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KERALA PSC SANITARY CHEMIST STUDY PLAN

by Sabira Ulfath
September 20, 2023
in Articles, Kerala PSC

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Table of Contents

 * Kerala PSC Sanitary Chemist Study Plan 2023
 * Main Topics to Cover : KPSC Sanitary Chemist 2023
 * Mock Tests : KPSC Sanitary Chemist 2023
 * Previous Year Questions : KPSC Sanitary Chemist 2023

Kerala Public Service Commission will be recruiting eligible candidates for the
post of Sanitary Chemist posts under the Kerala Water Authority ,Category number
127/2023 aim to fill the 04 vacant posts. An official notification regarding
this was released by the Commission on July 17,2023. Eligible candidates will be
selected through Written exams along with Interviews. The Post is open  under
the age of 36. Visit the official page of Kerala Public Service Commission
(KPSC) for more details.

As the recruitment notifications are released, all candidates have to take their
preparations seriously and follow a strict study method for high scores in the
exam. The Sanitary Chemist preparation is done best when you make a
topic-intensive study plan. There will be a tough competition as the number of
vacancies are less. So, select effective study materials for the preparation.
Before the preparation starts, the candidates must be on hold of sufficient
study materials and must have an idea about the best study materials that are
available.

Grab Study Materials for Kerala PSC Exams !!! Register Now !


KERALA PSC SANITARY CHEMIST STUDY PLAN 2023

As the date of exam notifications are released, all candidates have to take
their preparations seriously and follow a strict study method for high scores in
the exam. There will be a tough competition as the number of vacancies are less.
So, select effective study materials for the preparation.

Planning out a timetable for your preparations is the first step to scoring high
marks. Put your own effort into creating one or else you can follow the
below-given study plans. It all depends on you. Try not to pressurize yourself.
Take short notes as you go through the topics. Understand which are the topic
that carries maximum marks weightage and divide your study schedule accordingly.


DAY WISE TABLE- STUDY PLAN OF 30 DAYS

Days Topics Day 1
 * Atomic structure and chemical bonding
   * Bohr’s theory
   * Atomic spectrum of the hydrogen atom
   * De Broglie equation
   * Heisenberg’s Uncertainty Principle
   * Schrödinger’s wave equation
   * Quantum numbers and their significance
   *  Shapes of s, p, d, and f orbitals
   *  Pauli’s Exclusion Principle
   * Hund’s rule of maximum multiplicity
   *  Aufbau’s principle

Day 2
 * Atomic structure and chemical bonding
   * Variation of orbital energy with atomic number
   *  S, p, d, f block elements, and their properties
   *  Shielding effect
   *  Slater rules
   *  Variation of effective nuclear charge in the periodic table
   * Ionization enthalpy
   *  Factors affecting ionization energy
   * Applications of ionization enthalpy
   *  Electron gain enthalpy
   *  Trends of electron gain enthalpy
   *  Electronegativity

Day 3
 * Revise your notes and try doing previous year’s questions as many times as
   you can.

Day 4
 * Atomic structure and chemical bonding
   * Pauling’s/ Mulliken’s and Allred Rachow’s electronegativity scales
   * Hybridization, Inert pair effect, the relative stability of different
     oxidation states
   * Diagonal relationship and anomalous behavior of the first member of each
     group
   *  Structure, bonding, preparation, properties, and uses of boric acid and
     borates
   *  Boron nitrides, borohydrides (diborane), carboranes, silanes, Oxides, and
     oxoacids of nitrogen
   * Phosphorus and chlorine
   * Peroxo acids of sulfur, interhalogen compounds, polyhalite ions
   *  Pseudohalogens and basic properties of halogens
   *  Occurrence and uses of noble gases
   *  Clathrates; preparation and properties of xef2, xef4 and xef6
   *  Radius ratio rule, Born-Haber cycle, and its application
   *  Solvation energy
   * Lewis structure
   *  Valence bond theory
   * Resonance and resonance energy

Day 5
 * Coordination chemistry, metallurgy, and bioinorganic chemistry
   * Werner’s theory
   *  IUPAC nomenclature of coordination compounds
   *  Isomerism in coordination compounds
   * Stereochemistry of complexes with 4 and 6 coordination numbers
   *  Chelate effect, valence bond theory (inner and outer orbital complexes)
   * Back bonding
   * Crystal field theory, CFSE in weak and strong fields
   *  Pairing energies, factors affecting the magnitude of 10 Dq (Δo, Δt).
   * Octahedral vs. Tetrahedral coordination
   * Tetragonal distortions from octahedral geometry Jahn-Teller theorem
   * Square planar geometry
   * The qualitative aspect of the Ligand field and MO Theory

