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WE VALUE YOUR PRIVACY We and our partners store and/or access information on a device, such as cookies and process personal data, such as unique identifiers and standard information sent by a device for personalised ads and content, ad and content measurement, and audience insights, as well as to develop and improve products. With your permission we and our partners may use precise geolocation data and identification through device scanning. You may click to consent to our and our 777 partners’ processing as described above. Alternatively you may click to refuse to consent or access more detailed information and change your preferences before consenting. Please note that some processing of your personal data may not require your consent, but you have a right to object to such processing. Your preferences will apply to this website only. You can change your preferences at any time by returning to this site or visit our privacy policy. MORE OPTIONSDISAGREEAGREE ArticlePDF Available ROLLING BACK THE ‘MUDSTONE BLANKET’: COMPLEX GEOMETRIC AND FACIES RESPONSES TO BASIN ARCHITECTURE IN THE EPICONTINENTAL OXFORD CLAY FORMATION (JURASSIC, UK) * March 2022 * Newsletters on Stratigraphy 56(1) DOI:10.1127/nos/2022/0685 Authors: Mark A. Woods Mark A. Woods * This person is not on ResearchGate, or hasn't claimed this research yet. Jan Hennissen * British Geological Survey Andrew J. Newell Andrew J. Newell * This person is not on ResearchGate, or hasn't claimed this research yet. Keith Duff * Independent Researcher Show all 5 authorsHide Download full-text PDFRead full-text Download full-text PDF Read full-text Download citation Copy link Link copied -------------------------------------------------------------------------------- Read full-text Download citation Copy link Link copied References (86) Discover the world's research * 25+ million members * 160+ million publication pages * 2.3+ billion citations Join for free Public Full-text 1 Content uploaded by Jan Hennissen Author content All content in this area was uploaded by Jan Hennissen on Jun 23, 2022 Content may be subject to copyright. 1 Rolling back the ‘mudstone blanket’: complex geometric and facies responses to basin architecture 1 in the epicontinental Oxford Clay Formation (Jurassic, UK) 2 Mark A. Woodsa*, Jan A. I. Hennissena, Andrew J. Newellb, Keith L. Duffc, Philip R. Wilbya 3 aBritish Geological Survey, Keyworth, Nottingham, UK, NG12 5GG 4 bBritish Geological Survey, Maclean Building, Wallingford, UK, OX10 8BB 5 c 21 Bishops Walk, Barnack, Stamford, Lincs, UK, PE9 3EE 6 *Corresponding author: Email: maw@bgs.ac.uk 7 Abstract 8 Facies variability of mudstones is likely greater than generally perceived, with important implications 9 for their behaviour in major civil engineering, energy and waste disposal applications. Here, we 10 explore this variability for the UK Oxford Clay, a widely studied Middle/Upper Jurassic mudstone. 11 Evidence from wire-line logs, geochemistry, sequence stratigraphy and biofacies analyses are 12 combined to reveal heterogeneity within the Peterborough Member (Lower Oxford Clay) and to 13 explore the extent to which it blanketed basin features or responded dynamically to them. Thickness 14 modelling suggests that the Mid North Sea High, formed by Mid Jurassic thermal doming, likely 15 influenced sediment pathways, favouring thick sediment accumulation in the Wessex Basin, thinner 16 successions across the East Midlands Shelf, and sediment starvation in the Weald Basin. Biofacies 17 patterns, determined using a novel combination of detrended correspondence and cluster analysis, 18 vary significantly and suggest a complex patchwork of environments related to local basin setting. 19 The Type Section of the Peterborough Member seems to represent only a narrow range of 20 conditions that influenced its deposition, and cautions against developing basin-scale models based 21 on a few well exposed and heavily researched outcrop successions. 22 Key Words: Callovian, mudstone, heterogeneity, sequence stratigraphy, XRFS chemostratigraphy, 23 biofacies 24 1. Introduction 25 26 Recent research on the processes of mudstone deposition question the long-held view that these 27 sediments can be understood as a ‘mud-blanket’ resulting from slow deposition from suspension in 28 quiet water conditions (e.g. Scheiber et al. 2007, Macquaker and Bohacs 2007, Birgenheier et al. 29 2017). Earlier work on both the Oxford Clay (Hudson and Martill 1991) and the Kimmeridge Clay 30 (Wignall, 1989) suggested that more episodic depositional events, including storms, may be 31 important factors in mudstone accumulation. Temporal and spatial variability of facies in the lower 32 part of the Oxford Clay were mentioned by Hudson and Martill (1991), and wider evidence of 33 mudstone facies heterogeneity has emerged from outcrop and borehole studies (Macquaker 1994, 34 Macquaker and Howell 1999, Birgenheier et al. 2017). Here, we adopt a multidisciplinary surface-to-35 subsurface approach to test the extent of facies variation at basin scale across a range of contrasting 36 palaeogeographical settings for part of the Oxford Clay Formation (Peterborough Member) – a mud-37 dominated unit that has historically been regarded as generally uniform (Callomon 1968, Holloway 38 1985). Limited outcrop studies point to the presence of vertically stacked lithofacies that can be 39 related to patterns of relative sea level change and sequence stratigraphy frameworks (Partington et 40 al. 1993, Macquaker 1994, Norris and Hallam 1995, Macquaker and Howell 1999, Hesselbo 2008). 41 Our work combines these localised outcrop data with an extensive subsurface data archive, 42 2 FIGURE 1 43 3 providing a fully contextualised model-based understanding of the likely extent of facies variability 44 across the entire preserved basin, allowing understanding of the role of structural/bathymetric 45 features in controlling facies patterns. 46 Current knowledge of the Oxford Clay is strongly influenced by a few well-exposed onshore 47 sites distributed across its outcrop (particularly the type sections of the component members in 48 Cambridgeshire (Peterborough Member), Bedfordshire (Stewartby Member) and Dorset (Weymouth 49 Member); e.g. Hudson and Martill 1991, 1994, Kenig et al. 1994, Macquaker and Howell 1999, Page 50 et al. 2009; Figs 1, 2). These outcrops, however, provide an incomplete picture of the Oxford Clay 51 because much of the formation is concealed beneath a thick (up to 1km) cover of younger strata in 52 areas such as the Wessex-Channel Basin in southern England. Fortunately, a long history of 53 hydrocarbons exploration in these deep basins has left a rich source of borehole information. Here, 54 we make use of this subsurface information to elucidate the extent of facies heterogeneity in the 55 lower part of the Oxford Clay (Peterborough Member) and its relationship to basin architecture. To 56 achieve this we: 1) use borehole geophysical logs and biostratigraphical data to understand patterns 57 of sediment thickness with respect to major palaeogeographical and basin structural features; 2) 58 combine new geochemical data with existing knowledge to refine understanding of the impact of 59 relative sea level change; and 3) explore variability in biofacies data for a series of distinct basin 60 settings (shallow platform, shallow shelf, shallow flooded massif, intra-basinal high, deep shelf, 61 faulted basin margin, distal basin) in order to resolve the extent to which environmental signals are 62 reflected in the gross lithological character of local successions. 63 Key objectives of this study are to: 1) understand basin-scale facies variability for the 64 Peterborough Member, and the extent to which it behaves as a ‘mud blanket’; 2) develop 65 conceptual understanding of how basin architecture might influence sediment fluxes and 66 environments across the basin, and how these relate to facies variability; and 3) understand the 67 extent to which any heterogeneity in the Peterborough Member might be replicated in other 68 Jurassic mudstones. More broadly, our new digital model provides a resource for future assessment 69 of regional physical property variation in mudstones like the Oxford Clay, of particular relevance to 70 planned infrastructure development (National Infrastructure Commission 2018), and their suitability 71 as a host rock for nuclear waste storage (Delay et al. 2007, Butler 2010; Norris 2017). 72 2. Geological Setting 73 Deposition of the Oxford Clay Formation (Callovian/Oxfordian) coincided with a period of marked 74 crustal extension and fracturing associated with North Atlantic rifting (Wilhelm 2014). Mid Jurassic 75 (Late Toarcian – Bathonian) thermal doming of the North Sea region began to subside in the Early 76 Callovian (Underhill 1998), although the dome flanks persisted as a positive structural entity 77 (Bradshaw et al. 1992). These features added to a complex palaeogeographical fabric in the UK 78 region, where an epicontinental sea, dotted with emergent island massifs and cut by extensional 79 basins controlled by reactivated Variscan structures, formed the environment for deposition of the 80 Oxford Clay Formation (Fig. 1). 81 The Oxford Clay Formation is subdivided into three parts: the Peterborough, Stewartby and 82 Weymouth members (Fig. 2). The lowermost Peterborough Member is the most organic-rich part of 83 the formation, comprising brownish-grey mudstones and silty mudstones with typically 3 – 16 % TOC 84 (Kenig et al. 1994), plus occasional sandstone and concretionary limestone units. Compositionally, it 85 is a mixture of mica, illite, mixed illite/smectite, kaolinite and quartz, with calcite from shell beds, 86 foramininifera and nannofossils, and amorphous organic matter derived from marine phytoplankton 87 (Kenig et al. 1994; Macquaker 1994; Norry et al. 1994). The highest organic-rich mudstone unit 88 defines the top of the Peterborough Member. Younger parts of the formation (Stewartby and 89 Weymouth members; Fig. 2) typically comprise massive, paler grey silty mudstone (Cox et al. 1992) 90 4 FIGURE 2 91 5 and are less organic-rich, suggesting a more oxidizing depositional environment (Kenig et al. 1994). A 92 thin limestone interval (Lamberti Limestone) or equivalent shell bed/siltstone separates the 93 Stewartby and Weymouth members (Cox et al. 1992). In northern England (Yorkshire), deposition 94 was strongly influenced by a shallow structural block (Market Weighton High; Fig. 1) and the 95 Peterborough and Stewartby members are replaced by sandstones of the Osgodby Formation (Cope 96 2006, Powell et al. 2018, fig. 13; Fig. 2). This facies transition and thinning of the Oxford Clay across 97 eastern England into the Cleveland Basin was documented by Penn et al. (1986). Across the rest of 98 southern England, thickness data for the Peterborough Member indicate around 17 m at 99 Peterborough on the East Midlands Shelf (Hudson and Martill 1994), ca. 10.5 m in the Eriswell 100 Borehole (Bristow et al. 1989) on the flanks of the Anglo-Brabant Massif, ca. 15 – 18 m in boreholes 101 in the Weald Basin (Lake et al. 1987), and about 22 m near Weymouth on the Dorset coast 102 (Callomon and Cope 1995). 103 Offshore, strata equivalent to the Oxford Clay are sandy and silty in the Southern North Sea 104 (Seeley Formation; Lott and Knox 1994; Fig. 2), become deltaic and coal-bearing in the Central 105 Graben (Møller and Rasmussen 2003), and return to marine, mud and silt-dominated facies (Heather 106 Formation; Fig. 2) in the Moray Firth and Viking Graben (Underhill and Partington 1993). Across 107 southern England and the adjacent offshore regions the top of the Oxford Clay is widely conformable 108 with the overlying Corallian Group, except where the West Walton Formation has eroded into the 109 top of the Weymouth Member (Penn et al. 1986), or where the Corallian Group has been completely 110 removed by later erosion. 