was determined based on the measurements of Blackwell (1946). In that experiment, the difference in brightness (radiance) between the target (BT) and the background (B0) was calculated as(34)ΔB=BT−B0. The threshold ΔB was determined at the point when 50% of participants reported loss of sight of the target. Because the sensitivity of human eyes is adaptable to ambient light, ΔB is not a constant but rather changes with the surrounding light intensity. Following the “brightness constancy” concept (Freeman, 1967), the threshold of contrast in reflectance can be calculated as(35)Ctr=BT−B0Es,with Es representing the irradiance of surrounding light. In the experiments, because a majority of the ambient light came from the background screen (which occupies ~ 5° of the FOV of the human eye), the value of Es approximated the value of B0 (where the difference between BT and B0 is very small at the detection threshold) (Blackwell, 1946). The resultant Ctr values are nearly the same for 3–4 orders of magnitude change in the ambient light for a given target size under the photopic vision regime (see Table 8 of Blackwell (1946)), which is consistent with the “brightness constancy” concept. The replacement of Es by the values of B0 is appropriate for this experimental setting (Blackwell, 1946), but may not be valid over all observations in the field as ambient light does affect the adaptation of the human eye. The use of B0 instead of Es by Blackwell (1946) may also be the reason why researchers followed this approach to evaluate contrast for visual ranging (Eqs. (6), (9)). For Secchi disk sighting, where at least a few pixels of the target are required to make a judgment decision on detection, an average (0.013 sr− 1) was obtained using the measured Ctr values for sizes between 3.6 and 9.68 arcmin and for illumination between 10 and 1000 Footlambert (equivalent range is between 34 and 3400 Cd/m2, for the photopic vision regime). This average is then used for Ctr in Eq. (33), and a comparison between the measured ZSD and the Eq. (33) calculated ZSD is shown in Fig. 6b. For this independent ZSD dataset where ZSD is in a range of ~ 0.1 to 30 m (N = 338, 3 points were excluded as outliers, see Fig. 6b), the mean absolute relative difference between the estimated and measured ZSD, defined as the arithmetic average of 2*|ZSD-est − ZSD-mea|/(ZSD-est + ZSD-mea) from all data pairs, is 18.2%. Linear regression yields a coefficient of determination (R2) of 0.96, with a slope of 1.04 and intercept of ~ 0.2 m (see Fig. 6b). Considering that the 18.2% absolute relative difference includes both uncertainties in field-measured ZSD (typically ~ 10% or more) and uncertainties in Kd derived from non-perfect Rrs (Lee et al., 2013), this performance suggests that the new model for ZSD (which includes approximations of Kdpc = Kdtr and KTtr = 1.5 Kdtr) is excellent. In particular, in such a validation, the model and its parameterization are completely independent from the measurements covering different regions, thus the results indicate plausible interpretation and estimation of Secchi disk depth and the model's applicability for global waters. This agreement in ZSD also indirectly supports the hypothesis that due to the spectrally-selective attenuation by the water body the eye–brain system likely uses a narrow band associated with the maximum contrast for the detection of a Secchi disk. Furthermore, it is found that the logarithm term on the right side of Eq. (33) is within a narrow range (2.38 ± 0.03) for such a wide range of waters, which indicates that, as a rule of thumb, Secchi disk depth in water approximates(36)ZSD~1Kdtr. Interestingly, this is similar with the penetration depth for ocean color remote sensing (Gordon & Mcluney, 1975). 5. DISCUSSION AND CONCLUSIONS Given the excellent agreement between the model (together with its parameterization) predictions from the new theory and the independent visibility measurements from a wide range of environments, it is clear that the new theoretical model regarding Secchi disk depth is plausible. This robust performance is further supported through evaluating the diurnally varying ZSD observed in the field (see Fig. 7). Because Kd varies with sun angle (Gordon, 1989, Kirk, 1984, Lee et al., 2005), the new model provides a consistent explanation of diurnal changes in ZSD (assuming no change of water properties), whereas the classical theory could not predict such a variation because c is an IOP and c is significantly larger than Kd. However, it is desired and necessary to carry out more, especially controlled, measurements of ZSD, IOPs, and Kd with changing incident angles for such evaluations. In particular, narrow-band filters should be used to evaluate the sensitivity of human eyes to contrasts in different colors (i.e., wavelengths) in the real aquatic environments together with these measurements. 