Day 6
 * Coordination chemistry, metallurgy, and bioinorganic chemistry
   * Substitution reactions in square planar complexes
   *  Trans- effect, mechanism of nucleophilic substitution in square planar
     complexes
   * Thermodynamic and Kinetic stability
   *  Kinetics of octahedral substitution
   * Ligand field effects and reaction rates
   * Mechanism of substitution in octahedral complexes
   *  Chief modes of occurrence of metals, electrolytic Reduction
   * Hydrometallurgy, methods of purification of metals
   *  Electrolytic, Kroll process, van Arkel and Mond’s process, Zone refining
   *  Metal ions present in biological systems
   *  Classification of elements according to their action in the biological
     system

Day 7
 * Organometallic compounds
   * Classification of organometallic compounds based on the bond type
   * Concept of hapticity of organic ligands
   *  Metal carbonyls: 18 electron rule
   *  Electron count of mononuclear
   * Polynuclear and substituted metal carbonyls of 3d series
   *  General methods of preparation (direct combination, reductive
     carbonylation, thermal and photochemical decomposition) of mono and
     binuclear carbonyls of 3d series

Day 8
 * Organometallic compounds
   * Structures of mononuclear and binuclear carbonyls of Cr, Mn, Fe, Co, and Ni
     using VBT. -p acceptor behavior of CO
   *  Synergic effect and use of IR data to explain the extent of back bonding
   *  Zeise’s salt: Preparation and structure
   * Metal Alkyls: Important structural features of methyl lithium (tetramer)
     and trialkyl aluminum (dimer)
   * Concept of multicentre bonding in these compounds. Role of
     triethylaluminium in polymerisation of ethene (Ziegler – Natta Catalyst).
   *  Ferrocene: Preparation and reactions (acetylation, alkylation,
   * Metallation, Mannich Condensation). Structure and aromaticity.
   *  Comparison of aromaticity and reactivity with that of benzene.
   * Mechanism of Alkene hydrogenation (Wilkinsons Catalyst), Hydroformylation
     (Co salts),
   *  Wacker Process, Synthetic gasoline (Fischer Tropsch reaction)

Day 9
 * Revision
 * Mock Test
 * Test Series
 * Practice with the Previous year’s question paper

Day 10
 * Qualitative and quantitative aspects of analysis
   * Sampling, evaluation of analytical data, errors
   *  Accuracy and precision, methods of their expression
   *  Statistical test of data; F, Q, and t-test Basic principles involved in
     the analysis of cations and anions and solubility products, common ion
     effect.
   *  Principles involved in the separation of cations into groups and the
     choice of group reagents. Interfering anions (fluoride, borate, oxalate,
     and phosphate) need to remove after Group II.
   * Flame Atomic Absorption and Emission Spectrometry: Basic principles,
     Techniques of atomization and sample introduction; sources of chemical
     interferences and their method of removal.
   * Techniques for the quantitative estimation of trace level of metal ions
     from samples.
   * Classification of electroanalytical methods, a basic principle of ph
     metric, potentiometric and conductometric titrations.
   * Techniques used for the determination of pka values.

Day 11
 * Organic reaction mechanism and stereochemistry
   * Classification and nomenclature of organic compounds,
   * Hybridization, Inductive, electromeric, resonance, and mesomeric effects,
     hyperconjugation, and their applications.
   * Organic acids and bases; their relative strength. Homolytic and heterolytic
     fission, electrophiles and nucleophiles
   *  Types, shape, and their relative stability of carbocations, carbanions,
     free radicals, and carbenes. Introduction to types of organic reactions and
     their mechanism

Day 12
 * Organic reaction mechanism and stereochemistry
   *  Addition, Elimination, and Substitution reactions
   * Fischer Projection, Newmann and Sawhorse Projection formulae and their
     interconversions;
   *  Geometrical isomerism: cis-trans and, syn-anti isomerism E/Z notations
     with C.I.P rules. Optical Isomerism: Optical Activity
   *  Specific Rotation, Chirality/Asymmetry, Enantiomers, Molecules with two or
     more chiral centers, Distereoisomers, mesostructures,
   * Racemic mixture and resolution
   *  Relative and absolute configuration: D/L and R/S designations.
   * Applications of IR, UV, and NMR for identification of simple organic
     molecules.