111 112 3. Materials and Methodology 113 Determining the likely range and extent of basin-scale facies patterns in the Peterborough Member 114 requires broader knowledge of the depositional system that influenced those patterns. Key factors 115 are basin architecture, sea level fluctuation, and knowledge of environmental gradients (e.g. 116 oxygenation, wave energy) at different locations across the depositional landscape. To meet these 117 requirements our multidisciplinary approach uses borehole geophysical, lithological and biozonal 118 data to understand stratigraphical patterns and model sediment geometry; geochemistry to 119 interpret sea level fluctuation and its impact on the length of sediment pathways; and biofacies data 120 to infer environmental signals across contrasting basin settings. The large archive of subsurface data 121 (borehole core, geophysics, biostratigraphy) for the Peterborough Member held by the British 122 Geological Survey (BGS) provides both the spatial extent and stratigraphical resolution required by 123 the scale of this study. 124 3.1 Regional geophysical log interpretation 125 The inflection patterns of borehole geophysical logs in the Oxford Clay are usually sufficiently 126 distinctive to allow recognition of its component formations (Whittaker et al. 1985, Penn et al. 127 1986), with the elevated organic content of the Peterborough Member typically corresponding with 128 a higher gamma log response. Stratigraphic picks for the Oxford Clay were made mostly from gamma 129 ray and sonic logs for ca. 127 boreholes across southern, central and eastern England and adjacent 130 areas of the Channel and Southern North Sea basins (Figs 1, 3 and 4). Where present, stratigraphical 131 picks were made for the top of the Great Oolite Group (Cornbrash Formation), Kellaways Formation, 132 Peterborough Member, Stewartby Member and Weymouth Member, as well as associated 133 unconformities and faulted contacts. An important first step in this process was calibrating log 134 responses against known Oxford Clay stratigraphy in boreholes that, in addition to a suite of 135 geophysical logs, had associated core (Callomon and Cope 1971, Whittaker et al. 1985, Penn et al. 136 1986, Bristow et al. 1989, 1995 fig. 36) and biostratigraphical data (Gallois 1979, Cox 1977, 1984, 137 6 FIGURE 3 138 7 FIGURE 4 139 8 1988, 1991, Gallois and Worssam 1983, Buckley et al. 1991). These reference boreholes provided an 140 important constraint on extending stratigraphical interpretations into boreholes where only 141 geophysical logs and cuttings information were available. Interpretations were checked for internal 142 consistency using a grid of intersecting borehole correlation panels, and by flattening correlations on 143 multiple horizons to explore stratigraphical and structural trends. 144 Stratigraphic picks were subsequently used to create a refined thickness model of the 145 Peterborough Member and wider Oxford Clay Formation. Maps were interpolated using Discrete 146 Smooth Interpolation (DSI) (Mallet 1989) in SKUA-GOCAD™ software from borehole thickness data 147 that was corrected for both deviated borehole paths and variable structural dip. 148 3.2 Lithological data 149 Lithological information is provided by pre-existing boreholes in BGS archives, supplemented by two 150 newly drilled boreholes near Christian Malford, Wiltshire (Fig. 1), as well as information collated 151 from published records, BGS technical reports and unpublished borehole logs in BGS data archives. 152 The boreholes at Christian Malford are continuously cored and provide an important record of the 153 succession across the Coronatum/Athleta Zone boundary (Fig. 2) in an area where data are sparse. 154 Pre-existing borehole data (boreholes 2, 4, 9 – 11 of Fig. 2) relate to historical BGS work on the 155 Oxford Clay, and are represented by discontinuous core samples. These boreholes were selected 156 from the BGS archive to optimise core sample density (typically 0.1 m or less) and provide 157 representative stratigraphical and geographical coverage of the Peterborough Member. Lithological 158 descriptions of discontinuous core samples were made using a binocular microscope during 159 acquisition of biofacies data for these successions (see 3.4 below), and the observations used to 160 construct synthetic graphical borehole logs, supplemented by information from pre-existing logs and 161 reports where available and relevant. 162 3.3 Geochemistry 163 A newly drilled cored borehole (CM11; Fig. 1) in the higher part of the Peterborough Member 164 (Coronatum & Athleta biozones; Fig. 2) at Christian Malford, Wiltshire, provided material for 165 geochemical analysis (Fig. 5). Borehole CM9, drilled as part of a previous investigation at Christian 166 Malford (Hart et al. 2016, 2019) and partially overlapping with CM11, provided material for analysis 167 in the higher part of the Phaeinum Subzone. 168 Geochemical data were obtained from slabbed core lengths of CM11 using a portable Niton 169 XLt 793 X-Ray Fluorescence Spectrometer (XRFS), fitted with a 40kV Ag anode X-ray tube and using 170 the ‘Standard Soil Mode’. Measurements were made at 10 mm intervals and for 30 seconds along 171 the core length, with values checked for internal consistency against a designated standard 172 reference sample. This procedure was repeated for the partially overlapping succession in CM9 using 173 selected milled samples of core material, analysing for 120 seconds with the XRFS in a static semi-174 automated configuration. 175 176 3.4 Biofacies & biozonal data 177 Biofacies data (Figs 5 – 9) characterise stratigraphical intervals according to the types and 178 abundances of fossil material, and use understanding of palaeoecological affinities of facies 179 components to infer environmental signals. The technique can reveal patterns of environmental 180 change that can be compared with variability in the lithological character of host sedimentary 181 successions. Previous work on the Peterborough Member (Duff 1974, 1975) has used biofacies from 182 outcrop data for a limited part of the depositional basin to understand stratigraphical shifts in 183 depositional conditions. This work expands application of these data to a network of sites across the 184 9 wider depositional basin in southern and eastern England, selected to capture responses in a 185 probable diverse range of environmental settings in contrasting palaeogeographical and structural 186 settings. We analyse the distribution of biofacies components in borehole core using 187 correspondence analysis and clustering to explore their relationships and patterns in their 188 stratigraphical distribution. 189 Biofacies data for the Peterborough Member, comprising more than 2200 observations of 190 core samples, were compiled for the following 8 cored borehole sites (Fig. 1): Christian Malford CM9 191 and CM11 (distal shallow marine shelf), Down Ampney 2 (proximal shallow marine shelf), Combe 192 Throop (intra-basinal high), Kimmeridge 2 (deep marine shelf), Warlingham (faulted epicontinental 193 basin margin), Ashdown 2 (distal marine epicontinental basin), Parson Drove (shallow marine 194 platform), and Eriswell (shallow flooded massif margin). 195 For the Christian Malford (CM11) Borehole, biofacies data were collected from half-core 196 samples (10 cm diameter) at 10 mm intervals, examining part and counter-part bedding surfaces. 197 Biofacies components (Appendix 1) assessed as part of this study cover a range of taxonomic 198 groupings, mostly genera but including some broader categories (e.g. ammonites, foraminifera) 199 where appropriate, and also include the occurrence of features like wood and coprolite. Relative 200 frequency of key biofacies components (Appendix 1) was assessed using a semi-quantitative scale, 201 based on threshold counts (present; common, 2 – 4 specimens; abundant, ≥5 specimens; plaster, 202 with numerous specimens covering core surface). Biofacies data for the other boreholes rely on 203 discontinuous core samples, for which observations of all surfaces of each sample are combined into 204 a single record with a modified assessment of relative frequency (present; few, 2 specimens; 205 common, ≥3 specimens). Biofacies data for the Peterborough Member, collected at sites in eastern 206 and central England (Duff 1974, 1975) and re-analysed as part of this work, are fully quantitative 207 observations of aerially extensive bedding planes. 208 Statistical analysis of biofacies data uses a combination of Detrended Correspondence 209 Analysis (DCA) and clustering (hierarchical clustering & Non-Euclidian Relational Clustering (NERC)) 210 to explore: 1) the faunal composition of different samples; and 2) the grouping of samples into 211 coherent biofacies. NERC clustering is typically more suited to analysis of palaeontological data 212 which are incomplete (Vavrek 2016). However, because our data are from borehole core, with an 213 implied age/depth relationship between consecutive samples, we combine both hierarchical and 214 NERC clustering techniques in our results. 215 Primary data were conditioned by: removal of rare/ambiguous components that might 216 otherwise distort the analysis; merging records of related components (e.g. species within a genus); 217 coding sample composition, sample size and biozonal assignment, and standardising scale of relative 218 frequency (see Supplementary Data for detailed procedure). All statistical analyses were performed 219 in the open source environment R (R Core Team 2020) using the following packages: vegan (Oksanen 220 et al. 2018) (DCA analysis based on upper quartile biofacies components); NbClust (Charrad et al. 221 2014) (optimum number of clusters for each borehole based on analysis of primary data); rioja 222 (Juggins 2017) (hierarchical clustering); ecodist (Goslee and Urban 2007) (calculation of ecological 223 distance matrix); fossil (Vavrek 2016) (NERC cluster analysis). An ecological distance matrix is 224 required for NERC clustering, and for our semi-quantitative data we adopt the Sørenson dissimilarity 225 index (or Dice index), one of the most commonly used and effective presence/absence dissimilarity 226 measures (Southwood and Henderson 2000, Magurran 2004). Compilations of biofacies data for the 227 analysed boreholes and details of their statistical analysis are provided as Supplementary Data. 228 The boreholes that are the source of our biofacies data are part of a larger suite of cored 229 boreholes in the Peterborough Member across southern Britain, drilled in connection with BGS 230 regional mapping programmes that date back to the late 1960s. Biostratigraphical interpretations of 231 many of these successions, published in BGS memoirs and technical reports, were compiled for this 232 10 study to provide precise stratigraphical understanding of geophysical log signatures, to allow 233 accurate comparisons of biofacies data, and to provide additional insight into patterns of thickness 234 variation. 235 Supplementary material: Geophysical log correlations, geochemical data and detailed biofacies 236 data, methodology and results are available as Supplementary Data. 237 4. Results 238 Geophysical log data provide a highly resolved picture of thickness variation for the Peterborough 239 Member across Southern Britain, with correlation panels and biostratigraphical data compilation 240 emphasising regions that were the long-term focus of sedimentation and others where deposition 241 was persistently restricted (Figs 3, 4; 10). Cyclical trends in sedimentary geochemical data at 242 Christian Malford (Fig. 5) show a strong relationship with patterns of sedimentation and biofacies in 243 borehole core. Across the basin, biofacies data show significant lateral contrasts between sites (Fig. 244 6). The results for each category of data are discussed in turn below. Detailed compilations of our 245 results are provided as Supplementary Data. 246 4.1 Geophysical log correlation and basin modelling 247 Along the northern margin of the Anglo-Brabant Massif (ABM), from the East Midlands Shelf in the 248 NE, towards the Wessex Basin in the SW, there is a consistent regional trend of thickening, for both 249 the Peterborough Member (<5 m to >55 m) and Oxford Clay Formation as a whole (<10 m to ca. 180 250 m) (Figs 3, 4). Significant thinning of the Peterborough Member (to ≤ 10 m) occurs on the flanks of 251 the ABM, and likely also the whole of the Oxford Clay, although erosion of the succession prevents 252 confirmation. The succession remains thin into the Weald Basin to the south, where the total Oxford 253 Clay Formation is about 80 m thick in the Ashdown 2 Borehole, with ca. 15 m representing the 254 Peterborough Member (Fig. 3). Offshore thickness trends are consistent with the onshore data, with 255 extremely thin (possibly incomplete) Oxford Clay inferred to occur in the southern North Sea (where 256 the formation is generally not separated from the parent Humber Group), and relatively thick 257 Peterborough Member (ca. 42 m) forming part of an eroded Oxford Clay succession in the Channel 258 Basin. As well as basin-scale features (e.g. ABM), there is an apparent association of local thickness 259 patterns with 1:1500000 -scale structural lineament data (Fig. 3A), seen in parts of the Wessex Basin, 260 for example local thickening near Shrewton, and thinning across the fault-bounded Norton Ferris 261 High (Chadwick and Evans 2005, figs 86, 88). 