1. Download : Download high-res image (120KB) 2. Download : Download full-size image Fig. 7. Diurnal variation of Secchi disk depth. (Black) Ratio of ZSD(0°) to ZSD(θ) for measurements made in Garner Lake, TN (Verschuur, 1997), with data visually interpreted (average of five persons) from Fig. 3 of Verschuur (1997) and ZSD(0°) extrapolated from observations around 10°–20°. (Blue) Predicted ratio of ZSD(0°) to ZSD(θ) based on Eq. (10) (the classical theory), which is an average (along with standard deviation) for chlorophyll-a concentration 0.5, 1.0, and 3.0 mg/m3, respectively. For each chlorophyll-a concentration, the IOPs were simulated following the hyperspectral model of Lee et al. (1998), and a backscattering efficiency of 0.015 was used to convert particle backscattering coefficient to total scattering coefficient. (Green): Predicted ratio of ZSD(0°) to ZSD(θ) based on Eq. (29) (the new model), also an average (along with standard deviation) for chlorophyll-a concentration as 0.5, 1.0, and 3.0 mg/m3, respectively. IOPs used in the new theory were the same as those for the classical theory, and spectral Kd was modeled following Lee et al. (2013). The new theoretical interpretation of Secchi disk depth provides a more generalized view of visual ranging of “large” objects (but within the field-view of a human eye), while the subsequent mechanistic model for ZSD will have profound implications on remote sensing of water transparency and on studies of aquatic environments. First, because ZSD is a function of Kd, analytical remote sensing of water transparency on a global scale via ocean color remote sensing is now possible because spectral Kd is a standard data product of satellite ocean color missions. In contrast, ZSD mainly depends on c in the classical theory, where c is impossible to be analytically derived from passive remote sensing (Gordon, 1993) unless it is highly correlated with Kd. Note that water transparency has direct impact on a wide range of biogeochemical processes (e.g., photosynthesis, photo-oxidation, etc.) and bottom substrates such as coral reefs and sea grasses (Chen et al., 2007, Letelier et al., 2004, Sathyendranath and Platt, 1988, Vodacek et al., 1997, Weeks et al., 2012, Yentsch et al., 2002, Zimmerman, 2006). In the past and present, usually this is done via empirical tuning of regional ZSD algorithms (Chen et al., 2007, Gallegos et al., 2011, Kratzer et al., 2003, Stock, 2015), but there is always a challenge to define the spatial and temporal limitations of such local or regional algorithms. Further, in the past when modern instruments were not widely available for optical measurements of natural waters, ZSD was the standard measurement for a wide range of waters, with a large volume of data collected and archived (Boyce et al., 2012). The availability of such data and the mechanistic model developed here make it possible to derive new and robust remote sensing products to study global changes since the late 1970s. Such a task has been notoriously difficult to accomplish with other data products (e.g., chlorophyll-a concentration) due to the scarcity of measurements in the 1970s and 1980s, and contrary conclusions were sometimes reached from the same satellite ocean color measurements (Antoine et al., 2005, Gregg et al., 2005). Finally, there is a vast warehouse of in-situ data being collected through Citizen Science Projects (e.g., the Secchi Dip-In, http://www.secchidipin.org/index.php/monitoring-methods/; the Secchi APP, http://www1.plymouth.ac.uk/marine/secchidisk/Pages/default.aspx), thus the robust mechanistic model developed here provides a strong base to link these measurements with satellite estimations and the ability to compare the quality of various water bodies. There have been numerous studies trying to link the attenuation coefficient of the photosynthetically available radiation (KPAR, m− 1) with ZSD, from which a wide range of empirical relationships have been reported (Bukata et al., 1988, Effler, 1988, Hojerslev and Aarup, 2002, Holmes, 1970, Padial and M.Thomaz, 2008, Poole and Atkins, 1929, Tyler, 1968). This lack of algorithm uniformity via KPAR is a result of two factors: (1) Visual ranging in