Day 13
 * Aliphatic and aromatic hydrocarbons
   * Formation of alkanes,
   *  Wurtz Reaction, Wurtz-Fittig Reactions,
   * Free radical substitutions: Halogenation-relative reactivity and
     selectivity
   *  Formation of alkenes and alkynes by elimination reactions
   *  Mechanism of E1, E2, e1cb reactions. Saytzeff and Hofmann eliminations
   *  Reactions of alkenes: Electrophilic additions their mechanisms
     (Markownikoff/ Anti Markownikoff addition),
   *  Mechanism of oxymercuration-demarcation,
   *  Hydroboration-oxidation, ozonolysis, reduction (catalytic and chemical),
   *  Syn and anti-hydroxylation (oxidation), 1,2 and 1,4-addition reactions in
     conjugated dienes,

Day 14
 * Aliphatic and aromatic hydrocarbons
   *  Diels-Alder reaction;
   * Allylic and benzylic bromination and mechanism,
   *  Reactions of alkynes: Acidity, Electrophilic, and Nucleophilic additions.
   *  Hydration to form carbonyl compounds,
   * Alkylation of terminal alkynes.
   *  Types of cycloalkanes and their relative stability,
   *  Baeyer strain theory, Conformation analysis of alkanes and cyclohexane.
   *  Aromaticity: Hückel’s rule, aromatic character of arenes,
   * Cyclic carbocations/carbanions, and heterocyclic compounds with suitable
     examples.
   * Electrophilic aromatic substitution: halogenation, nitration, sulphonation,
     and Friedel-Craft’s alkylation/acylation with their mechanism.
   *  Directing effects of the groups.
   * Preparation and reactions of naphthalene, phenanthrene, and anthracene

Day15
 * Halogenated hydrocarbons and heterocyclic compounds
   * Alkyl halides: Methods of preparation,
   *  Nucleophilic substitution reactions – SN1, SN2, and sni mechanisms with
     stereochemical aspects and effect of solvent, etc.;
   *  Nucleophilic substitution vs. Elimination.
   * Aryl halides: Methods of reparation, nucleophilic aromatic substitution;
   *  Snar, Benzyne mechanism. Relative reactivity of alkyl, allyl/benzyl,
     vinyl, and aryl halides towards nucleophilic substitution reactions.

Day 16
 * Halogenated hydrocarbons and heterocyclic compounds
   * Organometallic compounds of Mg and Li – are used in the synthesis of
     organic compounds.
   * Classification and nomenclature,
   * Structure, aromaticity in 5-numbered and 6-membered rings containing one
     heteroatom;
   * Synthesis, reactions, and mechanism of substitution reactions of Furan,
     Pyrrole (Paal-Knorr synthesis, Knorr pyrrole synthesis, Hantzsch
     synthesis),
   * Thiophene, Pyridine (Hantzsch synthesis), Pyrimidine, Skraup synthesis,
     Friedlander’s synthesis, Knorr quinoline synthesis,
   * Bichler-Napieralski reaction Derivatives of furan: Furfural and furoic
     acid.

Day 17
 * Halogenated hydrocarbons and heterocyclic compounds
   * Alcohols, phenols, ethers, epoxides, and nitrogen compounds
   *  Alcohols: preparation, properties, and relative reactivity of 1°, 2°, 3°
     alcohols
   *  Bouvaelt-Blanc Reduction
   * Preparation and properties of glycols: Oxidation by periodic acid and lead
     tetraacetate
   *  Pinacol-Pinacolone rearrangement
   *  Phenols: Preparation and properties
   * Acidity and factors affecting it
   * Ring substitution reactions, Reimer–Tiemann and Kolbe’s–Schmidt Reactions

Day 18
 * Revisions
 * Mock test
 * Test series
 * Practice with the previous year’s question paper