262 4.2 Lithology 263 Borehole CM11 proved a strongly cyclical succession of lithofacies that can be matched with 264 geochemical data (4.3 below; Fig. 5). Three broad lithofacies are recognised in borehole core: 1) pale 265 grey silty mudstone with abundant shell remains, dominated by nuculacean bivalves, including 266 specimens with articulated valves; 2) massive or very weakly fissile, medium – grey-brown silty 267 mudstone with scattered or sparse shell remains, but including occasional bedding-plane plasters of 268 the bivalves Meleagrinella and/or Bositra and, 3) dark grey-brown, organic-rich laminated mudstone 269 with abundant plasters of Bositra and/or Meleagrinella. The bases of shell beds may be sharply 270 defined or gradational, and cycles comprise either: 1) sharp-based shell bed with thin gradational 271 intervals of weakly fissile mudstone into dark laminated mudstone (Type 1; Fig. 5), or 2) weakly 272 fissile mudstone, with thicker gradational transition into a shell bed (Type 2; Fig. 5). Type 1 cycles are 273 thin (ca. 30 cm) and occur in the middle part of the borehole succession, and Type 2 cycles are 274 thicker (ca. 70 cm) and occur particularly in the higher parts of CM 11 (Fig. 5). 275 276 11 FIGURE 5 277 12 For sites across the rest of southern England, lithological data summarised on synthetic 278 borehole logs (Fig. 6) show that in the Wessex Basin, conspicuously silty mudstone dominates in the 279 lowest part of the Peterborough Member (Calloviense and Jason Zones) in the Kimmeridge 2 and 280 Combe Throop boreholes. In the Kimmeridge Borehole this diminishes with the appearance of dark 281 grey mudstone in the Coronatum Zone, but remains a persistent feature of the Combe Throop 282 succession. Bioclastic mudstone is a feature of the Coronatum Zone in the CM 9 and CM11 283 boreholes, and extends north-eastwards, in both the Down Ampney 2 and Parson’s Drove 284 successions. In the Phaeinum Subzone, the rhythmic mudstone in CM9 and CM11 cannot be traced 285 into the Down Ampney 2 succession. Here, this interval contains a sharp contrast between darker 286 grey mudstone in the lower part of the subzone and much paler grey, biotubated mudstone in the 287 upper part. This change occurs immediately above a ca. 2.5 m thick laminated interval in the lower 288 part of the Phaeinum Subzone, that contains few fossils apart from wood, foraminifera and bone (Fig 289 6), and is unique to this borehole succession. A similar colour change occurs near the top of the 290 Peterborough Member in the Parson Drove succession on the East Midlands Shelf, although here the 291 lithology is laminated and silty, with greater development of dark mudstone in the underlying 292 Phaeinum Subzone. On the flanks of the ABM, the Coronatum Zone and Phaeinum Subzone in the 293 Eriswell Borehole comprises thin units of distinctively pale and medium grey, bioturbated mudstone 294 with abundant finely comminuted shell. The correlative interval thickens at the edge of the Weald 295 Basin in the Warlingham Borehole, where the lithology is rather uniformly bioclastic mudstone with 296 occasional laminated intervals, becoming distinctly silty in the upper part. The sparse data for the 297 central Weald Basin, from the Ashdown 2 Borehole, suggest a very different pattern of 298 sedimentation, with samples from the ?Coronatum Subzone represented by very dark brownish-299 grey, hard, silty, pyritic calcareous mudstone. 300 301 4.3 Geochemistry 302 303 Titanium in the Peterborough Member shows a strong correlation with silica (Norry et al. 1994), and 304 functions as a proxy for variability in the flux of hydrodynamically heavy detrital components to the 305 depositional basin and/or winnowing. Figure 5 plots the variability of Ti normalised to K (the optimal 306 proxy for understanding detrital fluxes in the absence of XRF values for Si, Zr and Al) through the 307 CM11 and CM9 successions. The plot shows a strongly cyclic pattern, with an overall shift from 308 relatively high values in the lower 2.5 m of the succession (Coronatum Zone), to relatively lower 309 values in the middle part (interval above S4 and below S10 of Fig. 5), spanning the latest Coronatum 310 and earliest Athleta zones. Shell concentrations are picked out by the Ca/K plot, with those 311 characterising the Type 1 cycles in the CM11 succession forming four strong, closely spaced peaks 312 (S4 – S7; Fig. 5). An inflection in the trend of Ti/K data, from sharply falling to gradually increasing, is 313 coincident with the interval between two regionally extensive marker-beds in the Oxford Clay, the 314 Comptoni Bed and the overlying Acutistriatum Band (Hudson and Martill 1994; Fig. 5). Above these, 315 peaks S9 – S15 define a stacked succession of Type 2 cycles, with progressively increasing detrital 316 content and shell beds coincident with sharp peaks in the Ca/K curve. 317 318 4.4 Biofacies 319 Litho- and biofacies variation occurs on a very fine (lamina) scale in the Oxford Clay (Macquaker and 320 Howell 1999). Our biofacies data resolves this fine-scale variation into decimetre-scale trends, 321 represented by the stratigraphical distribution of biofacies clusters (Figs 5 – 9), with the composition 322 of each cluster summarised as relative proportions in bar charts below each borehole log. The 323 number and composition of clusters is distinct for each site and determined by the data available for 324 13 FIGURE 6 325 14 FIGURE 6 (continued) 326 15 each site. Attempts to develop a unified biofacies classification across all sites forced removal of 327 components that were defining and common at individual sites, suggesting a significant degree of 328 site-specific biofacies character. Consequently, stratigraphical analysis of our biofacies data focuses 329 on identifying major contrasts in the arrangement and composition of biofacies within borehole 330 successions, and examining the extent to which these correspond with analogous or strongly 331 contrasting biofacies in correlative successions at other sites across the basin. 332 DCA plots of samples and taxa provide insight into which taxa are important for 333 characterising samples. DCA analysis for CM11 (Fig. 8A) is consistent with observations made during 334 borehole logging, and indicate two strongly contrasting end-members: 1) dark, organic-rich, fissile 335 mudstone dominated by remains of the thin-shelled bivalve Bositra (with or without Meleagrinella); 336 2) Shell beds associated with pale grey mudstone with abundant thick-shelled nuculacean bivalves, 337 often associated with the gastropod Procerithium and sometimes also the serpulid Genicularia. 338 Most biofacies clusters comprise mixtures of these end member components, and are therefore 339 environmental composites that reflect the extent to which particular environmental settings are 340 more or less dominant at the scale of individual laminations. 341 Differences between biofacies cluster composition for a given borehole can be subtle or very 342 significant. Both the Warlingham and Parson Drove boreholes show a strong pattern of 343 stratigraphical specificity in the distribution of biofacies clusters, but several of the cluster 344 compositions are very similar, suggesting either a limited range of environmental change at these 345 sites, or smearing of the ecological signal by external factors. It is notable that the extremely shell-346 rich Warlingham succession is characterised by an incongruent mixture of biofacies components 347 (e.g. Bositra, Meleagrinella, nuculacean bivalves, Genicularia; Fig. 6) that characterise discrete 348 intervals elsewhere. 349 The successions in the Kimmeridge 2 and Combe Throop boreholes show a regular repetition 350 of biofacies clusters, with a tendency for particular biofacies to be slightly more dominant at some 351 levels (Fig. 6). Kimmeridge 2 also shows a pronounced stratigraphical and compositional shift in 352 biofacies at the top of the core log. In the Down Ampney 2 succession there is more marked 353 domination of particular intervals by particular biofacies clusters (Fig. 6), and these are also more 354 compositionally distinct, a pattern that is even more pronounced in the CM11 succession. The 355 largest number of biofacies clusters are associated with the highly condensed Peterborough 356 Member section at Eriswell (Fig. 6). Despite this, there is a strong unifying compositional feature (a 357 high proportion of shell hash and relative paucity of ammonites) that is unique to this site. Data for 358 Ashdown 2 are limited, but are notable for the extremely high proportions of bone and the bivalve 359 Bositra in all biofacies clusters. 360 To explore the fidelity of our biofacies methodology and provide additional 361 palaeoenvironmental data, we have used the raw quantitative data collected by Duff (1975) as part 362 of his biofacies interpretation of the Peterborough Member (at Norman Cross near Peterborough, 363 Stewartby, Bletchley and Calvert) to generate biofacies classifications based on NERC clustering. 364 Figure 7 shows the correlation of the sections and compares the biofacies assignments of Duff 365 (1975) with those assigned using NERC. Both facies classifications show striking similarity in the 366 broad pattern of biofacies subdivisions for different biozonal intervals. The youngest and oldest 367 parts of successions show significant facies variability in both interpretations, with less variation in 368 the intervening part (Jason & Obductum subzones). In some cases there is direct correspondence of 369 biofacies recognised by Duff (1975) with biofacies clusters defined by NERC, and in other cases the 370 NERC analysis appears to be detecting contrasts identified by Duff (1975) although the boundaries of 371 these units are not necessarily coincident. These patterns, and the similarity in the taxa that define 372 distinct nodes in the DCA sample distribution (e.g. Bositra, Meleagrinella, nuculaceans, oysters; Fig. 373 374 16 FIGURE 7 375 17 9) to other localities examined as part of this study (Fig. 8), suggests our combined NERC – DCA 376 methodology is robust in identifying meaningful environmental gradients. 377 NERC biofacies data for the localities described by Duff (1975) show that, generally, the 378 oldest parts of the succession (Enodatum/Medea subzones) seen at Norman Cross and Bletchley are 379 relatively rich in ammonites and oysters, but including at Norman Cross thin intervals with sharply 380 contrasting facies, where these faunal elements are sparse and Bositra more dominant. Higher in the 381 succession (Jason/Obductum subzones), facies at most localities are dominated by a mixture of 382 Bositra, Meleagrinella and nuculacean bivalves, with the Obductum Subzone at Norman Cross and 383 Stewartby having a relatively higher proportion of Bositra compared to the corresponding interval at 384 Calvert. The distinctly more cyclic facies of the Grossouvrei Subzone contains frequent shell beds in 385 the Duff (1975) facies classification, corresponding with NERC facies clusters in which Meleagrinella 386 and/or nuculacean bivalves tend to be more dominant compared to Bositra. The appearance of 387 more shell-dominated facies appears somewhat delayed at Stewartby, occurring some distance 388 above the base of the Grossouvrei Subzone. Scattered through the succession are relatively thin (ca. 389 1 m or less) organic-rich mudstone units identified by Duff (1975) as Grammatodon-rich Bituminous 390 Shale, with apparently no consistent relationship to NERC biofacies clusters, and containing 391 relatively low proportions of Bositra and Meleagrinella and high concentrations of deposit-feeding 392 and infaunal suspension-feeding bivalves (particularly Grammatodon, nuculacean bivalves and the 393 gastropod Procerithium). Apart from these horizons, Grammatodon is absent from most of the 394 Peterborough Member. 