water likely measures light in the spectrally transparent window, where KPAR does not provide such information. Actually the contribution of Kdtr to KPAR is secondary compared to the contributions from other wavelengths that have higher attenuation coefficients (e.g., 600–700 nm in oceanic waters; 400–500 nm for coastal turbid waters), and; (2) because KPAR strongly depends on the depth range used for its calculation (Lee, 2009, Megard and Berman, 1989, Morel, 1988), there are large ambiguities in the measured and reported KPAR values. Therefore, to model ZSD of global waters as a function of KPAR is not supported from the radiative transfer point of view. In conclusion, due to the neglect of the target size and the doubtful use of contrast evaluation for visual judgment by the human eye, the century-old classical underwater visibility theory is found questionable in interpreting Secchi disk depth. The new theory tries to resolve both elements, resulting in a new Law of Contrast Reduction and a new mechanistic model to explain and predict Secchi disk depth, which is further validated and supported using data independently collected from a wide range of aquatic environments. Although the ultimate proof of the new theory regarding ranging of an under-water target by a human eye would require carefully designed field experiments, the mechanistic model developed here is expected to significantly improve the monitoring of water transparency of global waters via ocean color remote sensing and the findings here would expand our understanding of underwater visibility and visual ranging in general. ACKNOWLEDGMENTS We are in debt to all scientists who provided the valuable field data for community use. Financial support was provided by the National Natural Science Foundation of China (No. 41376177, Shang; No. 41471284, Du) and Ministry of Science and Technology of China (No. 2013BAB04B00, Shang), the National Aeronautic and Space Administration (NASA) (NNX14AK08G, NNX14AQ47A, NNX14AM15G) Ocean Biology and Biogeochemistry and Water and Energy Cycle Programs (Lee, Hu), the National Oceanic and Atmospheric Administration (NOAA) (DG-133E-12-SE-1931) JPSS VIIRS Ocean Color Cal/Val Project (Lee, Hu), Office of Naval Research (PE 0602435N, Hou, Weidemann), and the University of Massachusetts Boston (P20120000019675). Comments and suggestions by Curt Mobley and Ron Zaneveld greatly improved this manuscript. APPENDIX A. AN ILLUSTRATION OF THE RELATIONSHIP BETWEEN KDPC AND KDTR Following the radiative transfer theory, it has been found that the depth-averaged diffuse attenuation coefficient of downwelling plane irradiance can be expressed as (Gordon, 1989, Lee et al., 2005)(A1)Kdλ=faλ,bbλ,θSwith θS being the solar zenith angle. a and bb are the absorption and backscattering coefficients, respectively, and can be expressed as (Mobley, 1994)(A2)aλ=awλ+aphλ+adgλ,(A3)bbλ=bbwλ+bbpλ. Here the subscripts “w, ph, dg” represent water molecules, phytoplankton pigments, and the combination of detrital particles and gelbstoff, respectively; and bbp represents backscattering coefficient of particulates. aw and bbw spectra are known (Morel, 1974, Pope and Fry, 1997) and considered constants. aph spectrum in the visible domain (5-nm resolution) can be modeled as a function of aph(440) (Lee et al., 1998) while aph(440) can be modeled as a function of [Chl] (Bricaud, Babin, Morel, & Claustre, 1995)(A4)aph440=0.05Chl0.65. Spectral adg can be expressed as an exponential-decay function of wavelength with a spectral slope as 0.015 nm− 1 (Bricaud et al., 1981, Carder et al., 1989) and adg(440) was considered equal to aph(440) in the simulations (Morel, Claustre, et al., 2007, Morel and Maritorena, 2001). Spectral bbp can be modeled as (Gordon & Morel, 1983)(A5)bbpλ=bbp440440λ,and bbp(440) was modeled as the following (Gordon and Morel, 1983, Loisel and Morel, 1998) after considering a 1.5% backscattering/scattering ratio(A6)bbp440=0.006Chl0.6.a and bb spectra in the visible domain (5-nm resolution) were then modeled following the above descriptions for [Chl] as 0.03, 0.1, 0.3, 1, 3, 10, and 30 mg/m3, respectively. We further obtained spectral Kd for θS = 30° from zenith, and obtained Kdtr for each [Chl]. To obtain Kdpc for each [Chl], Lw spectrum was first calculated through Hydrolight (Mobley & Sundman, 2013) for each pair of spectral a and bb along with the Sun at 30° from zenith and a clear sky (with default atmospheric properties in Hydrolight). The Lw spectrum was then converted to a CIE color following the tristimulus calculations, and a corresponding wavelength was determined for the perceived color in the CIE chromaticity diagram (see Fig. 4 for examples). 