Day 19
 *  Carbonyl compounds, carboxylic acids, and their derivatives
   * Structure, reactivity, and preparation of carbonyl compounds
   * Nucleophilic additions
   * Nucleophilic addition-elimination reactions with ammonia derivatives
   *  Mechanisms of Aldol and Benzoin condensation
   *  Knoevenagel condensation, Claisan-Schmidt, Perkin, Cannizzaro and Wittig
     reaction
   *  Beckmann and Benzil-Benzilic acid rearrangements
   * Haloform reaction and Baeyer Villiger oxidation, α- substitution reactions
   *  Oxidations and reductions (Clemmensen, Wolff-Kishner, lialh4, nabh4, MPV)
   *  Michael addition

Day 20
 * Gaseous, liquid, and solid states
   * Kinetic gas equation, collision frequency
   *  collision diameter, mean free path, and viscosity of gases
   *  relation between mean free path and coefficient of viscosity
   *  variation of viscosity with temperature and pressure
   *  maxwell distribution and its use in evaluating molecular velocities
     (average, root mean square, and most probable)

Day 21
 * Gaseous, liquid, and solid states
   * Law of equipartition of energy
   * Degrees of freedom and molecular basis of heat capacities
   * The behavior of real gases: deviations from ideal gas behavior
   *  compressibility factor, z, and its variation with pressure for different
     gases
   *  van der waals equation of state
   *  virial equation of state
   * Glasses and liquid crystals

Day 22
 *  Ionic and chemical equilibria, phase equilibria
   *  Degree of ionization
   *  Factors affecting the degree of ionization
   *  Ionization constant and ionic product of water
   *  Ionization of weak acids and bases
   * Ph scale, common ion effect, dissociation constants of mono-, di-and
     tricrotic acids
   * Salt hydrolysis-calculation of hydrolysis constant
   *  Degree of hydrolysis and ph for different salts
   *  Buffer solutions, Henderson equation, and its applications

Day 23
 *   Chemical thermodynamics
   * Intensive and extensive variables
   * State and path functions; isolated, closed, and open systems
   * Zeroth law of thermodynamics. Concept of heat (q), work(w), internal energy
     (U), and statement of the first law, enthalpy (H)
   * Relation between heat capacities
   * Calculations of q, w, U, and H for reversible
   * Irreversible and free expansion of gases (ideal and van der Waals) under
     isothermal and adiabatic conditions
   * Variation of S, G, A with T, V, P
   * Free energy change and spontaneity

Day 24
 * Revisions
 * Mock test
 * Test Series
 * Practice with the Previous year’s question paper

Day 25
 * Chemistry Papers
 * and do the questions that come under this topic.
 * solve out some previous year’s questions too (minimum 20 questions).

Day 26
 * Chemical kinetics, surface chemistry, and catalysis
   * Order and molecularity of a reaction
   * Rate laws in terms of the advancement of a reaction
   * Differential and integrated form of rate expressions up to second-order
     reactions
   * Experimental methods of the determination of rate laws
   * Kinetics of complex reactions
   * Chain reactions
   * Effect of particle size and efficiency of nanoparticles as catalysts
   *  Enzyme catalysis, Michaelis-Menten mechanism, acid-base catalysis

Day 27
 * Prepare the Main highlighted sections as much as you can and keep doing more
   questions.

Day 28
 *  Electrochemistry
   * Conductivity
   * Molar conductivity at infinite dilution
   * kohlrausch law of independent migration of ions
   * debye-hückel-onsager equation
   * Wien effect, debye-falkenhagen effect,
   * Walden’s rules
   * Ionic velocities
   *  mobilities and their determinations
   * Transference numbers and their relation to ionic mobilities
   * Determination of transference numbers using hittorf and moving boundary
     methods)

Day 29
 *  Molecular spectroscopy
   * Interaction of electromagnetic radiation with molecules and various types
     of spectra
   * Born Oppenheimer approximation
   * Rotation spectroscopy
   *  Selection rules, intensities of spectral lines
   * Determination of bond lengths of diatomic and linear triatomic molecules
   *  Isotopic substitution Vibrational spectroscopy
   * Nuclear Magnetic Resonance (NMR) spectroscopy: Principles of NMR
     spectroscopy
   *  Larmor precession
   * Chemical shift and low-resolution spectra

Day 30
 * Revisions
 * Mock test
 * Test Series
 * Practice with the Previous year’s question paper

Grab Study Materials for Kerala PSC Exams !!! Register Now !