395 Overall, the results suggest that there are strong site-specific factors influencing the 396 composition and successions of biofacies, with stratigraphical persistence of the distinct character of 397 sites suggesting that this pattern is not a consequence of chance variation in palaeoecological 398 conditions. Detailed results of biofacies analysis for individual boreholes are discussed below in the 399 context of environmental interpretations. 400 4.5 Biozonal data 401 Compilation of biozonal data for the Peterborough Member (Fig. 10) in boreholes extending along 402 the same NE – SW alignment as our model thickness data reveals: 1) SW thickening is largely driven 403 by expansion of biozones in the lower part of the Peterborough Member; 2) the Eriswell Borehole, 404 located close to the ABM, shows maximum thinning of biozones, but expansion north-eastwards 405 away from this structural feature and towards the East Midlands Shelf and Southern North Sea is 406 muted, with the thickness of the Coronatum Zone in the Tydd St Mary and Parson Drove boreholes 407 similar to Eriswell. 408 5 Discussion 409 To understand the degree and likely causes of facies heterogeneity in the Peterborough Member 410 we: 1) use our modelled thickness data to resolve depositional geometry in the context of basin 411 structure and palaeogeography; 2) review existing sequence stratigraphy understanding for the 412 Peterborough Member in light of our new geochemical and regional biostratigraphical data to 413 establish a framework for understanding sea level variability, and 3) combine knowledge of (1) and 414 (2) to develop a conceptual basin model that explains contrasts and similarities in biofacies patterns, 415 and the extent to which they reflect basin-scale trends in mudstone variability. Finally, we make 416 comparisons with other well-known organic-rich Jurassic mudstone successions. 417 The constituent taxa of our biofacies have been the subject of previous work to understand 418 patterns of ecological change in the Peterborough Member, which are primarily controlled by 419 seabed oxygenation and/or substrate consistency (Duff 1975, Martill et al. 1994, Kenig et al. 2004). 420 421 18 FIGURE 8 422 19 FIGURE 9 423 20 Since our biofacies carry an ‘averaged’ environmental signal, our ecological conceptualisation of 424 them (below) is necessarily simplified, effectively dampening short-term environmental “noise”. 425 Here, we follow previous authors (Kauffman 1981, Etter 1996; Caswell et al. 2009; Danise et al. 426 2015) in regarding Bositra and Meleagrinella as opportunist suspension feeding taxa, tolerant of low 427 oxygenation. In the context of previous work by Kenig et al. (2004) using geochemical data to 428 understand environmental signals in the biofacies of the Peterborough Member, and the 429 relationship of biofacies to Ti/K data in the CM11 succession, end-members (4.4 above) represented 430 by (1) Bositra -rich organic mudstone and (2) nuculacean shell beds (+/- Procerithium, Genicularia) 431 are interpreted to correspond with low oxygen (anoxic or dysoxic) and more oxygenated (oxic) 432 settings, respectively. Meleagrinella-dominated successions appear to occupy a position between 433 these two end members. 434 5.1 Basin geometry and palaeogeography 435 Modelled thicknesses reveal clear trends in the depositional pattern of the Peterborough Member, 436 with distinctly wedge-shaped regional thickness geometries characterising the unit and wider Oxford 437 Clay along the northern edge of the ABM, from the Southern North Sea into the Wessex Basin (Fig. 438 3), as well as from the eastern Weald westwards (Fig. 4). However, the palaeogeographical settings 439 of these two regions are strongly contrasting in terms of likely sediment accommodation space (Fig. 440 1), suggesting that the similar geometries are a product of different processes. Along the northern 441 margin of the ABM, north-eastward thinning closely corresponds with flanks of the Mid North Sea 442 High, and the modelled thickness variation (Fig. 3A) seems consistent with a palaeobathymetric 443 gradient from relatively shallow water conditions around this semi-emergent feature to deeper 444 water conditions in the Wessex Basin. Certainly, there is evidence in the younger Corallian Group for 445 the margins of the Mid North Sea High being associated with the development of shallow-water 446 facies (Cameron et al. 1992), and it seems probable that prior to this the broad area of crust affected 447 by North Sea doming (>1250 km diameter; Underhill and Partington 1993) extended to the East 448 Midlands Shelf during deposition of the Peterborough Member. 449 Modelled thinning of the Peterborough Member and total Oxford Clay Formation across 450 much of the Weald Basin is striking and consistent with biozonal data from cored boreholes (Fig. 10), 451 including the Grove Hill [TQ 6008 1359] and Brightling No. 1 [TQ 6725 2182] boreholes in Sussex 452 (Lake et al. 1987). This sharply contrasts with the significant thickening seen in this area during 453 deposition of the prior Inferior and Great Oolite groups and subsequent Late Jurassic succession 454 (Whittaker 1985). The conclusion from our modelling is that this area is likely to have been relatively 455 sediment starved. 456 From the thick successions of Peterborough Member in the Wessex Basin there is evidence 457 of a slight thinning trend into the Channel Basin, particularly seen in the pattern of biozonal data for 458 Dorset (Fig. 10). This may reflect greater ability of the Wessex Basin to create additional 459 accommodation space through sediment loading, with some differential compaction across fault 460 lineaments potentially suggested by thickness data in the vicinity of the Shrewton Borehole (Fig. 3C). 461 5.2 Cyclicity and Sequence Stratigraphy 462 New geochemical data for Christian Malford, and its relationship to lithological features in borehole 463 core (Fig. 5), allows interpretation of likely patterns of relative sea level change during this time. 464 Combined with our basin-wide synthesis of biostratigraphical data (Fig. 10), and previously reported 465 observations of Mid/Late Callovian successions in the wider UK region (including data for the Moray 466 Basin), we outline a sequence stratigraphy framework for the Peterborough Member that can be 467 used to understand controls on the pattern of deposition and potentially also decimetre-scale trends 468 in biofacies data. Whilst often considered as a separate depositional entity, the succession 469 21 FIGURE 10 470 22 developed on the margin of the Moray Basin (at Brora) shows noted similarity with that of eastern 471 England (Page 2002); there is broad coincidence in the stratigraphical horizon of intervals showing 472 particular sequence stratigraphical responses (e.g. progradation, maximum flooding), and 473 palaeogeographical evidence supports probable wider marine connectivity with the Oxford Clay 474 depositional system (Davies et al. 1996). 475 5.2.1 Current knowledge framework 476 The oldest part of the Peterborough Member, and coeval parts of the Heather and Brora 477 Argillaceous formations in the Moray Basin (Fig. 2), relate to marine flooding at the base of the 478 Enodatum Subzone and regression in the overlying Jason Zone (Davies et al. 1996, Nagy et al. 2001, 479 Hesselbo 2008). At the type Peterborough section, initial flooding and later sea level fall corresponds 480 with the ‘Gryphaea and Reptile Beds’, comprising a thin (1.2 m) unit of fissile pyritic mudstone rich in 481 the oyster Gryphaea, consistent with shallow water oxic conditions (Duff 1975, Hudson and Martill 482 1994, Kenig et al. 2004). Maximum Flooding surfaces are usually associated with thickening of the 483 associated stratigraphical intervals towards the basin margins where sediment becomes ponded on 484 newly created shelf areas (Catuneanu et al. 2011). The thin Enodatum Subzone at Peterborough 485 (compared to more basinal setting; Fig 10) suggests either a very proximal setting at the maximum 486 extent of flooding, and/or significant erosion associated with later sea level fall. 487 Thickening of the Jason Zone into the Wessex Basin (Fig. 10) is consistent with relative sea 488 level fall focussing sedimentation towards available accommodation space in more distal areas. In 489 this context, organic-rich facies in the higher part of the Jason Zone at Peterborough (Bed 10 of 490 Hudson and Martill 1994), sandwiched between Gryphaea-rich intervals, probably reflects the 491 development of anoxia in a relatively shallow water setting, possibly in response to restricted local 492 circulation (ponding, boosting organic matter preservation) associated with sea level fall. Sandstone 493 in the likely Jason Zone at Stewartby (Bedfordshire), ca. 60 km to the south-west, is interpreted to 494 reflect winnowing or bypass of fine -grained sediment in a more proximal setting (Macquaker 1994), 495 providing further evidence of limited local sediment accommodation space close to the basin margin 496 at this time. 497 Relative sea level fall is inferred to have continued into the early Coronatum Zone before 498 rising in the later part of the Zone (Hesselbo 2008). In the Moray Basin this phase is represented by a 499 wedge of coarse, glauconitic sandstone (Nagy et al. 2001), and by stacked parasequences in the 500 Peterborough succession showing a trend of increasing up-section silt content (Macquaker and 501 Howell 1999). These successions may be a response to lack of accommodation space caused by 502 relative sea level fall, and/or reflect the rapid advance of sediment into limited areas of newly 503 created accommodation space during early transgression. 504 5.2.2 Completing the knowledge framework 505 The remainder of the Peterborough Member reflects rising relative sea level, peaking in the lower 506 part of the Phaeinum Subzone (Hesselbo 2008) and consistent with a widespread Maximum 507 Flooding Surface recognised in the Moray Basin (Davies et al. 1996, Nagy et al. 2001). Trends in the 508 Ti/K data from the Christian Malford Borehole CM 11 are a proxy for the delivery of coarse detrital 509 components to the depositional site, and shed new light on the pattern of environmental change 510 represented by the upper part of the Peterborough Member. We regard the regular cyclical pattern 511 of Ti/K data in the Christian Malford succession (Fig. 5) as analogous to the systematic trends in the 512 silt-content used by Mcquaker (1994) and Mcquaker and Howell (1999) to understand fluctuations in 513 the length of sediment transport pathways between source and sink caused by relative sea level 514 change. Individual cycles fine-up (Type 1 cycle) or coarsen-up (Type 2 cycle) and can be grouped into 515 broader associations showing overall reductions in Ti/K or overall increases in Ti/K. These broader 516 23 cycle trends, and the inflection points between these trends are used to infer likely changes in 517 sediment accommodation space and to make interpretations of sequence stratigraphy. 