pubs.rsc.org Open in urlscan Pro
78.25.196.229  Public Scan

Form analysis
4 forms found in the DOM

POST /en/results

<form action="/en/results" aria-label="Sitewide" id="SimpleSearch-form" method="post" role="search"> <label for="SearchText" class="sr-only">Search</label>
  <input autocomplete="off" class="pubs-search__input" id="SearchText" name="SearchText" type="search" value="">
  <div class="pubs-search__actions">
    <button class="input__search-submit" type="submit" aria-label="Search" id="btnNavSearchInput"><img src="https://www.rsc-cdn.org/oxygen/assets/icons/arrow-right.png" width="32" alt=""></button>
    <a class="pubs-search__adv-link" href="/en/search/advancedsearch" aria-label="Advanced search" id="advancedLink">Advanced</a>
  </div>
  <span class="pubs-search__icon"></span>
</form>

POST /en/results

<form action="/en/results" aria-label="Sitewide" id="SimpleSearch-formMobile" method="post" role="search"> <label for="SearchTextMobile" class="sr-only">Search</label>
  <div class="input__search">
    <i class="icon--search"></i>
    <input autocomplete="off" placeholder="Search term, doi, title, author" type="search" class="input__field input__field--basic input__label--block" id="SearchTextMobile" name="SearchText">
    <button class="input__search-submit" name="search" type="submit" aria-label="Search">
      <img src="https://www.rsc-cdn.org/oxygen/assets/icons/arrow-right.png" width="32" alt="" class="input__submit-icon">
    </button>
  </div>
  <div class="input--error" id="errSimpleSearchMobileText">You must enter a search term</div>
  <div class="fixpadv--m">
    <a class="pubs-search__adv-link " href="/en/search/advancedsearch" aria-label="Advanced search" id="advancedLink">Advanced search</a>
  </div>
</form>

POST /en/content/getformatedresult/d2cp02707k?downloadtype=article

<form action="/en/content/getformatedresult/d2cp02707k?downloadtype=article" method="post">
  <div class="select-basic">
    <span>
      <select class="select-field" id="ResultAbstractFormat" name="ResultAbstractFormat">
        <option>BibTex</option>
        <option>EndNote</option>
        <option>MEDLINE</option>
        <option>ProCite</option>
        <option>ReferenceManager</option>
        <option>RefWorks</option>
        <option>RIS</option>
      </select>
    </span>
    <span>
      <input type="submit" name="go" id="Submit1" value="Go" class="btn btn--tiny" onclick="gaTrack()">
    </span>
  </div>
</form>

POST /en/results/searchbyauthor

<form action="/en/results/searchbyauthor" aria-label="Author" id="SearchByAuthor" method="post" role="search">
  <div class="autopad">
    <h2 class="h--heading3">Search articles by author</h2>
    <div class="input-group">
      <div class="input__checkbox">
        <input type="checkbox" id="1" data-givenname="J." data-familyname="Ströh">
        <label for="1" class="input__label">J. Ströh</label>
      </div>
      <div class="input__checkbox">
        <input type="checkbox" id="2" data-givenname="T." data-familyname="Hess">
        <label for="2" class="input__label">T. Hess</label>
      </div>
      <div class="input__checkbox">
        <input type="checkbox" id="3" data-givenname="L." data-familyname="Ohrt">
        <label for="3" class="input__label">L. Ohrt</label>
      </div>
      <div class="input__checkbox">
        <input type="checkbox" id="4" data-givenname="H." data-familyname="Fritzsch">
        <label for="4" class="input__label">H. Fritzsch</label>
      </div>
      <div class="input__checkbox">
        <input type="checkbox" id="5" data-givenname="M." data-familyname="Etter">
        <label for="5" class="input__label">M. Etter</label>
      </div>
      <div class="input__checkbox">
        <input type="checkbox" id="6" data-givenname="A.-C." data-familyname="Dippel">
        <label for="6" class="input__label">A.-C. Dippel</label>
      </div>
      <div class="input__checkbox">
        <input type="checkbox" id="7" data-givenname="L. D." data-familyname="Nyamen">
        <label for="7" class="input__label">L. D. Nyamen</label>
      </div>
      <div class="input__checkbox">
        <input type="checkbox" id="8" data-givenname="H." data-familyname="Terraschke">
        <label for="8" class="input__label">H. Terraschke</label>
      </div>
    </div>
    <input type="submit" name="go" id="Search" value="Go" title="Go" class="btn btn--tiny">
    <input id="DOI" name="DOI" type="hidden" value="D2CP02707K">
    <input id="selectedAuthors" name="selectedAuthors" type="hidden" value="">
  </div>
</form>

Text Content

Jump to main content
Jump to site search
Publishing
 * Journals
 * Books
 * Databases


Search
Advanced



Search

You must enter a search term
Advanced search
Log in / register
You do not have JavaScript enabled. Please enable JavaScript to access the full
features of the site or access our non-JavaScript page.