MAIN TOPICS TO COVER : KPSC SANITARY CHEMIST 2023

The syllabus Plays key role in the preparation as well as acquiring effective
study materials. In a syllabus, there can be topics that are very important
because the questions from those topics appear frequently in the exams.
Therefore, it is necessary to refer to the previous year’s questions to find the
main topics. The main topics that the candidates should not miss under any
circumstance are given below.


SANITARY CHEMIST SYLLABUS MAIN TOPICS

Some of the main topics in the syllabus of Sanitary Chemist includes in this
section,

ATOMIC STRUCTURE AND CHEMICAL BONDING

Bohr’s theory, atomic spectrum of hydrogen atom, de Broglie equation,
Heisenberg’s Uncertainty Principle, Schrödinger’s wave equation, Quantum numbers
and their significance, Shapes of s, p, d and f orbitals. Pauli’s Exclusion
Principle, Hund’s rule of maximum multiplicity, Aufbau’s principle, Variation of
orbital energy with atomic number, s, p, d, f block elements and their
properties. Shielding effect, Slater rules, variation of effective nuclear
charge in periodic table. Ionization enthalpy, factors affecting ionization
energy, applications of ionization enthalpy. Electron gain enthalpy, trends of
electron gain enthalpy. Electronegativity, Pauling’s/ Mulliken’s and Allred
Rachow’s electronegativity scales, hybridization, Inert pair effect, relative
stability of different oxidation states, diagonal relationship and anomalous
behaviour of first member of each group. Structure, bonding, preparation,
properties and uses of boric acid and borates, boron nitrides, borohydrides
(diborane), carboranes, silanes, Oxides and oxoacids of nitrogen, phosphorus and
chlorine, Peroxo acids of sulphur, interhalogen compounds, polyhalide ions,
pseudohalogens and basic properties of halogens. Occurrence and uses of noble
gases, clathrates; preparation and properties of XeF2, XeF4 and XeF6.

COORDINATION CHEMISTRY, METALLURGY, AND BIOINORGANIC CHEMISTRY

Werner’s theory, IUPAC nomenclature of coordination compounds, isomerism in
coordination compounds. Stereochemistry of complexes with 4 and 6 coordination
numbers. Chelate effect, valence bond theory (inner and outer orbital
complexes), back bonding. Crystal field theory, CFSE in weak and strong fields,
pairing energies, factors affecting the magnitude of 10 Dq (Δo, Δt). Octahedral
vs. tetrahedral coordination, tetragonal distortions from octahedral geometry
Jahn-Teller theorem, square planar geometry. Qualitative aspect of Ligand field
and MO Theory. Substitution reactions in square planar complexes, Trans- effect,
mechanism of nucleophilic substitution in square planar complexes, Thermodynamic
and Kinetic stability, Kinetics of octahedral substitution, Ligand field effects
and reaction rates, Mechanism of substitution in octahedral complexes.
Chief modes of occurrence of metals, electrolytic Reduction, hydrometallurgy,
methods of purification of metals: Electrolytic, Kroll process, van Arkel and
Mond’s process, Zone refining. Metal ions present in biological systems,
classification of elements according to their action in biological system.
Sodium / K-pump, carbonic anhydrase and carboxypeptidase. Excess and deficiency
of some trace metals. Toxicity of metal ions (Hg, Pb, Cd and As), reasons for
toxicity, Use of chelating agents in medicine. Iron and its application in
bio-systems, Haemoglobin; Storage and transfer of iron.

ORGANOMETALLIC COMPOUNDS

Classification of organometallic compounds on the basis of bond type. Concept of
hapticity of organic ligands. Metal carbonyls: 18 electron rule, electron count
of mononuclear, polynuclear and substituted metal carbonyls of 3d series.
General methods of preparation (direct combination, reductive carbonylation,
thermal and photochemical decomposition) of mono and binuclear carbonyls of 3d
series. Structures of mononuclear and binuclear carbonyls of Cr, Mn, Fe, Co and
Ni using VBT.  acceptor behaviour of CO, synergic effect and use of IR data to
explain extent of back bonding. Zeise’s salt: Preparation and structure. Metal
Alkyls: Important structural features of methyl lithium (tetramer) and trialkyl
aluminium (dimer), concept of multicentre bonding in these compounds. Role of
triethylaluminium in polymerisation of ethene (Ziegler – Natta Catalyst).
Ferrocene: Preparation and reactions (acetylation, alkylation, metallation,
Mannich Condensation). Structure and aromaticity. Comparison of aromaticity and
reactivity with that of benzene. Mechanism of Alkene hydrogenation (Wilkinsons
Catalyst), Hydroformylation (Co salts), Wacker Process, Synthetic gasoline
(Fischer Tropsch reaction).