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Despite decades of research, development, and demonstrations, currently, there is no operational model that enables the retrieval of Zsd from the rich archive of Landsat, the long-standing civilian Earth-observation program (1972 – present). Devising a robust Zsd model requires a comprehensive in situ dataset for testing and validation, enabling consistent mapping across optically varying global aquatic ecosystems. This study utilizes Mixture Density Networks (MDNs) trained with a large in situ dataset (N = 5689) from 300+ water bodies to formulate and implement a global Zsd algorithm for Landsat sensors, including the Thematic Mapper (TM), Enhanced Thematic Mapper Plus (ETM+), and Operational Land Imager (OLI) aboard Landsat-5, -7, -8, and -9, respectively. Through an extensive Monte Carlo cross-validation with in situ data, we showed that MDNs improved Zsd retrieval when compared to other commonly used machine-learning (ML) models and recently developed semi-analytical algorithms, achieving a median symmetric accuracy (ε) of ∼29% and median bias (β) of ∼3%). A fully trained MDN model was then applied to atmospherically corrected Landsat data (i.e., remote sensing reflectance; Rrs) to both further validate our MDN-estimated Zsd products using an independent global satellite-to-in situ matchup dataset (N = 3534) and to demonstrate their utility in time-series analyses (1984 – present) via selected lakes and coastal estuaries. The quality of Rrs products rigorously assessed for the Landsat sensors indicated sensor-/band-dependent ε ranging from 8% to 37%. For our Zsd products, we found ε ∼ 39% and β ∼ 8% for the Landsat-8/OLI matchups. We observed higher errors and biases for TM and ETM+, which are explained by uncertainties in Rrs products induced by uncertainties in atmospheric correction and instrument calibration. Once these sources of uncertainty are, to the extent possible, characterized and accounted for, our developed model can then be employed to evaluate long-term trends in water transparency across unprecedented spatiotemporal scales, particularly in poorly studied regions of the world in a consistent manner. * REGIONAL TO GLOBAL ASSESSMENTS OF OCEAN TRANSPARENCY DYNAMICS FROM 1997 TO 2019 2023, Progress in Oceanography Show abstract Water transparency, often quantified using the Secchi disk depth (Zsd), is a key parameter for assessing the water quality and ecological health in marine environments. However, a limited understanding of global Zsd dynamics over the past two decades exists. To assess the variations of ocean transparency over multiple timescales, the Ocean Colour Climate Change Initiative (OC-CCI) datasets are used to retrieve monthly global Zsd products during 1997–2019. On regional to global scales, significant Zsd variations on seasonal, interannual, and long-term timescales are identified. Seasonal and interannual variations of Zsd in most open oceans are found to be closely linked to phytoplankton dynamics and climate change. In the coastal zones, the Zsd variability is attributed to various physical and environmental factors, including seasonal monsoons, river outflow, sediment resuspension, eutrophication, etc. Moreover, the climatological seasonal Zsd variations of 22 typical ocean areas and the associated influencing factors are investigated on regional scales. The long-term trends of Zsd suggest the widespread expansion of oligotrophic waters within the North Pacific, North Atlantic, and South Indian Ocean gyres, indicating ongoing ocean desertification. The OC-CCI Zsd datasets can be used to build a merged centennial time series of Zsd in marine optics by linking to historical measurements. By relying on satellite-derived products, global and time-varying images offer a more comprehensive understanding of regional to global Zsd dynamics. * AN OPERATIONAL APPROACH FOR LARGE-SCALE MAPPING OF WATER CLARITY LEVELS IN INLAND LAKES USING LANDSAT IMAGES BASED ON OPTICAL CLASSIFICATION 2023, Environmental Research Show abstract Water clarity is a critical parameter of water, it is typically measured using the setter disc depth (SDD). The accurate estimation of SDD for optically varying waters using remote sensing remains challenging. In this study, a water classification algorithm based on the Landsat 5 TM/Landsat 8 OLI satellite was used to distinguish different water