518 The decline in the Ti/K ratio in the lowest ca. 1 m of the CM11 succession (Grossouvrei 519 Subzone; Fig. 5), terminating abruptly at a peak in the Ca/K ratio (‘C’ of Fig. 5) suggests that an 520 increase in accommodation space acted to reduce the flux of detrital material to this site. The 521 conspicuous ammonite/foraminifera concentration at ‘C’ likely represents a period of sharply 522 reduced sedimentation rate in response to sea level rise. Three cycles in the Ti/K ratio (S1 – 3, Fig. 5) 523 in the overlying ca. 1.5 m of mudstone correspond with alternating paler and darker grey mudstone 524 units, and show an overall upward increase in Ti/K. This trend through cycles S1 – 3 suggests 525 progressively enhanced delivery (progradation) of coarser-grade sediment to the depositional site 526 associated with shortening of sediment pathways. These are analogous to the parasequences 527 described in the lower part of the Peterborough succession by Macquaker and Howell (1999). The 528 largest peak (S3, Fig. 5) in Ti/K marks the beginning of a sharp upward shift to significantly lower Ti/K 529 values that persists through several metres of the overlying succession. This peak is interpreted to 530 represent a major pulse of marine transgression associated with current winnowing on newly 531 flooded areas and significant increase in available accommodation space. 532 The four closely spaced Type 1 cycles (see above) in CM11, corresponding with peaks S4 – S7 533 (Fig. 5), are interpreted to represent a series of transgressive pulses, initially marked by sediment 534 winnowing events, separated by periods with less current scour. The overall reduction in the Ti/K 535 ratio through this interval is consistent with an increase in accommodation space and lengthening of 536 sediment pathways. The major Ti/K peak (S4) associated with the lowest shell bed suggests that this 537 was a particularly strong/prolonged pulse of transgression. It coincides with a major shift in 538 biofacies, a sharp upward decline in the abundance of wood potentially reflecting increased distance 539 from shorelines, and a decline in foraminifera that is a possible response to increased current scour 540 (Fig. 5). Sharp/erosive (‘X’ Fig. 5) bases to the shell beds are consistent with significant current scour 541 which was probably important for oxygenation and colonisation of seabed sediment by the infaunal 542 bivalves that dominate these units. Minor Ti/K peaks (S5 – 7; Fig. 5) that cap subsequent shell beds 543 suggest a phase of enhanced off-shelf movement of mobile sediment from newly flooded areas by 544 wave scour following each transgressive pulse (including material swept across the site into more 545 distal settings). The alternation of shell-rich units and intervening mudstone is matched by a 546 pronounced oscillation in biofacies (Fig. 5). The less diverse fauna, dominated by foraminifera and 547 the bivalves Bositra and Meleagrinella, in the dark, fissile units that cap the cycles, suggests quieter 548 depositional conditions with less consistent sea bed oxygenation. The Comptoni Bed (peak S8), 549 widely associated with a rolled and winnowed fauna (Hudson and Martill 1994), is inferred to mark 550 the maximum extent of transgression, and therefore the Maximum Flooding Surface. 551 Above the Acutistriatum Band in CM11, the progressive cyclical build-up in Ti/K (Fig. 5, S9 – 552 S14), indicates a major shift in basin evolution. Biofacies at and just above the Acutistriatum Band 553 (and particularly between peaks S9 & S10) are indicative of dysoxic conditions (enrichment in 554 Bositra, coprolite) and are consistent with low sedimentation rates (enrichment in bone), and the 555 Acutistriatum Band is interpreted as a Condensed Section at the base of a Highstand Systems Tract 556 (cf. Catuneanu et al. 2009). The stacked succession of Type 2 cycles (see above) with progressively 557 increasing detrital content that form the remainder of the succession in CM11 and overlapping parts 558 of CM9 are interpreted to form part of a ‘normal regression’ (Catuneanu et al. 2011) during sea level 559 Highstand. Peaks S11 – 15 (Fig. 5), and likely represent the winnowed tops of prograding 560 parasequences, represented by paler and generally more shell-rich mudstone units in borehole core. 561 Reducing amplitude of Ca/K peaks upwards through the interval is probably a response to increasing 562 dilution of shell by sediment influx, whilst the gradational bases of shell beds (‘Y’ Fig. 5) might reflect 563 the ability of infauna colonising parasequences to progressively improve the habitability of deeper 564 24 sediment layers by improving oxic water circulation. Decimetre-thick intervals of dark, organic-rich, 565 fissile mudstones, that are either sparsely shelly or dominated by Bositra and ammonites, represent 566 periods of deposition when creation of new accommodation space (e.g. from minor sea level 567 fluctuation or basin subsidence) outstripped sediment flux, and current circulation was less effective 568 at maintaining seabed oxygenation. Initially, the Type 2 cycles are poorly defined by biofacies data, 569 but around the ‘Squid Bed’ (Fig. 5) and coincident with the horizon of the Christian Malford 570 Lagerstätte (Wilby et al. 2008), the distinction of Bositra-rich intervals suggests an increasing trend 571 towards anoxia/dysoxia. Plateauing of Ti/K values above S14 potentially reflects over-extension of 572 sediment pathways, and diversion of material to adjacent regions with steeper shelf to basin 573 gradients. 574 5.3 Conceptual basin model and mudstone heterogeneity 575 Modelled thickness data for the Peterborough Member, combined with knowledge of the 576 palaeogeographical framework for the Mid Callovian (Figs. 1, 3), suggest that a depth gradient from 577 the Mid North Sea High, and laterally contiguous areas, was likely significant in focusing sediment 578 south-westwards towards the Wessex Basin, potentially augmented by sediment flows via the 579 Worcester Graben. Palaeocurrent data for the Oxford Clay are sparse, but Hudson and Martill (1991) 580 speculated that a large assemblage of belemnites seen at Peterborough (>300 specimens; Martill, 581 1985) with a N – S alignment might reflect the action of currents responsible for removing sediment 582 from the East Midlands Shelf succession and depositing it in deeper parts of the basin. In the Mid 583 Callovian, the Mid North Sea High formed an extensive semi-emergent area arcing around the 584 southern North Sea Basin, with a coal-forming deltaic system in the Central North Sea (Møller and 585 Rasmussen 2003), both providing significant potential for delivery of fine-grained sediment to 586 offshore regions (Fig. 11). Thin and significantly condensed sedimentation on the flanks of the ABM 587 (Figs. 3, 10) suggests that even if not fully emergent, it likely formed a significant structural feature. 588 However, similarly thin Peterborough Member successions in the Weald Basin, where sediment 589 accommodation space is unlikely to have been limited, suggest sediment starvation, with limited 590 supply of sediment from the ABM itself and likely shielding by the ABM from sediment sources 591 further north. 592 In the Wessex Basin, the thick Peterborough Member potentially includes material fed via 593 the Worcester Graben (Fig. 11), which structural and regional gravity data (Chadwick and Evans, 594 2005; Fig. 12) suggest was a long-lived conduit for Mesozoic sediments. Published data for the 595 source of Oxford Clay sediments are lacking, but it is noticeable that thickening of the Peterborough 596 Member occurs in geophysical log transects across the buried mouth of this structure, located north 597 of the current outcrop margin (Fig. 12). Maintenance of accommodation space in the Wessex Basin 598 was probably a response of the highly fractured basement to the extensional stresses responsible for 599 North Sea rifting, coupled with greater potential for compactional subsidence of the thick underlying 600 Triassic and Early Jurassic succession, in contrast to the shallow-buried Variscan basement on the 601 East Midlands Shelf (Whittaker 1985, Map 3). 602 The inferred patterns of sea level change are reflected by variable litho- and bio-facies 603 across the basin, that appears largely a response to local basin setting. Thus, sea level fall in the 604 Jason Zone is associated with the development of organic-rich mudstone in probable shallow water 605 settings on the East Midlands Shelf, whereas coeval strata at Combe Throop and Kimmeridge 2, in 606 the Wessex Basin, contain relatively low proportions of Bositra, and high proportions of oysters, 607 nuculacean bivalves and the deep burrowing bivalve Thracia (Fig. 6), indicative of broadly oxic 608 conditions. Higher in the succession, sea level rise across the Coronatum/Athleta Zone boundary is 609 reflected by a shift to more organic-rich facies at Christian Malford. Further south-west in the 610 Wessex Basin, correlative strata at Combe Throop comprise silty laminated sediments characterised 611 25 FIGURE 11 612 26 by high proportions of both Bositra and nuculacean bivalves (Fig. 6), suggesting more rapidly 613 fluctuating oxic/suboxic/anoxic environments. This plausibly reflects the position of the borehole on 614 the Hampshire – Dieppe High, and perhaps also contrasting conditions affecting the fault-bounded 615 Mere Basin opening immediately to the north (Chadwick and Evans 2005, fig. 85). 616 In the Down Ampney 2 Borehole, 30 km NE of CM11, laminated mudstone facies in the 617 lower part of the Phaeinum Subzone (Fig. 6) contains common wood, bone and foraminifera, but 618 few other fossil remains. The abundance of wood and bone in laminated mudstone facies suggests 619 low rates of sedimentation in a low energy, near-shore setting. The general absence of biota might 620 indicate significant localised freshwater run-off affecting both salinity and potentially also 621 oxygenation. This unusual and unique unit suggests significant influence of local 622 basin/environmental factors. It occurs between two contrasting successions: dark grey laminated 623 bioclastic mudstone in the early Phaeinum Subzone (with biofacies dominated by Bositra, 624 Meleagrinella & nuculacean bivalves) suggesting an intermittently dysoxic marine setting, and pale 625 grey, poorly laminated and conspicuously bioturbated silty and shelly mudstone above (with 626 biofacies dominated by nuculaceans, Procerithium, foraminifera and subsidiary Bositra), suggesting 627 more, oxic, open marine circulation. 628 In the Parson Drove Borehole on the East Midlands Shelf, biofacies clusters with high 629 proportions of Bositra dominate much of the succession, suggesting a persistent pattern of low 630 oxygenation (Fig. 6). Pale grey, silty mudstone facies that dominate most of the Phaeinum Subzone 631 in the Down Ampney succession, only occur near the top of the Phaeinum Subzone in the Parson 632 Drove succession. This interpretation is supported by the sparse record of Genicularia in much of the 633 Pason Drove succession, seen also in the voluminous quantitative data of Duff (1974, 1975) collected 634 from the East Midlands Shelf. Genicularia is an epifaunal suspension feeding serpulid (Duff, 1975) 635 that our biofacies data show is predominantly associated with strongly developed nuculacean shell 636 beds. On DCA data plots (Fig. 8) Genicularia is consistently distant from poles defined by fauna linked 637 to dysoxic environments (e.g. Bositra, Meleagrinella), and Duff (1975) recorded it as a dominant 638 component in his calcareous clay facies, characterised by a diverse fauna including nuculaceans and 639 oysters and low Total Organic Carbon (TOC). With these characteristics, we regard Genicularia in our 640 biofacies data as an indicator of some of the least dysoxic conditions in the Peterborough Member. 641 In the Parson Drove Borehole, Genicularia is present towards the top of the succession, coincident 642 with a shift to much paler grey, silty mudstone (Fig. 6), potentially presaging wider regional 643 environmental change in the later part of the Athleta Zone. 644 The sporadic distribution of the Grammatodon-rich Bituminous Facies of Duff (1975), and its 645 unusual fauna dominated by elements more typical of oxic conditions is enigmatic. Duff (1974) 646 suggested that this facies was likely associated with a slight increase in current activity, and many 647 modern arcid bivalves (like Grammatodon) are adapted to life in unstable environments from which 648 they might be dislodged by currents (Thomas 1978). Such an environment seems unfavourable for 649 the build-up of significant organic enrichment (up to 6.1% TOC; Duff, 1974), unless this was prolific 650 and occurred in periods of relatively short duration (e.g. linked to disturbance of redox boundaries 651 across the East Midlands Shelf by enhanced storm activity). 