QUALITATIVE AND QUANTITATIVE ASPECTS OF ANALYSIS

 * Sampling, evaluation of analytical data, errors
 *  Accuracy and precision, methods of their expression
 *  Statistical test of data; F, Q, and t-test Basic principles involved in the
   analysis of cations and anions and solubility products, common ion effect.
 *  Principles involved in the separation of cations into groups and the choice
   of group reagents. Interfering anions (fluoride, borate, oxalate, and
   phosphate) need to remove after Group II.
 * Flame Atomic Absorption and Emission Spectrometry: Basic principles,
   Techniques of atomization and sample introduction; sources of chemical
   interferences and their method of removal.
 * Techniques for the quantitative estimation of trace level of metal ions from
   samples.
 *  Classification of electroanalytical methods, a basic principle of ph metric,
   potentiometric and conductometric titrations.
 * Techniques used for the determination of pka values.
 * Theory of thermogravimetry (TG), Techniques for quantitative estimation of Ca
   and Mg from their mixture. Complexometric titration: EDTA titration.

ORGANIC REACTION MECHANISM AND STEREOCHEMISTRY

 * Classification and nomenclature of organic compounds,
 * Hybridization, Inductive, electromeric, resonance, and mesomeric effects,
   hyperconjugation, and their applications.
 * Organic acids and bases; their relative strength. Homolytic and heterolytic
   fission, electrophiles and nucleophiles
 *  Types, shape, and their relative stability of carbocations, carbanions, free
   radicals, and carbenes. Introduction to types of organic reactions and their
   mechanism
 *  Addition, Elimination, and Substitution reactions
 * Fischer Projection, Newmann and Sawhorse Projection formulae and their
   interconversions;
 *  Geometrical isomerism: cis-trans and, syn-anti isomerism E/Z notations with
   C.I.P rules. Optical Isomerism: Optical Activity
 *  Specific Rotation, Chirality/Asymmetry, Enantiomers, Molecules with two or
   more chiral centers, Distereoisomers, mesostructures,
 * Racemic mixture and resolution
 *  Relative and absolute configuration: D/L and R/S designations.
 * Applications of IR, UV, and NMR for identification of simple organic
   molecules.

ALIPHATIC AND AROMATIC HYDROCARBONS

 * Formation of alkanes,
 *  Wurtz Reaction, Wurtz-Fittig Reactions,
 * Free radical substitutions: Halogenation-relative reactivity and selectivity
 *  Formation of alkenes and alkynes by elimination reactions
 *  Mechanism of E1, E2, e1cb reactions. Saytzeff and Hofmann eliminations
 *  Reactions of alkenes: Electrophilic additions their mechanisms
   (Markownikoff/ Anti Markownikoff addition),
 *  Mechanism of oxymercuration-demarcation,
 *  Hydroboration-oxidation, ozonolysis, reduction (catalytic and chemical),
 *  Syn and anti-hydroxylation (oxidation), 1,2 and 1,4-addition reactions in
   conjugated dienes,
 *  Diels-Alder reaction;
 * Allylic and benzylic bromination and mechanism,
 *  Reactions of alkynes: Acidity, Electrophilic, and Nucleophilic additions.
 *  Hydration to form carbonyl compounds,
 * Alkylation of terminal alkynes.
 *  Types of cycloalkanes and their relative stability,
 *  Baeyer strain theory, Conformation analysis of alkanes and cyclohexane.
 *  Aromaticity: Hückel’s rule, aromatic character of arenes,
 * Cyclic carbocations/carbanions, and heterocyclic compounds with suitable
   examples.
 * Electrophilic aromatic substitution: halogenation, nitration, sulphonation,
   and Friedel-Craft’s alkylation/acylation with their mechanism.
 *  Directing effects of the groups.
 * Preparation and reactions of naphthalene, phenanthrene, and anthracene