types, in which the waters were divided into two types by using the ad(443)/ap(443) ratio. Water type 1 refers to waters dominated by phytoplankton, while water type 2 refers to waters dominated by non-algal particles. For the different water types, a specific algorithm was developed based on 994 in situ water samples collected from Chinese inland lakes during 42 cruises. First, the Rrs(443)/Rrs(655) ratio was used for water type 1 SDD estimation, and the band combination of (Rrs(443)/Rrs(655) - Rrs(443)/Rrs(560)) was proposed for water type 2. The accuracy assessment based on an independent validation dataset proved that the proposed algorithm performed well, with an R2 of 0.85, mean absolute percentage error (MAPE) of 25.98%, and root mean square error (RMSE) of 0.23 m. To demonstrate the applicability of the algorithm, it was extensively evaluated using data collected from Lake Erie and Lake Huron, and the estimation accuracy remained satisfactory (R2 = 0.87, MAPE = 28.04%, RMSE = 0.76 m). Furthermore, compared with existing empirical and semi-analytical SDD estimation algorithms, the algorithm proposed in this paper showed the best performance, and could be applied to other satellite sensors with similar band settings. Finally, this algorithm was successfully applied to map SDD levels of 107 lakes and reservoirs located in the Middle-Lower Yangtze Plain (MLYP) from 1984 to 2020 at a 30 m spatial resolution, and it was found that 53.27% of the lakes and reservoirs in the MLYP generally show an upward trend in SDD. This research provides a new technological approach for water environment monitoring in regional and even global lakes, and offers a scientific reference for water environment management of lakes in the MLYP. * A2DWQPE: ADAPTIVE AND AUTOMATED DATA-DRIVEN WATER QUALITY PARAMETER ESTIMATION 2023, Journal of Hydrology Show abstract Accurate remote sensing estimation of inland water quality parameters (WQPs) plays a crucial role in guiding water resource management. To achieve this, researchers have explored various data-driven approaches utilizing machine learning (ML) techniques. However, there are two major challenges in WQPs estimation for inland waters. Firstly, current data-driven approaches focus on building a unified estimation model for an entire study area, which underestimates the complex dynamics of water constituents and optical properties. Secondly, ML models, particularly neural networks, require extensive hyperparameter tuning and are not user-friendly for researchers lacking relevant background and experience. In this paper, we propose an innovative method called adaptive and automated data-driven water quality parameter estimation (A2DWQPE) to address both challenges. Our method operates under the assumption that water bodies with similar spectral characteristics should share the same WQP estimation model. A2DWQPE is composed of three phases. Firstly, water types are automatedly classified by unsupervised hierarchical clustering according to spectral similarity. Then, optimal Deep Neural Network (DNN) models for estimating WQPs from multi-spectral satellite images are customized for each water type utilizing Bayesian optimization (BO). Finally, the target WQP is estimated based on the type-specific estimates and degree of membership of each water type. To evaluate the effectiveness of A2DWQPE, we applied it to estimate Secchi disk depth (SDD) in Lake Erie with in situ measurements and Moderate Resolution Imaging Spectroradiometer (MODIS) images. The results demonstrate that A2DWQPE outperforms the traditional approaches of developing a unified model for the entire study area. A2DWQPE achieved high accuracy with coefficient of determination (R2) over 0.72 and root mean square error (RMSE) below 1.4 m. Our method also outperforms the methods that applied Genetic Algorithm (GA) and Particle Swarm Optimization (PSO) instead of BO, and several traditional ML algorithms. We firmly believe that A2DWQPE holds great potential for accurate inland water quality estimation and will contribute significantly to various applications in water quality monitoring and pollution prevention. * RELATIVE IMPACT OF ENVIRONMENTAL VARIABLES ON THE LAKE TROPHIC STATE HIGHLIGHTS THE COMPLEXITY OF EUTROPHICATION CONTROLS 2023, Journal of Environmental Management Show abstract For the effective management of lakes apart from defining and monitoring their current state it is crucial to identify environmental variables that are mostly responsible for the nutrient input. We used interpretative