652 Significant contrasts with the East Midlands Shelf and Wessex Basin occur in the facies at the 653 margin of the ABM at Eriswell, and at Warlingham on the edge of the Weald Basin. At Eriswell, 654 biofacies are consistently rich in broken-up shell material and generally poor in ammonites, where 655 current winnowing in a relatively shallow water setting likely shaped deposition of the thin and 656 condensed succession. The large number of faunal clusters might reflect the development of cryptic 657 omission surfaces separating units with subtly varying faunal composition. Here, the relative rarity of 658 Genicularia is unexpected in a setting that evidence suggests was likely well oxygenated, and may be 659 a response to the high energy marine setting. The main facies response to rising sea level at the base 660 27 of the Athleta Zone in the Eriswell succession is a slight increase in the frequency of ammonites as 661 marine deepening likely strengthened connectivity with open marine settings. In contrast, 662 Genicularia is unusually abundant in the Athleta Zone in the Warlingham succession (CL3, Fig. 6), 663 where the DCA plot and the composition of biofacies clusters (Fig. 6, 9B) show that Bositra and 664 nuculacean bivalves are closely associated and present in high proportions throughout the 665 succession. Here, inferred sea level rise across the Coronatum/Athleta Zone boundary is marked by a 666 subtle change in biofacies composition, largely related to the disappearance of the bivalve 667 Meleagrinella in the lower part of the Athleta Zone. A similar gap in the record of this bivalve is 668 noticeable at other sites (e.g. Eriswell, CM11, Combe Throop), and is likely driven by factors that are 669 not site specific. Thus, at Warlingham, the significance of this bivalve for defining a change in 670 biofacies at the Coronatum/Athleta Zone boundary is largely an indication of the unusual 671 compositional stability of other biofacies components through much of the succession. High 672 concentrations of bone suggest low sedimentation rates and/or in situ sediment winnowing 673 (Boessenecker et al. 2014) causing mixing of faunal components. This process may have been helped 674 by export of winnowed sediment from the adjacent ABM, potentially aided by Callovian syn-675 depositional normal faulting at the margin of the Weald Basin (Holloway 1985), creating a steep 676 sediment pathway. Further out into the Weald Basin the conditions influencing deposition are 677 unclear. The thin succession and evidence of pyritic and organic-rich lithologies rich in Bositra and 678 bone seen in Ashdown 2 Borehole, suggest a poorly oxygenated, sediment starved setting. 679 6. The Peterborough Member in context 680 Facies patterns in the Peterborough Member appear more laterally variable than other organic-rich 681 Jurassic mudstone units in SE Britain, like the underlying Lias Group and overlying Kimmeridge Clay 682 Formation (Wignall 1991, Taylor et al. 2001), in which depositional patterns are predominantly 683 modulated by Milankovitch climate cycles (Weedon et al., 2004, Pearce et al. 2010, Xu et al. 2017) or 684 major oceanographic change (Toarcian Oceanic Anoxic Event (OAE); McArthur et al. 2008). The 685 evidence from this work is that basin palaeogeography produced a more laterally variable response 686 of facies in relation to relative sea level change in the Peterborough Member. This facies variability 687 may, at least in part, reflect the timing of deposition of the Peterborough Member, which occurred 688 at a relatively early stage in a cycle of broader sea level rise following rifting, potentially providing a 689 more dynamic and accentuated basin environment for its deposition compared to other Jurassic 690 mudstones. The contrasting development of organic-rich mudstones in the lower Phaeinum 691 Subzone at Christian Malford, compared to some more distal parts of the Wessex Basin, might not 692 only reflect the influence of complex structure transecting the basin; it might also indicate that 693 shallower regions of the basin margin more easily became thermally stratified and anoxic. This is 694 somewhat analogous to transgressive nearshore black shales described by Wignall and Newton 695 (2001) in the Kimmeridgian, and by Leonowicz (2016) in the Middle Jurassic of Poland, although the 696 Christian Malford organic mudstone succession appears to represent deposition during early 697 Highstand and also in a more distal, though not basinal, setting. 698 Although some previous workers have characterised the Callovian as an OAE (Hautevelle et 699 al. 2006, Soua 2014), widespread deposition of organic-rich facies (Dromart et al. 2003, Martinez 700 and Dera 2015) appears more strongly related to continental rifting (Robertson and Ogg 1986) and 701 the creation of intra-shelf basins (Carrigan et al. 1995). These widely distributed but more localised 702 tectonic settings, coupled with marine transgression and a nutrient supply fed by humid climate 703 weathering, seem likely to have been controlling influences in both organic matter accumulation in 704 the Callovian, and the demise of contemporary shallow-water carbonate platforms (Hautevelle et al. 705 2006, Andrieu et al. 2016). 706 707 28 FIGURE 12 708 709 Termination of Callovian organic matter sequestration that defines the Peterborough 710 Member coincides with evidence of southward migration of polar and sub-polar waters across the 711 Eur-Russian area and a major shift in the Late Jurassic climate system (Dromart et al. 2003, Dera et 712 al. 2015). This may have been a consequence of carbon-burial and CO2 draw-down (Dromart et al. 713 2003), or potentially in response to the impact of rifting on patterns of marine circulation. 714 7. Conclusions 715 Deposition of the Peterborough Member was likely strongly influenced by highly variable basin 716 architecture, with a depositional gradient from the Mid North Sea High channelling sediment 717 towards the Wessex Basin, and the Anglo-Brabant Massif acting to shield the Weald Basin from this 718 sediment source. Deposition on the flanks of the ABM is thin and condensed, and limited in the 719 Weald Basin, suggesting sediment starvation, despite the likely presence of significant sediment 720 accommodation space. 721 The facies at given points in the basin reflect the impact of local basin architecture and its 722 interplay with variable sea level. Spatial contrasts in facies across the basin provide evidence of 723 environmental gradients that can be used to inform how these facies are likely to be distributed and 724 transition across the basin. For example, organic-rich mudstones on the East Midlands Shelf in the 725 Jason Zone, coincident with low relative sea level, correspond with biofacies in the Wessex Basin 726 29 indicative of relatively greater oxygenation, with significant silt content, and containing limited 727 lithological evidence for poor circulation. The facies response of the Peterborough Member to 728 relative sea level rise at the base of the Athleta Zone is markedly variable. At the edge of the Wessex 729 Basin there is a sharp transition into organic-rich mudstone with a sparse fauna of infaunal bivalves; 730 further into the Wessex Basin the signal is much less stark, with no sustained facies shift, but instead 731 evidence of rapid oscillation between more and less oxic facies; and at the margin of the Weald 732 Basin the event occurs within a shell-rich interval, with components indicative of a range of 733 environments, that may reflect the impact of steep (?fault-controlled) depositional gradients. 734 Compared to other organic-rich mudstones, like the Kimmeridge Clay Formation, the 735 Peterborough Member seems to be a product of a much more heterogeneous depositional 736 environment. This may reflect deposition at an early stage in the cycle of regional sea level rise 737 combined with the continued impact of earlier regional uplift, both potentially acting to restrict 738 accommodation space (Macquaker, 1994) and accentuate the impact of basin irregularity on facies 739 patterns. Given the broad and varied character of the successions investigated for this work, the 740 location of the stratotype Peterborough Member appears unrepresentative of conditions across the 741 wider depositional basin. It cautions against developing basin-scale models from a few well exposed 742 and heavily researched outcrop successions, and emphasises the value of multidisciplinary studies 743 for revealing the underlying depositional controls that shape the geometry and complexity of 744 mudstone heterogeneity. 745 Acknowledgements: We thank J D Hudson (University of Leicester), M J Norry (formerly University 746 of Leicester) and S G Molyneux (BGS) for useful discussion and comment, and K N Page (University of 747 Exeter) and M J Barron (formerly BGS) for providing advice on stratigraphy and correlation. We 748 particularly acknowledge the contribution of our former colleague B M Cox for the wealth of data on 749 the fauna and stratigraphy of the Oxford Clay published in BGS Technical Reports. We also 750 acknowledge the United Kingdom Oil and Gas Authority (https://www.ogauthority.co.uk/) for 751 allowing use of borehole geophysical log data. 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Map 1096 references for localities are given in text and/or Supplementary Data. 1097 1098 Fig. 2. The stratigraphy of the Oxford Clay Formation and coeval geological units in the Southern 1099 North Sea and Moray basins. Grey highlight indicates stratigraphy that is the focus of this study. 1100 Boreholes are continuously cored successions drilled for BGS, or partially cored successions drilled 1101 by others for hydrocarbons exploration (Ashdown 2, Kimmeridge 2) and held in the BGS national 1102 borehole archive at Keyworth, Nottingham. Biozonal nomenclature used in the text follows the 1103 conventions discussed by Cox (1990), in regarding Jurassic ammonite zones as chronostratigraphical 1104 units, referred to by species name with an initial capital letter written in non-italicized text. For 1105 clarity, we include the genus name on Figure 2, abbreviated by an initial letter for Subzones where 1106 this is the same as the genus used for the corresponding zone. 1107 1108 Fig. 3. Modelled thickness and correlation of the Peterborough Member. (A) Gamma ray log 1109 correlation: Southern North Sea - East Midlands Shelf - Wessex Basin - Channel Basin (Line 1 of Fig. 1110 1). (B) Gamma ray log correlation: East Midlands Shelf - Anglo-Brabant Massif - Weald Basin (Line 2 1111 of Fig. 1). (C) Interpolated thickness map showing faults (from Pharaoh et al. 1996) and borehole 1112 locations. Borehole numbering follows that used on Fig. 1. WWB (West Walton Beds); MD 1113 (measured depth, metres); TVD (true vertical depth, metres); gAPI (gamma ray American Petroleum 1114 Institute units). Cored boreholes (annotated) provide stratigraphical control for interpretations. 1115 Fig. 4. Gamma log correlation of the Oxford Clay Formation and Peterborough Member in the Weald 1116 and Wessex basins. Log interpretations are guided by the records from cored and geophysically 1117 logged boreholes, published log interpretations (e.g. Winterborne Kingston; Rhys et al., 1981), and 1118 related borehole data held in BGS data archives. 1119 1120 Fig. 5. Stratigraphy, geochemistry and biofacies of the CM9 and CM11 boreholes. Geochemical data 1121 show patterns of enrichment in shell (red curve) and detrital material (blue curve). The 1122 stratigraphical distribution of samples and their biofacies assignment is represented by the pattern 1123 of short horizontal lines plotted for each defined biofacies cluster (Chm 1, 2 etc). The composition of 1124 biofacies clusters is given in bar charts showing relative proportions of the key components, 1125 calculated by dividing the total number of records for each component by the total number of 1126 samples. See Supplementary Data for full details. Contrasting detail of shell beds at different levels in 1127 38 the succession are shown as core images for interval 'X' (sharp-based shell bed) and for interval 'Y' 1128 (shell bed with gradational base). ‘C’ and S1 – S15 are geochemical peaks discussed in the text. 1129 1130 Fig. 6. Lithology and biofacies of cored borehole successions in the Peterborough Member. Biofacies 1131 clusters are unique to each site and based on NERC clustering. See caption to Fig. 5 for explanation. 