HALOGENATED HYDROCARBONS AND HETEROCYCLIC COMPOUNDS

Alkyl halides: Methods of preparation, nucleophilic substitution reactions –
SN1, SN2 and SNi mechanisms with stereochemical aspects and effect of solvent
etc.; nucleophilic substitution vs. elimination.
Aryl halides: Methods of reparation, nucleophilic aromatic substitution; SNAr,
Benzyne mechanism. Relative reactivity of alkyl, allyl/benzyl, vinyl and aryl
halides towards nucleophilic substitution reactions. Organometallic compounds of
Mg and Li – use in synthesis of organic compounds. Classification and
nomenclature, Structure, aromaticity in 5-numbered and 6-membered rings
containing one heteroatom; Synthesis, reactions and mechanism of substitution
reactions of: Furan, Pyrrole (Paal-Knorr synthesis, Knorr pyrrole synthesis,
Hantzsch synthesis), Thiophene, Pyridine (Hantzsch synthesis), Pyrimidine,
Skraup synthesis, Friedlander’s synthesis, Knorr quinoline synthesis,
Bischler-Napieralski reaction Derivatives of furan: Furfural and furoic acid.

 CARBONYL COMPOUNDS, CARBOXYLIC ACIDS, AND THEIR DERIVATIVES

 *  Structure, reactivity, and preparation of carbonyl compounds
 *  Nucleophilic additions
 * Nucleophilic addition-elimination reactions with ammonia derivatives
 *  Mechanisms of Aldol and Benzoin condensation
 *  Knoevenagel condensation, Claisan-Schmidt, Perkin, Cannizzaro and Wittig
   reaction
 *  Beckmann and Benzil-Benzilic acid rearrangements
 * Haloform reaction and Baeyer Villiger oxidation, α- substitution reactions
 *  Oxidations and reductions (Clemmensen, Wolff-Kishner, lialh4, nabh4, MPV)
 *  Michael addition

GASEOUS, LIQUID, AND SOLID STATES

 * Kinetic gas equation, collision frequency
 *  collision diameter, mean free path, and viscosity of gases
 *  relation between mean free path and coefficient of viscosity
 *  variation of viscosity with temperature and pressure
 *  maxwell distribution and its use in evaluating molecular velocities
   (average, root mean square, and most probable)
 * Law of equipartition of energy
 *  degrees of freedom and molecular basis of heat capacities
 * The behavior of real gases: deviations from ideal gas behavior
 *  compressibility factor, z, and its variation with pressure for different
   gases
 *  van der waals equation of state
 *  virial equation of state
 * Glasses and liquid crystals

 IONIC AND CHEMICAL EQUILIBRIA, PHASE EQUILIBRIA

 *  Degree of ionization
 *  Factors affecting the degree of ionization
 *  Ionization constant and ionic product of water
 *  Ionization of weak acids and bases
 * Ph scale, common ion effect, dissociation constants of mono-, di-and
   tricrotic acids
 * Salt hydrolysis-calculation of hydrolysis constant
 *  Degree of hydrolysis and ph for different salts
 *  Buffer solutions, Henderson equation, and its applications

  CHEMICAL THERMODYNAMICS

 *  Intensive and extensive variables
 * State and path functions; isolated, closed, and open systems
 * Zeroth law of thermodynamics. Concept of heat (q), work(w), internal energy
   (U), and statement of the first law, enthalpy (H)
 * Relation between heat capacities
 *  Calculations of q, w, U, and H for reversible
 *  Irreversible and free expansion of gases (ideal and van der Waals) under
   isothermal and adiabatic conditions
 * Variation of S, G, A with T, V, P
 *  Free energy change and spontaneity

CHEMICAL KINETICS, SURFACE CHEMISTRY, AND CATALYSIS

 * Order and molecularity of a reaction
 *  Rate laws in terms of the advancement of a reaction
 * Differential and integrated form of rate expressions up to second-order
   reactions
 *  Experimental methods of the determination of rate laws
 * Kinetics of complex reactions
 *  Chain reactions
 * Effect of particle size and efficiency of nanoparticles as catalysts
 *  Enzyme catalysis, Michaelis-Menten mechanism, acid-base catalysis