machine learning to investigate the environmental parameters that influence the lake's trophic state and recognize their patterns. We analysed the influence of the 25 environmental variables on the commonly used trophic state indicators values: total phosphorus (TP), Chlorophyll-a (Chl-a) and Secchi depth (SD) of 60 lakes located in the Central European Lowlands. We attempted to delineate the lakes into groups due to the influence of common prevailing environment variable/variables on the water trophic state reflected by each indicator. The results indicated that the relative impact of environmental variables on the lake trophic state has an individual hierarchy unique for each indicator. The most important are variables related to catchment impact on the lake, Ohle ratio (L. catchment area/L. area) for TP and Schindler ratio (L. area + L. catchment area)/L. volume for Chl-a and SD. There are also few variables strongly influential only for small sub-groups of lakes that stand out: lake maximum depth, catchment slope steepness expressed by the height standard deviation. The methods used in the study enabled the assessment of the character of the influence of the environmental variables on the indicator value and revealed that most essential variables (Ohle ratio for TP and Schindler ratio for Chl-a and SD) have bimodal distribution with a clear threshold value. These findings contribute to a better understanding of the drivers shaping the lake trophic status and have implication for planning effective management strategies. * MONITORING INLAND WATER VIA SENTINEL SATELLITE CONSTELLATION: A REVIEW AND PERSPECTIVE 2023, ISPRS Journal of Photogrammetry and Remote Sensing Show abstract Clean Water and Sanitation, the sixth goal of Sustainable Development Goals (SDGs 6) is a call for action by the United Nations aiming at balancing the water cycle for sustainable life on the earth. For water security and regional sustainable development, the quantity and quality of inland waters are key variables. Over the past decades, satellite remote sensing offers global information about inland water dynamics in a real-time and low-cost way. Amongst, the Sentinel satellites designed by the European Space Agency can provide global monitoring with a spatial resolution of up to 10 m and several days of revisit time. Although Sentinel satellites have been explored in inland water monitoring for a long time period, a systematical review on the research progress and challenges of their applications has not been documented well. This review aims to present a comprehensive review of the Sentinel satellites (especially for Sentinel-1, Sentinel-2, and Sentinel-3) in monitoring inland water, both on the quantity and quality dimensions, including the water extent, level, depth, volume and water quality (e.g., chlorophyll-a, phycocyanin, suspended particulate matter, colored dissolved organic matter, and Secchi disk depth). A total of 690 publications are involved and the bibliometric quantitative approach is used to analyze the areas in which Sentinel instrument excelled and their performance with different processing methods. The implications for virtual constellation construction using Sentinel satellites from different missions and the contribution of a virtual constellation in support of the SDG 6 are also discussed. According to the initial investigation and characteristics of various satellites, we have proposed several schemes for Sentinel virtual constellation toward different missions covering water quantity measurement and water quality monitoring, which can maximize the observation capability of the satellite. The optimal Sentinel virtual constellation constructing scheme theoretically enables a coverage of 10 m spatial resolution and less than 2 days temporal resolution for all-weather inland water monitoring. These solutions will significantly enhance the observational capacity to obtain high-quality, long-term water security parameters in supporting SDG 6. Nevertheless, there remains a scarcity of freely available Sentinel-derived products, widely applicable data processing algorithms, and unified platform, capable of supporting water security monitoring on a broad scale. View all citing articles on Scopus Copyright © 2015 Published by Elsevier Inc. RECOMMENDED ARTICLES * OPTICAL TECHNIQUES FOR REMOTE AND IN-SITU CHARACTERIZATION OF PARTICLES PERTINENT TO GEOTRACES Progress in Oceanography, Volume 133, 2015, pp. 43-54 Emmanuel Boss, …, Robert M. 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