1132 NB: for clarity of other detail, shell hash not annotated on Eriswell log, but it is common throughout. 1133 * denotes lithologically and faunally distinct interval in Down Ampney 2 Borehole characterised by 1134 concentration of wood, foraminifera and bone. 1135 Fig. 7. Correlation and biofacies classification of Peterborough Member successions according to 1136 Duff (1974, 1975) compared with biofacies classifications assigned using DCA and NERC clustering. 1137 The comparison shows broad similarity in the pattern of classification deduced by the contrasting 1138 methodologies. The stratigraphical ranges of NERC biofacies clusters (Ca1, BL1, St1, NC1, etc.) 1139 corresponds with quantitative data for individual beds within each succession. The composition of 1140 biofacies clusters is given in bar charts showing percentages of key components in each NERC 1141 cluster. 1142 Fig. 8. Detrended Correspondence Analysis (DCA) of fossil assemblages in the Christian Malford CM 1143 11 (A) and Warlingham (B) boreholes, showing positions of samples and upper quartile taxa. The 1144 highly contrasting geometry of sample points with respect to key taxa at Warlingham compared to 1145 Christian Malford suggests a significantly contrasting relationship in the association of different taxa 1146 that characterise biofacies at the two sites. The distributions at Warlingham are inferred to be a 1147 mixing signal rather than an indication of altered palaeoecological relationships between taxa (see 1148 text for details). The proximity of Bositra and nuculacean bivalves on the DCA plot for Warlingham is 1149 reflected in their unusually close association in biofacies clusters throughout this succession (Fig. 7). 1150 See Fig. 7 for key to biofacies components. DCA plots for all cored boreholes forming part of this 1151 study are given in Supplementary Data. 1152 Fig. 9. Detrended Correspondence Analysis (DCA) for localities described by Duff (1974, 1975) 1153 showing positions of samples and upper quartile taxa, with samples classified according to NERC 1154 cluster assignment. See Fig. 7 for key to taxa. DCA plots for all cored boreholes forming part of this 1155 study are given in Supplementary Data. 1156 Fig. 10. Biozonal correlation of cored boreholes and key outcrops in the Peterborough Member. 1157 Borehole numbering follows that used on Fig. 1. Zn (Zone), Sz (Subzone), Gr (Grossouvrei), Ob 1158 (Obductum). 1159 1160 Fig. 11. Conceptual basin model for deposition of the Peterborough Member, showing key 1161 palaeogeographical and structural elements. 1: deltaic deposition in collapsed graben along crest of 1162 Mid-North Sea High; 2: thin successions with organic-rich mudstone on East Midlands Shelf; 3: highly 1163 condensed deposition with abundant shell hash on flanks of Anglo-Brabant Massif; 4: shell-rich 1164 mudstone at faulted margin of Weald Basin, fed by sediment from higher on flank of Anglo-Brabant 1165 Massif; 5: sediment-starved basin with thin, organic-rich and pyritic mudstone and limestone; 6: 1166 intra-basinal high with silty and sand-rich mudstone; 7: main depocentre underlain by extensive 1167 network of east-west faults, fed by sediment from flanks of Mid-North Sea High, East Midlands Shelf 1168 and pathways associated with the buried Worcester Graben. Note: vertical scale exaggerated. 1169 Fig. 12. The Worcester Graben defined by regional gravity data, with significant thickening of 1170 Peterborough Member occurring to the south and south-west, in line with the mouth of this 1171 39 structure. Black arrows denote likely sediment pathways. Gravity data from Smith and Edwards 1172 (1997), https://www.bgs.ac.uk/datasets/gb-land-gravity-survey/. 1173 1174 Appendix 1 – Biofacies components and their abbreviation used in statistical analysis. Data list has 1175 been conditioned to remove species-level data (mainly applicable to data originally collected by 1176 Duff (1974, 1975) 1177 1178 ammonite (AM) 1179 ammonite spat (AmS) 1180 Anisocardia (Aic) 1181 aptychus (AP) 1182 arcid (AR) 1183 Bathrotomaria (BA) 1184 belemnite (BL) 1185 Belemnotheutis (BT) 1186 bone (BN) 1187 Bositra (BO) 1188 bryozoan (BR) 1189 burrowing (BU) 1190 Camptonectes (Ca) 1191 Chlamys (CH) 1192 cirripede (CI) 1193 coprolite (CO) 1194 Corbicella (CL) 1195 Corbulomima (C) 1196 crinoid ossicle (Cr) 1197 Dicroloma (DI) 1198 Discomiltha (Dm) 1199 Echinoid spine (Es) 1200 Entolium (EN) 1201 foraminifera (FO) 1202 gastropod (juvenile) (GJ) 1203 40 Genicularia (GE) 1204 Grammatodon (GR) 1205 Gryphaea (GY) 1206 Shell hash (HS) 1207 Hooks (belemnoid) (HO) 1208 Isocyprina (IS) 1209 Isognomon (IG) 1210 Lingula (Li) 1211 Mastigophora (MA) 1212 Mecochirus (MS) 1213 Meleagrinella (ME) 1214 Mesosacella (MC) 1215 Modiolus (MO) 1216 Myophorella (MP) 1217 Nanogyra (NG) 1218 Neocrassina (NE) 1219 Nicaniella (NI) 1220 nuculaceans (NU) 1221 Ooliticia (OO) 1222 Ophiuroid (OP) 1223 Orbiculoidea (Orb) 1224 ostracod (OS) 1225 otolith (OT) 1226 Oxytoma (OX) 1227 oyster (OR) 1228 Parainoceramus (PA) 1229 Pecten (PN) 1230 Pholadomya (PM) 1231 Pinna (PIN) 1232 Plagiostoma (PG) 1233 Pleuromya (PL) 1234 41 ?Praecoria (PRa) 1235 Procerithium (PR) 1236 Protocardia (PC) 1237 Pteroperna (PT) 1238 Quenstedtia (QU) 1239 rhynchonellid (Rh) 1240 Rollierella (Ro) 1241 scaphopod (SC) 1242 serpulid (SE) 1243 shell hash (HS) 1244 Solemya (SO) 1245 solitary coral (Sco) 1246 spat (SP) 1247 sponges (Spo) 1248 terebratulid (TE) 1249 Thracia (TH) 1250 trigoniid (Tr) 1251 wood (W) 1252 1253 Appendix 2 – Other abbreviations used in statistical outputs 1254 Athleta Zone (Az) 1255 Calloviense Subzone (Csz) 1256 Calloviense Zone (Caz) 1257 Combined Coronatum, 1258 Jason, Calloviense 1259 Zones (CJC) 1260 Coronatum Zone (Cz) 1261 Enodatum Subzone (Esz) 1262 Grossouvrei Subzone (Gsz) 1263 Jason Subzone (Jsz) 1264 Jason Zone (Jz) 1265 42 Medea Subzone (Msz) 1266 Phaeinum Subzone (Psz) 1267 Sample Size (Sz) 1268 1269 CITATIONS (0) REFERENCES (86) ResearchGate has not been able to resolve any citations for this publication. Reconstructing the Christian Malford ecosystem in the Oxford Clay Formation (Callovian, Jurassic) of Wiltshire: exceptional preservation, taphonomy, burial and compaction Article Full-text available * Jul 2019 * J MICROPALAEONTOL * Malcolm B. Hart * Kevin N. Page * Gregory D. Price * Christopher W. Smart The Christian Malford lagerstätte in the Oxford Clay Formation of Wiltshire contains exceptionally well-preserved squid-like cephalopods, including Belemnotheutis antiquus (Pearce). Some of these fossils preserve muscle tissue, contents of ink sacks and other soft parts of the squid, including arms with hooks in situ and the head area with statoliths (ear bones) present in life position. The preservation of soft-tissue material is usually taken as an indication of anoxic or dysaerobic conditions on the sea floor and within the enclosing sediments. Interestingly, in the prepared residues of all these sediments there are both statoliths and arm hooks as well as abundant, species-rich, assemblages of both foraminifera and ostracods. Such occurrences appear to be incompatible with an interpretation of potential sea floor anoxia. The mudstones of the Oxford Clay Formation may have been compacted by 70 %–80 % during de-watering and burial, and in such a fine-grained lithology samples collected for microfossil examination probably represent several thousand years and, therefore, a significant number of foraminiferal life cycles. Such samples (even if only 1–2 cm thick) could, potentially, include several oxic–anoxic cycles and, if coupled with compaction, generate the apparent coincidence of well-preserved, soft-bodied, cephalopods and diverse assemblages of benthic foraminifera. View Show abstract Radioactive Waste Confinement: Clays in Natural and Engineered Barriers – introduction Article Full-text available * Mar 2017 * Simon Norris Extract There is general agreement internationally (Nuclear Energy Agency, OECD 2008) that geological disposal provides the safest long-term management solution for higher-activity radioactive waste. Many countries (e.g. Canada, Finland, France, Switzerland, Sweden, UK and USA) have chosen to dispose of all or part of their radioactive waste in facilities constructed at an appropriate depth in stable geological formations. The development of a repository (sometimes also referred to as a geological disposal facility) on a specific site requires a systematic and integrated approach, taking into account the characteristics of (i) the waste to be emplaced, (ii) the enclosing engineered barriers and (iii) the host rock and the geological setting of the host rock. Three main rock types are usually considered for geological disposal: crystalline rocks, salt and clays. Each type includes bedrock formations with a relatively broad spectrum of geological properties. The engineered barriers contain different types of materials, such as metals, concrete and natural materials, such as clay. View Show abstract Exceptional accumulations of statoliths in association with the Christian Malford Lagerstätte (Callovian, Jurassic) in Wiltshire, United Kingdom Article Full-text available * May 2016 * Malcolm B. Hart * ALEX DE JONGHE * Kevin Page * Christopher W. Smart In the shell-rich, laminated clays of the Phaeinum Subzone (Athleta Zone, upper Callovian, Middle Jurassic) of the Peterborough Member of the Oxford Clay Formation, large numbers of statoliths and otoliths have been recovered. This apparent mass mortality is associated with the Christian Malford Lagerstätte in which there is exceptional, soft-bodied preservation of coleoid fossils. Statoliths are the aragonitic 'stones' that are found in the fluidfilled cavities (or statocysts) within the cartilaginous head of all modern and probably many fossil coleoids. Jurassic statoliths are largely undescribed and there are no known genera or species available to aid their classification. Otoliths, which may be of somewhat similar appearance, are the aragonitic stato-acoustic organs of bony (teleost) fish. These are more familiar to micropaleontologists and have a better known, though limited, fossil record. The abundance of statoliths in the Phaeinum Subzone at Christian Malford may indicate a mass mortality of squid that extends over some 3 m of strata and, therefore, a considerable interval of time. This has been tentatively interpreted as a record of a breeding area (and subsequent death) of squid-like cephalopods over an extended period of time rather than a small number of catastrophic events. View Show abstract Nearshore transgressive black shale from the Middle Jurassic shallow-marine succession from southern Poland Article Full-text available * Apr 2016 * Paulina Leonowicz Five facies types are distinguished in the Middle Jurassic dark-grey mudstone of the Częstochowa Ore-Bearing Clay Formation on the basis of sedimentary structures, bioturbation intensity, and composition of trace fossil and benthic fauna associations. Three of them, laminated mudstone (Ml), laminated claystone (Cl), and alternating laminated and bioturbated mudstone (Ma), are varieties of black shale. They formed in relatively shallow water, several tens of meters deep, in an epicontinental sea, mainly during the early phase of Middle Jurassic transgression. Suboxic conditions developed beneath a temporary pycnocline in a narrow, proximal zone near flooded land, which delivered increased amounts of organic matter and nutrients, triggering plankton blooms. Oxygen-deficient conditions were recurrently interrupted by re-oxygenation events, linked with the activity of storm-generated bottom currents, which simultaneously redistributed significant amounts of sediment from the basin-margin shoreface zones. Oxygenation improvement varied in duration from single storms to periods lasting several tens