 ELECTROCHEMISTRY

 *  Conductivity
 * Molar conductivity at infinite dilution
 *  kohlrausch law of independent migration of ions
 *  debye-hückel-onsager equation
 * Wien effect, debye-falkenhagen effect,
 * Walden’s rules
 * Ionic velocities
 *  mobilities and their determinations
 * Transference numbers and their relation to ionic mobilities
 * Determination of transference numbers using hittorf and moving boundary
   methods)

 MOLECULAR SPECTROSCOPY

 * Interaction of electromagnetic radiation with molecules and various types of
   spectra
 * Born Oppenheimer approximation
 * Rotation spectroscopy
 *  Selection rules, intensities of spectral lines
 * Determination of bond lengths of diatomic and linear triatomic molecules
 *  Isotopic substitution Vibrational spectroscopy
 * Nuclear Magnetic Resonance (NMR) spectroscopy: Principles of NMR spectroscopy
 *  Larmor precession
 * Chemical shift and low-resolution spectra


MOCK TESTS : KPSC SANITARY CHEMIST 2023

By attending mock tests candidates get familiarized with exam patterns and can
improve their preparation. Through daily practice, mock tests will make the
candidate more efficient and get to know about time management. Striving mock
test series is a very important part of the preparation.

Trying more number of questions can always be beneficial while attending a
competitive exam. A question can provide you a reach to many topics. While you
start preparing, keep an eye on every single topic and should focus on main
important topics. Thus, it is always effective to try out various questions.

Kerala PSC Sanitary Chemist PDF/ Link Sanitary Chemist Mock Test Paper 2021
Download Here Sanitary Chemist Mock Test Paper 2020 Download Here

Grab Study Materials for Kerala PSC Exams !!! Register Now !


PREVIOUS YEAR QUESTIONS : KPSC SANITARY CHEMIST 2023

Solving Sanitary Chemist previous question papers is an important part of exam
preparation. Through taking previous questions, you may get an idea of the
important topics while preparing. Solving out previous questions adds more
points to your exams. Referring to previous year’s questions will give an idea
of the exam pattern. The chances of reappearing the previous year’s questions in
the exams are high. Also, it helps you to study effectively. It becomes easier
for you to know which are the important topics that need your focus. Thus, it is
very relevant to find previous question papers.

Kerala PSC Sanitary Chemist PDF Sanitary Chemist Previous Year Question Paper
2017 Download Here Sanitary Chemist Previous Year Question Paper 2019 Download
Here Sanitary Chemist Previous Year Question Paper 2021 Download Here


SAMPLE QUESTIONS AND ANSWERS

Q.1 The emissions of an α particle and two β particles in succession produce an
………………of the starting atom.

(a) Isotope  (b) Isobar  (c) Isotone  (d) Isomer

Ans: (a) Isotope

Q.2 The order of the C₂V point group is:

(a) 3  (b) 4  (c) 1  (d) 2                                                      
                                                 

Ans: (b) 4

Q.3 Among CO, NO, HCl and CO₂, that which will not yield a microwave spectrum
is: 

(a) CO  (b) NO  (c) HCl  (d) CO₂

Ans: (d) CO₂

Q.4 The number of the normal mode of vibration of  C6H6  molecule is           
                                                  (a) 30  (b) 36  (c) 31  (d) 35

Ans: (a) 30

Q.5 The π donor ligand in Ziese’s salt is

(a) Chlorine  (b) Ethylene  (c) Acetylene  (d) Carbonyl

Ans: (b) Ethylene

Q.6 The number of signals exhibited by the protons of TMS in its NMR Spectrum
is:

(a) 2  (b) 1  (c) 3  (d) 4

Ans: (b) 1

Q.7 Which among the following is the optical property of colloid? 

 (a) Brownian Movement  (b) Electrophoresis  (c) Tyndal Effect  (d) Electro
Osmosis

Ans: (b) Electrophoresis

Q.8 How many isoprene units are present in monoterpenes?

(a) 3  (b) 4  (c) 2  (d) 1

Ans: (c) 2

Q.9 Radioactive disintegration follows …………… order kinetics.

(a) First Order  (b) Second Order  (c) Third Order  (d) Fourth Order   

Ans: (a) First Order

Q.10 The emission of radiant energy after a time lag after its absorption by a
substance is called:

(a) Fluorescence  (b) Phosphorescence  (c) Vibrational Relaxation  (d) Inter
System Crossing 

Ans: (b) Phosphorescence

Grab Study Materials for Kerala PSC Exams !!! Register Now !

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