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* Skip to Article Content * Skip to Article Information Search withinThis JournalAnywhere * Search term Advanced Search Citation Search * Search term Advanced Search Citation Search Login / Register * Individual login * Institutional login * REGISTER Advanced Energy Materials Volume 8, Issue 17 1703137 Review SODIUM AND SODIUM-ION BATTERIES: 50 YEARS OF RESEARCH Claude Delmas, Corresponding Author Claude Delmas * claude-henri.delmas@icmcb.cnrs.fr * orcid.org/0000-0002-8188-0067 ICMCB-CNRS, 87, Av Dr A. Schweitzer, 33608 Pessac, France E-mail: claude-henri.delmas@icmcb.cnrs.frSearch for more papers by this author Claude Delmas, Corresponding Author Claude Delmas * claude-henri.delmas@icmcb.cnrs.fr * orcid.org/0000-0002-8188-0067 ICMCB-CNRS, 87, Av Dr A. Schweitzer, 33608 Pessac, France E-mail: claude-henri.delmas@icmcb.cnrs.frSearch for more papers by this author First published: 19 February 2018 https://doi.org/10.1002/aenm.201703137 Citations: 937 Read the full text About * REFERENCES * RELATED * INFORMATION * PDF PDF Tools * Request permission * Export citation * Add to favorites * Track citation ShareShare Give access Share full text access Close modal Share full-text access Please review our Terms and Conditions of Use and check box below to share full-text version of article. I have read and accept the Wiley Online Library Terms and Conditions of Use -------------------------------------------------------------------------------- Shareable Link Use the link below to share a full-text version of this article with your friends and colleagues. Learn more. Copy URL Share a link Share on * Email * Facebook * x * LinkedIn * Reddit * Wechat ABSTRACT This paper gives an overview of the research carried out on sodium batteries in the last 50 years. The discovery of the very high Na+ ion conductivity in β-Al2O3 opened the way to high-energy batteries (sodium/sulfur and sodium/NiCl2) for load leveling and electrical vehicles. Then, the liquid electrolyte batteries were considered with intercalation-based electrodes and lithium and sodium as mobile ions. When Sony proposed the lithium-ion batteries, most research moved to lithium systems, exhibiting a higher energy density. These are now currently used in electronic devices, hybrid electrical vehicle (HEV) and electrical vehicle (EV). The development of renewable energies, which have an intermittent character, requires very large batteries for frequency regulation and peak production shift. For these stationary applications the most important parameters are the lifetime, the power, the price, and the material availability. Since sodium ion batteries are able to satisfy these criteria, these new material families now concern a large part of the scientific community. This article gives a general introduction and an overview of the research carried out on the materials that are presented in detail, in the articles within this special issue on sodium batteries. CONFLICT OF INTEREST The authors declare no conflict of interest. REFERENCES * 1Y. Yao, J. Kummer, Inorg. Nucl. Chem. 1967, 29, 2453. 10.1016/0022-1902(67)80301-4 CASWeb of Science®Google Scholar * 2F. Bragg, C. Gottfried, J. West, Z. Krist. 1931, 77, 255. CASWeb of Science®Google Scholar * 3C. A. Beevers, M. A. Ross, Z. Krist. 1937, 97, 59 10.1524/zkri.1937.97.1.59 CASWeb of Science®Google Scholar * 4J. Thery, D. Briancon, Rev. Hautes Temp. Refract. 1964, 1, 221. Google Scholar * 5J. Coetzer, R. C. Galloway, R. J. 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KGaA, Weinheim KEYWORDS * electrode materials * sodium batteries * sodium-ion batteries PUBLICATION HISTORY * Issue Online: 15 June 2018 * Version of Record online: 19 February 2018 * Manuscript revised: 14 December 2017 * Manuscript received: 09 November 2017 Close Figure Viewer Previous FigureNext Figure Caption Download PDF back ADDITIONAL LINKS ABOUT WILEY ONLINE LIBRARY * Privacy Policy * Terms of Use * About Cookies * Manage Cookies * Accessibility * Wiley Research DE&I Statement and Publishing Policies * Developing World Access HELP & SUPPORT * Contact Us * Training and Support * DMCA & Reporting Piracy OPPORTUNITIES * Subscription Agents * Advertisers & Corporate Partners CONNECT WITH WILEY * The Wiley Network * Wiley Press Room Copyright © 1999-2024 John Wiley & Sons, Inc or related companies. All rights reserved, including rights for text and data mining and training of artificial intelligence technologies or similar technologies. 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