of years. The association of laminated mudstone with the beginning of major transgression, relatively shallow water, frequent oxygenation of the sea floor, and the occurrence of better-oxygenated time-equivalent facies in more distal settings, indicates that these deposits represent nearshore transgressive black shale. The limited occurrence of black shale and its poor correlation with minor transgressive–regressive cycles show that its formation depended mainly on local conditions, which were only partly influenced by relative sea-level changes within the basin. View Show abstract A comparison of clustering methods for biogeography with fossil datasets Article Full-text available * Feb 2016 * Matthew Vavrek Cluster analysis is one of the most commonly used methods in palaeoecological studies, particularly in studies investigating biogeographic patterns. Although a number of different clustering methods are widely used, the approach and underlying assumptions of many of these methods are quite different. For example, methods may be hierarchical or non-hierarchical in their approaches, and may use Euclidean distance or non-Euclidean indices to cluster the data. In order to assess the effectiveness of the different clustering methods as compared to one another, a simulation was designed that could assess each method over a range of both cluster distinctiveness and sampling intensity. Additionally, a non-hierarchical, non-Euclidean, iterative clustering method implemented in the R Statistical Language is described. This method, Non-Euclidean Relational Clustering (NERC), creates distinct clusters by dividing the data set in order to maximize the average similarity within each cluster, identifying clusters in which each data point is on average more similar to those within its own group than to those in any other group. While all the methods performed well with clearly differentiated and well-sampled datasets, when data are less than ideal the linkage methods perform poorly compared to non-Euclidean based k-means and the NERC method. Based on this analysis, Unweighted Pair Group Method with Arithmetic Mean and neighbor joining methods are less reliable with incomplete datasets like those found in palaeobiological analyses, and the k-means and NERC methods should be used in their place. View Show abstract R: A Language and Environment for Statistical Computing Book * Jan 2015 * Core R Team View Disentangling the control of tectonics, eustasy, trophic conditions and climate on shallow-marine carbonate production during the Aalenian–Oxfordian interval: From the western France platform to the western Tethyan domain Article * Sep 2016 * SEDIMENT GEOL * Simon Andrieu * Benjamin Brigaud * Jocelyn Barbarand * Thomas Saucède The objective of this work is to improve our understanding of the processes controlling changes in the architecture and facies of intracontinental carbonate platforms. We examined the facies and sequence stratigraphy of Aalenian to Oxfordian limestones of western France. Seventy-seven outcrop sections were studied and thirty-one sedimentary facies identified in five depositional environments ranging from lower offshore to backshore. Platform evolution was reconstructed along a 500 km cross-section. Twenty-two depositional sequences were identified on the entire western France platform and correlated with European third-order sequences at the biozone level, demonstrating that eustasy was the major factor controlling the cyclic trend of accommodation. The tectonic subsidence rate was computed from accommodation measurements from the Aalenian to the Oxfordian in key localities.Tectonism controlled the sedimentation rate and platform architecture at a longer time scale. Tectonic subsidence triggered the demise of carbonate production at the Bathonian/Callovian boundary while the uplift made possible the recovery of carbonate platform from Caen to Le Mans during the mid Oxfordian. Topography of the Paleozoic basement mainly controlled lateral variations of paleodepth within the western France platform until the mid Bathonian. A synthesis of carbonate production in the western Tethyan domain at that time was conducted. Stages of high carbonate production during the Bajocian/Bathonian and the middle to late Oxfordian are synchronous with low δ¹³C, high eccentricity intervals, and rather dry climate promoting (1) evaporation and carbonate sursaturation, and (2) oligotrophic conditions. Periods of low carbonate production during the Aalenian and from the middle Callovian to early Oxfordian correlate with high δ¹³C and low eccentricity intervals, characterized by wet climate and less oligotrophic conditions. Such conditions tend to diminish growth potential of carbonate platforms. This work highlights the importance of climate control on carbonate growth and demise at large scale in western Tethyan epicontinental seas. View Show abstract Shell form and the ecological range of living and extinct Arcoida Article * Jan 1978 * Roger D K Thomas Arcoid bivalves occupy an intermediate position, in terms both of morphology and of adaptive range between the Pterioida and the Veneroida. The range and limits of arcoid adaptations are related to the growth patterns of their shells. Both the arcoid hinge and ligament grow by the serial repetition of simple structures, in contrast with the development of more specialized, complex structures in other groups. These simple growth patterns place significant mechanical constraints on the range of possible shell forms. Most arcoids live in moderately unstable environments, where they are liable to be excavated or detached from their substrates. Many employ recovery strategies, being adapted to regain their life positions. However, a variety of specialized forms, convergent on other groups of bivalves, have become adapted to avoid being dislodged in the first place. Thus, intrinsic growth patterns and substrate relationships have been the major factors in the evolution of the Arcoida. View Show abstract Geology of the country around Ely. Memoir for 1:50 000 geological sheet 173 ( England & Wales). Article * Jan 1988 * R W Gallois Traces the geological history of the district from the muddy seas of the Silurian of 400 My, via the deserts of the Triassic and the shallow tropical and subtropical seas of the Jurassic and Cretaceous, to the Quaternary glaciations of 250 000 to 18 000 years ago when the district was covered by ice sheets up to several thousand feet thick. Finally, it records the history of the period after the retreat of the ice when temperate climates returned and the broad glaciated hollow that was to become Fenland was infilled with muds and peats. The greater part of the district is occupied by the Recent sediments of Fenland. These were deposited during the past 10 000 years, during which period sea level has risen by about 30 m. Through man's activities the fens have been converted to richly fertile peat soils and the meres to calcareous marls. But in the process, shrinkage and wastage of the soils due to the drainage works have caused large areas of the underlying geology, including the Jurassic clays, Quaternary gravels and Recent marine clays, to be revealed and have given rise to markedly less fertile soils. Provides an authoritative account of all aspects of the geology of the Ely district including descriptions of the rock types and their faunas, their structure and geological history, and the relationships of these features to past and present land use.-from Author View Show abstract The Kellaways Beds and the Oxford Clay Article * Jan 1968 * J.H. Callomon View Show more RECOMMENDED PUBLICATIONS Discover more Article PRESERVATION OF CARBOHYDRATES THROUGH SULFURIZATION IN A JURASSIC EUXINIC SHELF SEA: EXAMINATION OF... September 2006 · Organic Geochemistry * Bart E. van Dongen * J. S. Sinninghe-Damste * Stefan Schouten A complete total organic carbon (TOC) cycle in the Upper Jurassic Kimmeridge Clay Formation (KCF) comprising the extremely TOC-rich (34%) Blackstone Band was studied to investigate the controlling factors on TOC accumulation. Compared with the under- and overlying strata, TOC in the Blackstone Band was enriched by a factor of six and, concomitantly, the δ13CTOC shows a ∼4‰ enrichment. ... [Show full abstract] Al-normalized TOC values indicated that the enhanced TOC values were probably caused by increased TOC accumulation and not by a decreased dilution with inorganic matter. The amounts of short chain alkylated thiophenes and the sulfur-rich unresolved complex mixture (UCM) in the kerogen pyrolysates, as well as the TOC/Al ratios, correlated linearly with δ13CTOC for sediments with TOC/Al ratios >1.7. The alkylated thiophenes and sulfur-rich UCM both originate from sulfurized carbohydrate carbon (Ccarb), suggesting that the primary cause of the TOC maximum is the enhanced contribution of Ccarb to TOC. Since carbohydrates can be substantially 13C-enriched over lipids in biomass, the enhanced contribution of Ccarb explains the enriched δ13CTOC values. Compound specific isotope data showed that primary productivity during deposition of the KCF TOC cycle varied little, while a two member isotopic mixing model showed that the preservation of Ccarb relative to that of the lipid carbon may have increased by a factor of >10 in the Blackstone Band. The enhanced preservation of Ccarb was most likely caused by more frequent or longer lasting events of photic zone euxinia, as revealed by the concentration of isorenieratene derivatives. Enhanced contributions of Ccarb have also been observed in other KCF cycles, suggesting that enhanced preservation of Ccarb, rather than an increase in primary production, exerted direct control on the TOC cycles of the KCF. Read more Chapter Full-text available VARIATION IN ORGANIC-MATTER COMPOSITION AND ITS IMPACT ON ORGANIC-CARBON PRESERVATION IN THE KIMMERI... January 2005 * Richard D. Pancost * Bart E. van Dongen * AMY ESSER * [...] * J. S. Sinninghe-Damste View full-text Article Full-text available PRESERVING THE UNPRESERVABLE: A LOST WORLD REDISCOVERED AT CHRISTIAN MALFORD, UK May 2008 · Geology Today * Philip Wilby * Kevin Page * Keith Duff * Susan Martin The small village of Christian Malford, Wiltshire (UK) is known to palaeontologists the world over because of the chance discovery of an astonishing fossil bonanza in the mid-nineteenth century. Pits in the Jurassic Oxford Clay yielded thousands of specimens of exquisitely preserved ammonites, fish and crustaceans, but became most famous for squid-like cephalopods and belemnites (collectively ... [Show full abstract] termed coleoids) with fossilized soft-parts. The precise location of the find has remained obscure, until now, and a new attempt is underway to understand the ancient environment that triggered this unusual preservation. View full-text Article ARM HOOKS OF COLEOID CEPHALOPODS FROM THE JURASSIC SUCCESSION OF THE WESSEX BASIN, SOUTHERN ENGLAND April 2018 · Proceedings of the Geologists Association * Malcolm B. Hart * Kevin N. Page * Christopher W. Smart * [...] * Z. Hughes The Jurassic succession of the Wessex Basin – especially that cropping out within the Dorset and East Devon Coast World Heritage Site – contains important lagerstätten for coleoid cephalopods. The Blue Lias and Charmouth Mudstone formations of West Dorset, the Oxford Clay Formation of North Wiltshire and the Kimmeridge Clay Formation of Purbeck have provided large numbers of important body ... [Show full abstract] fossils that inform our knowledge of coleoid palaeobiology, including the hooks present in the arms. Isolated hooks are also found in the processed residues studied by micropalaeontologists and these occurrences can be used – in some cases – to record the presence of key taxa in the absence of well-preserved body fossils. While some hook morphotypes can be attributed to known species, there are many forms of hook described where the parent animal remains unknown. The present state of our knowledge of the Jurassic assemblages in the Wessex Basin is presented and remaining issues identified. Read more Discover the world's research Join ResearchGate to find the people and research you need to help your work. 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