Issue 6, 2023
 * Previous Article
 * Next Article

From the journal:


PHYSICAL CHEMISTRY CHEMICAL PHYSICS



DETAILED INSIGHTS INTO THE FORMATION PATHWAY OF CDS AND ZNS IN SOLUTION: A
MULTI-MODAL IN SITU CHARACTERISATION APPROACH†


J. Ströh,a   T. Hess,a   L. Ohrt,a   H. Fritzsch,a   M. Etter, b   A.-C. Dippel,
b   L. D. Nyamen *ac  and  H. Terraschke *a  
Author affiliations

* Corresponding authors

a Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel,
Max-Eyth-Str. 2, 24118 Kiel, Germany
E-mail: hterraschke@ac.uni-kiel.de

b DESY Photon Science, Notkestr. 85, 22607 Hamburg, Germany

c Department of Inorganic Chemistry, University of Yaoundé I, P. O. Box 812,
Yaoundé, Cameroon


ABSTRACT

The high stability, high availability, and wide size-dependent bandgap energy of
sulphidic semiconductor nanoparticles (NPs) render them promising for
applications in optoelectronic devices and solar cells. However, the tunability
of their optical properties depends on the strict control of their crystal
structure and crystallisation process. Herein, we studied the structural
evolution during the formation of CdS and ZnS in solution by combining in situ
luminescence spectroscopy, synchrotron-based X-ray diffraction (XRD) and pair
distribution function (PDF) analyses for the first time. The influence of
precursor type, concentration, temperature and heating program on the product
formation and on the bandgap or trap emission were investigated in detail. In
summary, for CdS, single-source precursor (SSP) polyol strategies using the
dichlorobis(thiourea)cadmium(II) complex and double-source precursor approaches
combining Cd(CH3COO)2·2H2O and thiourea led to the straightforward product at
100 °C, while the catena((m2-acetato-O,O′)-(acetate-O,O′)-(m2-thiourea)-cadmium)
complex was formed at 25 and 80 °C. For ZnS, the reaction between
Zn(CH3COO)2·2H2O and thiourea at 100 °C led to the product formation after the
crystallisation and dissolution of an unknown intermediate. At 180 °C, besides
an unknown phase, the acetato-bis(thiourea)-zinc(II) complex was also detected
as a reaction intermediate. The formation of such reaction intermediates, which
generally remain undetected applying only ex situ characterisation approaches,
reinforce the importance of in situ analysis for promoting the advance on the
production of tailored semiconductor materials.





You have access to this article
Please wait while we load your content... Something went wrong. Try again?

About
Cited by
Related

This content is free to download. Please choose one of the options below to gain
access.

Log in Using your FREE account Register for a FREE account


--------------------------------------------------------------------------------

Other ways to access this content

Log in Using your institution credentials Sign in With your membership or
subscriber account


SUPPLEMENTARY FILES

 * Supplementary information PDF (4015K)


ARTICLE INFORMATION

DOI https://doi.org/10.1039/D2CP02707K
Article type Paper
Submitted 15 Jun 2022
Accepted 17 Dec 2022
First published 19 Dec 2022


DOWNLOAD CITATION

Phys. Chem. Chem. Phys., 2023,25, 4489-4500

BibTex EndNote MEDLINE ProCite ReferenceManager RefWorks RIS


PERMISSIONS

Request permissions


DETAILED INSIGHTS INTO THE FORMATION PATHWAY OF CDS AND ZNS IN SOLUTION: A
MULTI-MODAL IN SITU CHARACTERISATION APPROACH

J. Ströh, T. Hess, L. Ohrt, H. Fritzsch, M. Etter, A.-C. Dippel, L. D. Nyamen
and H. Terraschke, Phys. Chem. Chem. Phys., 2023, 25, 4489 DOI:
10.1039/D2CP02707K

To request permission to reproduce material from this article, please go to the
Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to
request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to
reproduce figures and diagrams provided correct acknowledgement is given. If you
want to reproduce the whole article in a third-party publication (excluding your
thesis/dissertation for which permission is not required) please go to the
Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.


SOCIAL ACTIVITY


Tweet
Share


SEARCH ARTICLES BY AUTHOR

J. Ströh
T. Hess
L. Ohrt
H. Fritzsch
M. Etter
A.-C. Dippel
L. D. Nyamen
H. Terraschke

Fetching data from CrossRef.
This may take some time to load.

Loading related content


SPOTLIGHT




ADVERTISEMENTS



 * rsc.org
 * Journals, books & databases

 * Home
 * About us
 * Membership & professional community
 * Campaigning & outreach
 * Journals, books & databases
 * Teaching & learning
 * News & events
 * Locations & contacts
 * Careers
 * Awards & funding
 * Advertise
 * Help & legal
 * Privacy policy
 * Terms & conditions

--------------------------------------------------------------------------------

Facebook Twitter LinkedIn YouTube
© Royal Society of Chemistry 2023
Registered charity number: 207890

--------------------------------------------------------------------------------


Publishing


JOURNALS

 * Current Journals
 * Archive Journals
 * All Journals


BOOKS

 * Browse Books
 * Series
 * For Authors and Editors
 * About


DATABASES

 * Literature Updates
 * ChemSpider
 * The Merck Index*
 * MarinLit


MORE

 * For Members
 * For Librarians
 * Subscribe
 * RSS Feeds
 * Blogs
 * Chemistry World
 * Education in Chemistry
 * Open Access
 * Historical Collection

Got a spare 5 minutes to help us improve our website?
I'll do itNo thanks